GB349387A - Process for spinning acid solutions of silk fibroin - Google Patents
Process for spinning acid solutions of silk fibroinInfo
- Publication number
- GB349387A GB349387A GB24905/30A GB2490530A GB349387A GB 349387 A GB349387 A GB 349387A GB 24905/30 A GB24905/30 A GB 24905/30A GB 2490530 A GB2490530 A GB 2490530A GB 349387 A GB349387 A GB 349387A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bath
- filaments
- solution
- alkali salts
- per cent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F4/00—Monocomponent artificial filaments or the like of proteins; Manufacture thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Peptides Or Proteins (AREA)
Abstract
349,387. Artificial silk. I. G. FARBENINDUSTRIE AKT.-GES., Frankforton-Main, Germany. Aug. 20, 1930, No. 24905. Convention date, Aug. 31, 1929. [Class 2 (ii).] Albuminoids, processes for making filaments from. -Refers to Specification 339,089 [Class 2 (ii), Cellulose &c.], and consists in spinning a phosphoric acid solution of silk fibroin into two successive coagulating baths, the first having a slower action than the second. The first bath contains chiefly alkali salts of mineral acids, while the second bath contains one or more alkali salts of lower fatty acids. Alkali salts of hydroxy or keto acids may be added to one or both baths. After leaving the second bath the filaments are given a long air travel without stretch and are then stretched 5-8 times and afterwards washed on the spool, soaped and dried. To prevent adhesion of the filaments, an ethereal oil is added to the spinning bath. In an example, a solution of fibroin in phosphoric acid is prepared as described in Specification 339,089, with an addition of 0À04 per cent of turpentine oil, and is passed into a first coagulating bath containing sodium and potassium chloride, lactates, and formates, together with formaldehyde. After leaving the first bath, the thread is passed over a roller into a second bath consisting of a saturated solution of ammonium formate mixed with about #th of its volume of a 64 per cent sodium lactate solution. The second bath is made as long as possible, e.g. at least 50 cms. After an air travel of one or several metres, the thread is stretched. Soft, brilliant threads are obtained having a single titre down to one denier, dry tenacity up to 2 grams per denier, wet tenacity of more than 1 gram per denier, and extensibility of 12 per cent.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI36101D DE510489C (en) | 1928-11-14 | 1928-11-14 | Method for loosening and reprecipitating silk fibroin |
| DEI39189D DE534571C (en) | 1928-11-14 | 1929-08-31 | Process for spinning solutions of silk fibroin in phosphoric acid by means of falling balls |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB349387A true GB349387A (en) | 1931-05-28 |
Family
ID=25981534
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB34846/29A Expired GB339089A (en) | 1928-11-14 | 1929-11-14 | Process for making artificial threads, hairs, bands or the like from solutions of silk fibroin |
| GB24905/30A Expired GB349387A (en) | 1928-11-14 | 1930-08-20 | Process for spinning acid solutions of silk fibroin |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB34846/29A Expired GB339089A (en) | 1928-11-14 | 1929-11-14 | Process for making artificial threads, hairs, bands or the like from solutions of silk fibroin |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US1990588A (en) |
| DE (1) | DE534571C (en) |
| GB (2) | GB339089A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2461602A (en) * | 1946-01-17 | 1949-02-15 | American Viscose Corp | Method of manufacturing synthetic sutures and the like |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2711376A (en) * | 1949-06-25 | 1955-06-21 | Thomas C Whitner | Preparation and use of sericeous solutions |
| US6287340B1 (en) * | 1999-05-14 | 2001-09-11 | Trustees Of Tufts College | Bioengineered anterior cruciate ligament |
| GB0108181D0 (en) * | 2001-04-02 | 2001-05-23 | Xiros Plc | Silk-based fibre |
| DE10125359B4 (en) * | 2001-05-23 | 2005-07-28 | Osypka Medical Gmbh | An AC power source for generating an AC current to be transmitted through the body and a method of generating a stable AC current |
| US6902932B2 (en) * | 2001-11-16 | 2005-06-07 | Tissue Regeneration, Inc. | Helically organized silk fibroin fiber bundles for matrices in tissue engineering |
| US20110009960A1 (en) * | 2001-11-16 | 2011-01-13 | Allergan, Inc. | Prosthetic fabric structure |
| US20040219659A1 (en) * | 2002-04-22 | 2004-11-04 | Altman Gregory H. | Multi-dimensional strain bioreactor |
| US20110121485A1 (en) * | 2006-10-30 | 2011-05-26 | Spintec Engineering Gmbh | Method and apparatus for the manufacture of a fiber |
| US9326840B2 (en) | 2008-12-15 | 2016-05-03 | Allergan, Inc. | Prosthetic device and method of manufacturing the same |
| CN102271620B (en) | 2008-12-15 | 2015-04-08 | 阿勒根公司 | A prosthetic device and method of manufacturing the same |
| US9308070B2 (en) * | 2008-12-15 | 2016-04-12 | Allergan, Inc. | Pliable silk medical device |
| US9204954B2 (en) * | 2008-12-15 | 2015-12-08 | Allergan, Inc. | Knitted scaffold with diagonal yarn |
| US9204953B2 (en) | 2008-12-15 | 2015-12-08 | Allergan, Inc. | Biocompatible surgical scaffold with varying stretch |
| WO2011031854A1 (en) * | 2009-09-11 | 2011-03-17 | Allergan, Inc. | Prosthetic device and method of manufacturing the same |
-
1929
- 1929-08-31 DE DEI39189D patent/DE534571C/en not_active Expired
- 1929-11-12 US US406718A patent/US1990588A/en not_active Expired - Lifetime
- 1929-11-14 GB GB34846/29A patent/GB339089A/en not_active Expired
-
1930
- 1930-08-20 GB GB24905/30A patent/GB349387A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2461602A (en) * | 1946-01-17 | 1949-02-15 | American Viscose Corp | Method of manufacturing synthetic sutures and the like |
Also Published As
| Publication number | Publication date |
|---|---|
| US1990588A (en) | 1935-02-12 |
| GB339089A (en) | 1930-12-04 |
| DE534571C (en) | 1931-09-28 |
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