GB343102A - Improvements in or relating to the printing of cotton - Google Patents
Improvements in or relating to the printing of cottonInfo
- Publication number
- GB343102A GB343102A GB2484329A GB2484329A GB343102A GB 343102 A GB343102 A GB 343102A GB 2484329 A GB2484329 A GB 2484329A GB 2484329 A GB2484329 A GB 2484329A GB 343102 A GB343102 A GB 343102A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- glycerine
- ammonia
- sodium
- reduced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Coloring (AREA)
Abstract
Dye preparations; printing.-Dyestuff pastes for cotton-printing purposes are made by reducing vat dyes in the presence of water, a water-soluble alcohol, and an alkali weaker than an alkali metal hydroxide, such as potassium carbonate or ammonia. Glycerine, glycol, diethyleneglycol, glycerine oxyethylether, thiodiglycol, and thiodiglycerol are specified as water soluble alcohols; mixtures of such alcohols and commercial products such as crude glycerine lyes containing them can also be employed. The preparations may be mixed with hydrotropic agents before or after reduction, such agents including urea, substituted ureas, thiourea, hexamethylenetetramine, potassium ethylether sulphonate, potassium or sodium isovalerate, and alkali salts of the following acids:-isobutyric acid, phenylacetic acid, benzoic acid, o-toluic acid, salicylic acid, benzene sulphonic and sulphinic acids, p-toluene sulphonic and sulphinic acids, naphthalene sulphonic acids, e.g. a - and b -naphthalene sulphonic acids, aniline sulphonic acids and their substitution products e.g. dimethylsulphanilic acid, dimethylmetanilic acid, diethylmetanilic acid and dimethyl-2-toluidine-4-sulphonic acid, and hydroaromatic carboxylic and sulphonic acids, e.g. cyclohexanecarboxylic acid and tetrahydronaphthalene-b -sulphonic acid. Sodium hydrosulphite is preferably employed as reducing agent; iron-carbonyl and titanium trichloride are also specified. In examples, (1) the dyestuff obtained by coupling 1 : 2-pheno-5-oxynaphthocarbazole with isatin anilide is reduced with hydrosulphite in the presence of ammonia and glycerine, the preparation thus obtained is pasted with a thickening containing wheat starch, British gum, tragacanth, glycerine, potassium carbonate and sodium formaldehyde sulphoxylate, printed in the usual manner, and the prints are steamed and developed with potassium dichromate and acetic acid, (2) the dyestuff of Example 1 of Specification 201,786, [Class 2 (iii), Dyes, &c.], is reduced with hydrosulphite and ammonia in the presence of crude saponification glycerine and urea and printed as in Example 1, (3) the dyestuff of Example 1 of Specification 2592/07, [Class 2, Acids and salts, Organic, &c.], is reduced with ammonia and hydrosulphite in the presence of glycerine and sodium benzenesulphonate, (4) the dyestuff of Example 2 of U.S.A. Patent 1,537,928 is similarly reduced in the presence of glycerine or diethyleneglycol and urea, (5) the dyestuff from 6-methoxy-3-oxythionaphthene and 4-methyl-6-brom-2 : 3-dihydro-3-ketothionaphthene-2-(p-dimethylamino)-anil (Specification 222,094), [Class 2 (iii), Dyes, &c.] is reduced with hydrosulphite and ammonia in the presence of glycerine and sodiumbenzene sulphonite, (6) 6 : 61-diethoxythioindigo is similarly reduced, (7) 6 : 61-dichlor-4 : 41-dimethylthioindigo is reduced with hydrosulphite and ammonia in the presence of phthalic anhydride, which reacts with the ammonia to form ammonium phthalate; instead of phthalic anhydride, the sodium salts of p-dimethylamino-benzoic acid, o-cresotinic acid, or dimethylsulphanilic acid may be used, (8) 4 : 7 : 41 : 71-tetramethyl-6 : 61-dichlorthioindigo and 6 : 61-dimethyl - 4 : 41 - dichlorthioindigo are similarly reduced, the sodium salts of benzenesulphonic acid, dimethylmetanilic acid, dimethylsulphanilic acid or salicylic acid being used instead of phthalic anhydride, and (9) Caledon jade green is reduced with ammonia and hydrosulphite in the presence of crude saponification glycerine and sodium dimethylmetanilate or sodium naphthalene-b -sulphonate. Glycerine derivatives.-Glycerine oxyethylether, which is not a uniform compound, is made by treating glycerine with ethyleneoxide. Thiodiglycerol is made from monochlorhydrin and sodium sulphide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2484329A GB343102A (en) | 1929-08-14 | 1929-08-14 | Improvements in or relating to the printing of cotton |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2484329A GB343102A (en) | 1929-08-14 | 1929-08-14 | Improvements in or relating to the printing of cotton |
Publications (1)
Publication Number | Publication Date |
---|---|
GB343102A true GB343102A (en) | 1931-02-16 |
Family
ID=10218108
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2484329A Expired GB343102A (en) | 1929-08-14 | 1929-08-14 | Improvements in or relating to the printing of cotton |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB343102A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE864989C (en) * | 1950-07-18 | 1953-01-29 | Schroers Co Textilausruest | Process for the production of highly dispersed Kuepen dyes in the form of Kuepen acids |
-
1929
- 1929-08-14 GB GB2484329A patent/GB343102A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE864989C (en) * | 1950-07-18 | 1953-01-29 | Schroers Co Textilausruest | Process for the production of highly dispersed Kuepen dyes in the form of Kuepen acids |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB997017A (en) | Water-insoluble azo and phthalocyanine dyestuffs and containing mercapto groups and process for their manufacture and use | |
GB422488A (en) | Process of printing textile materials | |
GB343102A (en) | Improvements in or relating to the printing of cotton | |
US1987583A (en) | Sulphur dyestuff preparation | |
US2302753A (en) | Printing of ester salts of leuco | |
US1989784A (en) | Tfd statfs patfnt office | |
US2063147A (en) | Vat or sulphur dyestuff | |
US2147635A (en) | Dyestuff pastes and process for applying the same | |
US2074150A (en) | Vat dye assistants and method of using | |
GB373212A (en) | Improvements in or relating to cotton printing by means of sulphur dyestuffs | |
GB372828A (en) | Improvements in or relating to the printing of cotton | |
US2008966A (en) | Process and composition for applying and fixing dyestuff | |
US2003641A (en) | Printing of textile fabrics with vat | |
GB420095A (en) | The manufacture of vat and sulphur dyestuff preparations for textile printing | |
US2503300A (en) | Development of sulfuric acid esters of leuco vat dyes using hydroxylammonium salts | |
GB529140A (en) | Improvements in dyeing or printing with anthraquinone derivatives | |
GB535668A (en) | Improvements in printing fabrics of natural silk | |
GB511424A (en) | Improved process for printing textile materials | |
GB343597A (en) | Improvements in or relating to the printing of cotton | |
GB380860A (en) | Improvements in or relating to textile printing by means of vat dyestuff preparations | |
GB371836A (en) | Improvements in or relating to the manufacture of vat dyestuff preparations for textile printing | |
BERTHOLD et al. | Other Classes | |
GB344964A (en) | Improvements in dyeing and printing by means of vat-dyestuffs | |
GB614600A (en) | Improvements in the colouration of textile materials | |
GB544636A (en) | Production of colour resists under aniline-black |