GB2490835A - Pyrolysis of biomass - Google Patents

Pyrolysis of biomass Download PDF

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Publication number
GB2490835A
GB2490835A GB1215219.5A GB201215219A GB2490835A GB 2490835 A GB2490835 A GB 2490835A GB 201215219 A GB201215219 A GB 201215219A GB 2490835 A GB2490835 A GB 2490835A
Authority
GB
United Kingdom
Prior art keywords
pyrolysis
biomass material
char
product
binding agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB1215219.5A
Other versions
GB201215219D0 (en
Inventor
Rodney Taylor
Lee Mcmahon
Garth Philip Wilton Way
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Energy Environmental Ltd
Original Assignee
Energy Environmental Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Energy Environmental Ltd filed Critical Energy Environmental Ltd
Publication of GB201215219D0 publication Critical patent/GB201215219D0/en
Publication of GB2490835A publication Critical patent/GB2490835A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B19/00Heating of coke ovens by electrical means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122Incoherent waves
    • B01J19/129Radiofrequency
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/34Other details of the shaped fuels, e.g. briquettes
    • C10L5/36Shape
    • C10L5/363Pellets or granulates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/08Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • C10L9/083Torrefaction
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/10Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of field or garden waste or biomasses
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K1/00Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/30Pyrolysing
    • F23G2201/302Treating pyrosolids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/30Pyrolysing
    • F23G2201/303Burning pyrogases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2203/00Furnace arrangements
    • F23G2203/20Rotary drum furnace
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2204/00Supplementary heating arrangements
    • F23G2204/20Supplementary heating arrangements using electric energy
    • F23G2204/203Microwave
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/10Waste heat recuperation reintroducing the heat in the same process, e.g. for predrying
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Thermal Sciences (AREA)
  • Electromagnetism (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A method of treating biomass material, particularly plant - derived biomass material, to produce pyrolysis thereof, comprising subjecting the biomass material to radio frequency electromagnetic radiation, e.g. microwave radiation, while the material is being agitated, under suitable conditions to produce a desired degree of pyrolysis. The pyrolysis temperature is between about 70 °C and 175 °C (torrefaction). Char solid product obtained by the process, use thereof as feedstock for a coal -fired power station. The application also pertains to a compressed char product, which can be prepared by further processing the char solid product by mixing with a binding agent, such as starch binding agent, and compressing the mixture to form compressed product.
GB1215219.5A 2010-03-04 2011-03-01 Pyrolysis of biomass Withdrawn GB2490835A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1003587.1A GB201003587D0 (en) 2010-03-04 2010-03-04 Pyrolysis of biomass
PCT/GB2011/050405 WO2011107789A2 (en) 2010-03-04 2011-03-01 Pyrolysis of biomass

Publications (2)

Publication Number Publication Date
GB201215219D0 GB201215219D0 (en) 2012-10-10
GB2490835A true GB2490835A (en) 2012-11-14

Family

ID=42136452

Family Applications (2)

Application Number Title Priority Date Filing Date
GBGB1003587.1A Ceased GB201003587D0 (en) 2010-03-04 2010-03-04 Pyrolysis of biomass
GB1215219.5A Withdrawn GB2490835A (en) 2010-03-04 2011-03-01 Pyrolysis of biomass

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GBGB1003587.1A Ceased GB201003587D0 (en) 2010-03-04 2010-03-04 Pyrolysis of biomass

Country Status (8)

Country Link
US (1) US20120324785A1 (en)
EP (1) EP2542649A2 (en)
KR (1) KR20130050281A (en)
BR (1) BR112012022133A2 (en)
CA (1) CA2700104A1 (en)
GB (2) GB201003587D0 (en)
MX (1) MX2012010137A (en)
WO (1) WO2011107789A2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ596549A (en) * 2011-11-21 2014-05-30 Carbonscape Ltd Apparatus and method for processing biomass
US20130276363A1 (en) * 2012-04-23 2013-10-24 Enginuity Worldwide, Inc. Moisture Resistant Biomass Fuel Compact and Method of Manufacturing
WO2013163127A1 (en) * 2012-04-23 2013-10-31 Enginuity Worldwide, LLC Moisture resistant biomass fuel compact and method of manufacturing
IN2014KN02959A (en) * 2012-06-22 2015-05-08 Suganit Systems Inc
WO2014043051A1 (en) * 2012-09-11 2014-03-20 D4 Energy Group Process and device for devolatizing a feedstock
WO2014152931A1 (en) * 2013-03-15 2014-09-25 Enginuity Worldwide, LLC Moisture resistant biomass fuel compact and method of manufacturing
KR101580621B1 (en) * 2013-10-24 2015-12-28 부산대학교 산학협력단 Bio-coal Using Algae and Method for Manufacturing the Same
CZ2014546A3 (en) * 2014-08-15 2016-01-27 TESORO Spin off, s.r.o. Process for producing biocarbon-based formulation for plant growth incentive
EP3256421A4 (en) * 2015-02-13 2018-08-08 CarbonScape Limited Graphite production from biomass
CN104891765A (en) * 2015-05-22 2015-09-09 成都恩承油气有限公司 Material drying and thermolysis method
CN107227160B (en) * 2017-07-10 2018-03-02 许可 A kind of continuous garbage disposal furnace based on magnetic energy carbonization
AU2022209700A1 (en) * 2021-01-21 2023-09-07 Carbon Technology Holdings, LLC Processes for producing biocarbon pellets with adjustable grindability index
CN112899005A (en) * 2021-03-23 2021-06-04 南宁学院 Carbonization treatment method for biomass material
CN113061446B (en) * 2021-04-08 2022-05-17 广东康帝绿色生物科技有限公司 Machine-made environment-friendly carbon based on camellia oleifera shells and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3843457A (en) * 1971-10-14 1974-10-22 Occidental Petroleum Corp Microwave pyrolysis of wastes
GB2448531A (en) * 2007-04-19 2008-10-22 Coal Products Ltd Fuel briquette
WO2010001137A2 (en) * 2008-07-04 2010-01-07 University Of York Microwave torrefaction of biomass

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04350408A (en) 1991-05-29 1992-12-04 Shin Meiwa Ind Co Ltd Waste material treatment equipment
US7101464B1 (en) * 1997-05-09 2006-09-05 The Tire Chief, Inc. Microwave pyrolysis apparatus for waste tires
US7301060B2 (en) * 2003-03-28 2007-11-27 Ab-Cwt, Llc Process for conversion of organic, waste, or low-value materials into useful products
US8585786B2 (en) * 2006-03-31 2013-11-19 Coaltek, Inc. Methods and systems for briquetting solid fuel
US8585788B2 (en) * 2006-03-31 2013-11-19 Coaltek, Inc. Methods and systems for processing solid fuel
US8466332B1 (en) * 2011-12-21 2013-06-18 Climax Global Energy Method and apparatus for microwave depolymerization of hydrocarbon feedstocks

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3843457A (en) * 1971-10-14 1974-10-22 Occidental Petroleum Corp Microwave pyrolysis of wastes
GB2448531A (en) * 2007-04-19 2008-10-22 Coal Products Ltd Fuel briquette
WO2010001137A2 (en) * 2008-07-04 2010-01-07 University Of York Microwave torrefaction of biomass

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
BUDARIN V L ET AL, "THE PREPARATION OF HIGH-GRADE BIO-OILS...", 1 DECEMBER 2009, BIORESOURCE TECHNOLOGY, ELSEVIER BV, VOL100, NO.23 P 6064-6068. *
HORST-GUNTER BROCKSIEPE, "CHARCOAL", ULLMANN'S ENCYCLOPEDIA OF INDUSTRIAL CHEMISTRY, ELECTRONIC RELEASE, 15 JUNE 2000, P1-6. *
JAMES R ARCATE, "GLOBAL MARKETS AND TECHNOLOGIES...", 1 JULY 2002, WOOD ENERGY, ITBE, P26-28 *

Also Published As

Publication number Publication date
US20120324785A1 (en) 2012-12-27
KR20130050281A (en) 2013-05-15
BR112012022133A2 (en) 2016-10-25
GB201003587D0 (en) 2010-04-21
WO2011107789A2 (en) 2011-09-09
CA2700104A1 (en) 2011-09-04
WO2011107789A3 (en) 2011-10-20
MX2012010137A (en) 2012-11-30
EP2542649A2 (en) 2013-01-09
GB201215219D0 (en) 2012-10-10

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