GB355573A - Improvements in the manufacture and production of polymerisation products - Google Patents
Improvements in the manufacture and production of polymerisation productsInfo
- Publication number
- GB355573A GB355573A GB31131/30A GB3113130A GB355573A GB 355573 A GB355573 A GB 355573A GB 31131/30 A GB31131/30 A GB 31131/30A GB 3113130 A GB3113130 A GB 3113130A GB 355573 A GB355573 A GB 355573A
- Authority
- GB
- United Kingdom
- Prior art keywords
- styrene
- substances
- mixtures
- polymerized
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Polymerized styrene and its homologues or mixtures thereof or mixtures of these with other substances are obtained by treating the styrene &c. in aqueous emulsion with oxygen or agents supplying oxygen such as benzoyl peroxide or hydrogen peroxide. The emulsifying agents may be soaps, saponins, sulphonic acids, sulphuric esters and their salts, preferably with the addition of higher alcohols, albumenous substances, degradation products of albumen, and other substances which promote emulsification, such as bentonite. The polymerization agent may be added before, during, or after the emulsification. In the examples styrene is emulsified with (1) oleic acid and aqueous ammonia and (2) ammonium oleate and aqueous ammonia and polymerized in each case with hydrogen peroxide at 60-70 DEG C. and 30 DEG C. respectively. Unpolymerized styrene is removed from the product by steam distillation.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE626585T | 1930-01-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB355573A true GB355573A (en) | 1931-08-27 |
Family
ID=34812914
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB31131/30A Expired GB355573A (en) | 1930-01-29 | 1930-10-17 | Improvements in the manufacture and production of polymerisation products |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE626585C (en) |
FR (1) | FR709592A (en) |
GB (1) | GB355573A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2835582A (en) * | 1954-02-03 | 1958-05-20 | Eastman Kodak Co | Gelatin-polymeric hydrosol mixtures and photographic articles prepared therefrom |
US2971893A (en) * | 1958-05-29 | 1961-02-14 | Hercules Powder Co Ltd | Phenol purification |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1015600B (en) * | 1950-01-03 | 1957-09-12 | Dow Chemical Co | Process for the production of copolymers from styrene and ª ‡ -methylstyrene with increased dimensional stability by means of bulk polymerisation |
BE516713A (en) * | 1952-01-12 |
-
1930
- 1930-01-29 DE DE1930626585D patent/DE626585C/en not_active Expired
- 1930-10-17 GB GB31131/30A patent/GB355573A/en not_active Expired
-
1931
- 1931-01-17 FR FR709592D patent/FR709592A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2835582A (en) * | 1954-02-03 | 1958-05-20 | Eastman Kodak Co | Gelatin-polymeric hydrosol mixtures and photographic articles prepared therefrom |
US2971893A (en) * | 1958-05-29 | 1961-02-14 | Hercules Powder Co Ltd | Phenol purification |
Also Published As
Publication number | Publication date |
---|---|
FR709592A (en) | 1931-08-11 |
DE626585C (en) | 1936-02-28 |
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