GB253911A - Manufacture of cyclic hydrocarbons and derivatives thereof - Google Patents
Manufacture of cyclic hydrocarbons and derivatives thereofInfo
- Publication number
- GB253911A GB253911A GB15039/26A GB1503926A GB253911A GB 253911 A GB253911 A GB 253911A GB 15039/26 A GB15039/26 A GB 15039/26A GB 1503926 A GB1503926 A GB 1503926A GB 253911 A GB253911 A GB 253911A
- Authority
- GB
- United Kingdom
- Prior art keywords
- air
- carbinol
- reducing
- arylmethanes
- methylanthracene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B3/00—Dyes with an anthracene nucleus condensed with one or more carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
- C07C2603/24—Anthracenes; Hydrogenated anthracenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
253,911. I. G. Farbenindustrie Akt.- Ges., (Assignees of Farbwerke vorm. Meister. Lucius, & Br³ning). June 22, 1925, [Convention date]. Addition to 251,270. Cyclic hydrocarbons, carbinols.-The process of the parent Specification is modified in the following ways (a) the vapours of aromatic alcohols or mixed aliphatic-aromatic alcohols, containing a methyl or methylene group in the o-position to the carbinol group, are subjected to ring closure by passage over a heated highly porous body; instead of the alcohols their derivatives such as ethers or esters may be employed; oxygen, air, or an agent which yields oxygen such as a nitro derivative, may be mixed with the alcohol vapour and an oxidation catalyst may be added to the contact mas ; (b) di- or tri-arylmethanes containing a methyl or methylene group in the o-position to the methane carbon are subjected to ring closure by passing their vapours over a heated contact mass in presence of an oxidizing agent and in the presence or not of an oxygencarrier. According to examples the following hydrocarbons are prepared:- (1) #-methylanthracene from m-xylylpbenylcarbinol or its acetate and air in the presence of active charcoal made as described in Specification 201,163, [Class 55 (ii) Gas manufacture &c.] ; (2) 1 : 4 : 6- trimethylanthracene from di-p-xylylcarbinol and air in presence of active charcoal containing copper and cobalt oxides; (3) #-methylanthracene from m-xylylphenylmethane vapour and air in presence of active carbon containing oxides of manganese and cobalt. The Specification as open to inspection under Sect. 91 (3) (a.) is not limited to the treatment of the di- and tri-arylmethanes in presence of air or an oxidizing agent; it also describes the preparation of the following compounds (1) 1 : 3- dimethyl-7 : 8-benzanthracene from the carbinol obtained by reducing a-naphthoylmesitylene; (2) an acenaphthanthracene from the carbinol made by reducing 5-(0-toluoyl)- acenaphthene; in this case the reaction is carried out under diminished pressure; (3) 1:2:7: 8-dibenzanthracene from the carbinol made by reducing a-naphthoyl-2- methylnaphthalene using silica gel as the contact material. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE253911X | 1925-06-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB253911A true GB253911A (en) | 1927-08-18 |
Family
ID=5955463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB15039/26A Expired GB253911A (en) | 1925-06-22 | 1926-06-15 | Manufacture of cyclic hydrocarbons and derivatives thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB253911A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2889381A (en) * | 1955-08-22 | 1959-06-02 | Ici Ltd | Manufacture of anthracenes |
-
1926
- 1926-06-15 GB GB15039/26A patent/GB253911A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2889381A (en) * | 1955-08-22 | 1959-06-02 | Ici Ltd | Manufacture of anthracenes |
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