GB353763A - Improvements in and relating to the manufacture of fertilisers - Google Patents
Improvements in and relating to the manufacture of fertilisersInfo
- Publication number
- GB353763A GB353763A GB28331/30A GB2833130A GB353763A GB 353763 A GB353763 A GB 353763A GB 28331/30 A GB28331/30 A GB 28331/30A GB 2833130 A GB2833130 A GB 2833130A GB 353763 A GB353763 A GB 353763A
- Authority
- GB
- United Kingdom
- Prior art keywords
- calcium
- potassium
- nitrate
- mixture
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B11/00—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes
- C05B11/04—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid
- C05B11/06—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid using nitric acid (nitrophosphates)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
Phosphoric acid; calcium and potassium nitrates; ammonium phosphates.--Fertilizers are obtained from phosphate rock and potassium salts by dissolving phosphate rock in nitric acid, crystallizing calcium nitrate from the resulting solution, converting all or part of the calcium nitrate by means of potassium salts into potassium nitrate, mixing a convenient portion of the potassium nitrate with the mother liquors from the crystallization of calcium nitrate, neutralizing the mixture with ammonia and drying the product. The potassium salts referred to are the sulphate and chloride. The mother liquor may be freed from its remaining calcium by precipitation with reagents such as hydrofluoric acid, sulphuric acid, ammonium or potassium fluoride, ammonium or alkali sulphates or bisulphates prior to its further treatment, the calcium precipitates being used in known manner to regenerate the reagent. The mixture or solution of potassium nitrate and phosphoric acid containing mother liquor is preferably brought to dryness during the neutralizing reaction with ammonia, the mixture being injected into, or subjected to stirring in, an apparatus into which gaseous ammonia is introduced under such conditions that the water present is evaporated by the heat developed, with if necessary a further supply of heat so that a dry product is obtained capable of continuous removal. The amount of calcium nitrate separated by crystallization may be limited so that the product contains di-calcium phosphate. Specifications 339,340 and 339,969, [both in Class 1 (ii), Inorganic compounds, other than &c.], are referred to.ALSO:Fertilizers are obtained from phosphate rock and potassium salts by dissolving phosphate rock in nitric acid, crystallizing calcium nitrate from the resulting solution, converting all or part of the calcium nitrate by means of potassium salts into potassium nitrate, mixing a convenient portion of the potassium nitrate with the mother liquors from the crystallization of calcium nitrate, neutralizing the mixture with ammonia and drying the product. The potassium salts referred to are the sulphate and chloride. The mother liquor may be freed from its remaining calcium by precipitation with reagents such as hydrofluoric acid, sulphuric acid, ammonium or potassium fluoride, ammonium or alkali sulphates or bisulphates prior to its further treatment, the calcium precipitates being used in known manner to regenerate the reagent. The mixture or solution of potassium nitrate and phosphoric acid containing mother liquor is preferably brought to dryness during the neutralizing reaction with ammonia, the mixture being injected into, or subjected to stirring in, an apparatus into which gaseous ammonia is introduced under such conditions that the water present is evaporated by the heat developed, with if necessary a further supply of heat so that a dry product is obtained capable of continuous removal. The amount of calcium nitrate separated by crystallization may be limited so that the product contains di-calcium phosphate. Specifications 339,340 and 339,969, [both in Class 111, Sewage &c.], are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO353763X | 1929-09-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB353763A true GB353763A (en) | 1931-07-30 |
Family
ID=19905354
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB28331/30A Expired GB353763A (en) | 1929-09-28 | 1930-09-22 | Improvements in and relating to the manufacture of fertilisers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB353763A (en) |
-
1930
- 1930-09-22 GB GB28331/30A patent/GB353763A/en not_active Expired
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