GB2483335A - Method of manufacturing recyclable mineral paper - Google Patents
Method of manufacturing recyclable mineral paper Download PDFInfo
- Publication number
- GB2483335A GB2483335A GB1113597.7A GB201113597A GB2483335A GB 2483335 A GB2483335 A GB 2483335A GB 201113597 A GB201113597 A GB 201113597A GB 2483335 A GB2483335 A GB 2483335A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sheet
- machine
- paper
- extension
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 39
- 239000011707 mineral Substances 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 46
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000000470 constituent Substances 0.000 claims abstract description 27
- 230000006835 compression Effects 0.000 claims abstract description 25
- 238000007906 compression Methods 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 238000007493 shaping process Methods 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 11
- -1 polypropylene Polymers 0.000 claims abstract description 10
- 239000004743 Polypropylene Substances 0.000 claims abstract description 9
- 229920001155 polypropylene Polymers 0.000 claims abstract description 9
- 238000003825 pressing Methods 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims description 29
- 238000000576 coating method Methods 0.000 claims description 29
- 239000004698 Polyethylene Substances 0.000 claims description 15
- 229920000573 polyethylene Polymers 0.000 claims description 15
- 239000004626 polylactic acid Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 8
- 238000004804 winding Methods 0.000 claims description 6
- 238000009966 trimming Methods 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 3
- 238000003851 corona treatment Methods 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- 238000007590 electrostatic spraying Methods 0.000 claims description 2
- 238000010285 flame spraying Methods 0.000 claims description 2
- 238000004898 kneading Methods 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000007750 plasma spraying Methods 0.000 claims description 2
- 238000004381 surface treatment Methods 0.000 claims description 2
- 230000004927 fusion Effects 0.000 claims 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 24
- 229910000019 calcium carbonate Inorganic materials 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 6
- 229920000747 poly(lactic acid) Polymers 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 231100000167 toxic agent Toxicity 0.000 description 4
- 239000003440 toxic substance Substances 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 235000012054 meals Nutrition 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910052570 clay Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 150000002605 large molecules Chemical class 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/36—Inorganic fibres or flakes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
A method is provided for manufacturing recyclable mineral paper, which has a composition comprising 60-85wt% natural inorganic mineral powders, 5-40wt% polypropylene (PP), and 1-5wt% assisting agents, through the following steps: feeding and mixing of the constituents of the composition; stirring and mixing the composition; pressing to cause bi-directional extension of the composition so as to form a sheet; subjecting the sheet to operation of a high density squeezing machine for further mixing and pressing the sheet; turning and shaping the sheet using a five-roller compression and extension machine for further extension of the sheet; and continuous compression and extension of the sheet to induce further bi-directional extension of the sheet in both lateral and longitudinal direction and to control thickness of the sheet.
Description
TITLE: METHOD FOR MANUFACTURING RECYCLABLE
MINERAL PAPER
(a) Technical Field of the Invention
The present invention generally relates to a method for manufacturing recyclable mineral paper, which comprises a paper composition containing 60-85wt% natural inorganic mineral powders, 15-4Owt% polypropylene (PP) (which comprises a mixture of polylactic acid (PLA) or PP and polyethylene (PE)) and I-Swt% assisting agents and is made with a continuous compression molding process, whereby the paper so made is recyclable and only consumes PP, which is of a small fraction, in combustion so as not to generate high temperature, smoke, and toxicant gases and to allow the residuals that are primarily the natural inorganic minerals that are of a major fraction to return to the earth and the nature after combustion.
(b) Description of the Prior Art
Various types of synthetic paper are available in the international market and one that is made in the form of single-layer or multi-layer structure with a primary constituent of polypropylene (PP), as well as a filling substance of inorganic mineral powders, is conventionally made of a formula of thin-film plastic products. The manufacture is often done with a single layer or multiple layer co-extrusion through a flat nozzle of a shaping mold to form a thin sheet. The paper sheet, which is subjected to longitudinal stretching, receives additional sheets bonded to opposite surfaces thereof or laminated therewith, and is then further subjected lateral stretching. The synthetic paper so made is a multi-layer synthetic paper, which comprises a core layer that is stretched in two directions and surface layers that are stretched in only one direction.
The synthetic paper, either single-layered or multi-layered, which is made by subjecting a paper sheet first to longitudinal stretching and then lateral stretching, has a surface that shows bi-directional extendibility The synthetic paper so made, although being advantageous in certain respects, is still of great difference from the performance of pulp paper. Disadvantages of the synthetic paper include: poor foldability great difference between longitudinal tearability and lateral tearability, or excessive or insufficient tearability.
Further, the synthetic paper that is made of a primary constituent of PP is not oxidized and decomposed in the nature in a short period pf time after being disposed, so that it does not help in reducing secondary pollution. Furthei the cost for manufacturing the synthetic paper is much higher than regular pulp paper. Due to such drawbacks, the synthetic paper has been of no appealing and attraction to the consumers.
SUMMARY OF THE INVENTION
In view of the previously discussed problems of the conventional technology, the present invention aims to provide a method for manufacturing recyclable mineral paper in order to overcome the problem that a conventional synthetic paper that is made of a primary constituent of PP cannot be oxidized and decomposed in the nature in a short period of time after being disposed of and thus cannot reduce secondary pollution, as well as the problem that the conventional synthetic paper must be made with a much higher cost with the regular pulp paper.
An objective of the present invention is to provide a method for manufacturing recyclable mineral paper, of which the composition comprises 60-85wt% natural inorganic mineral powders, l5-4Owt% polypropylene (PP) (which comprises a mixture of polylactic acid (PLA) or PP and polyethylene (PE)), and l-Swt% assisting agents and is made with a single-layer continuous compression molding process, which comprises the following steps: Step one: constituents of the composition are automatically fed and mixed according to the ratios of the constituents; Step two: continuous mixture and stirring are performed to realize uniform mixture of the compositional constituents; Step three: combined pressing is performed to cause bi-dlirectional extension of the compositional constituents to form a sheet in a bonded condition; Step four: the sheet is passed through a high density squeezing machine for further mixing and pressing of the sheet; Step five: a five-roller compression and extension machine is used to compress and extend the sheet so as to realize bi-directional extension in both lateral and longitudinal directions; Step six: a cooling and shaping machine is used to perform continuous compression and extension on the sheet to induce further bi-directional extension in both lateral and longitudinal direction in order to control thickness of the sheet; Step seven: a roll-winding machine is used to automatically roll the sheet up; and Step eight: a trimming machine is used to trim the sheet into a planar piece of paper of a desired size.
In this process, if the desired form of final paper product is a roll, then the eighth step can be omitted. The paper made in this way, after being used, can be recycled for regeneration and only the constituent of PP, which is of a minor fraction, will be consumed in combustion, so as not to generate high temperature, smoke, and toxicant gases and to allow the residuals that are primarily the natural inorganic minerals that arc of a major fraction to return to the earth and the nature afier combustion, making the present invention perfectly fit to the requirement of environmental protection.
Mother objective of the present invention is to provide a method for manufacturing recyclable mineral papei; which has a ratio between longitudinal tensile strength and lateral tensile strength of 1:1 to 1:2, or 2:1 to 1:1, or 1:2 to 1:3 and a ratio between longitudinal tear strength and lateral tear strength of 1:1 to 1:2, or2:l to 1:1, or 1:2 to 1:3, andeomprises aprimary constituent of at most 85wt% natural inorganic mineral powders (including calcium carbonate (light calcium carbonate, heavy calcium carbonate, colloid calcium carbonate, active heavy calcium carbonate), pulverized coal powder, calcium sulfate, barium sulfate, kaolin, mica powder, zinc oxide, dolomite powder, calcium silicate, glass fiber hollow micro-particle of glass, silica powder, chalk powder, talcum powder, pigment, titanium dioxide, silicon dioxide, bentonite, clay, diatomite, and mixtures thereof, being subjected to calcination or not), together with l5-4Owt% PP (including a combination of PP and low density PE, ethylene vinyl acetate (EVA), and polylactic acid (PLA)), and l-Swt% assisting agents (including solid softening agent, activating agent, promotel; aging prevention agent, scorch prevention agent, bonding agent, heat resisting agent, initiator agent, polymerization catalyst, dispersing agent, emulsifying agent, plasticizer, heat/light stabilizer, fire retardant, mold release agent, decomposable substances (which can be starch (such as soybean powder, corn meal1, casaval meal and the likes)), chitin, S polycaprolactone, modified aromatic polyesters, and the likes).
A further objective of the present invention is to provide a method for manufacturing recyclable mineral papei; which has a composition comprising 60-8Swt% natural inorganic mineral powders, l5-4Owt% PP (which comprises a mixture of PLA or PP and PE) and l-Swt% assisting agents and which shows improved characteristics over the regular pulp paper in respect of foldability, stiffness, levelabilit opaqueness, glossiness, and writability of ball pen, pencil, and water-based pens, and printing resolution, and has longitudinal and lateral tear strengths and tensile strength close to the regular pulp paper, and also shows the characteristics of water resistance, improved strength, perforation resistance, wear resistances, fold resistance, and verniln-eatmg resistance.
Yet a further objective of the present invention is to provide a method for manufacturing recyclable mineral paper, which has a composition comprising 60-85wt% natural inorganic mineral powders, 1S-4Owt% PP (which comprises a mixture of PLA or PP and PE) and l-Swt% assisting agents, whereby depending upon the assisting agents used, the paper can be biodegradable, which is decomposed in the nature by microorganisms into carbon dioxide and water, or photo-degradable, which can be decomposed by exposure to ultraviolet components contained in the sun light to have main chains of large molecules thereof broken, or oxidation decomposable, which is decomposed through oxidation of the constituent materials thereof with oxygen to form oxides. Thus, the disposed paper can be returned to the earth, generates no toxicant gas or cause water pollution, so as to completely meet the requirement for environmental protection.
The foregoing objectives and summary provide only a brief introduction to the present invention. To fully appreciate these and other objects of the present invention as well as the invention itseif all of which will become apparent to those skilled in the art, the following detailed description of the invention and the claims should be read in conjunction with the accompanying drawings. Throughout the specification and drawings identical reference numerals refer to identical or similar parts.
Many other advantages and features of the present invention will become manifest to those versed in the art upon making reference to the detailed description and the accompanying sheets of drawings in which a preferred structural embodiment incorporating the principles of the present invention is shown by way of illustrative example.
BRIEF DESCRiPTION OF THE DRAWINGS
FIG 1 is a schematic view showing a compression and extension paper making device according to the present invention.
FIG 2 is a schematic view showing an automatic metering machine according to the present invention.
FIG 3 is a schematic view showing an automatic stirring and mixing machine according to the present invention.
FIG 4 is a schematic view showing a combined sheet forming machine according to the present invention.
FIG 5 is a schematic view showing a high-density squeezing machine according to the present invention.
FIG 6 is a schematic view showing a five-roller compression and extension machine according to the present invention.
FIG 7 is a schematic view showing a cooling and shaping machine according to the present invention.
FIG 8 is a schematic view showing an automatic roll-winding machine according to the present invention.
FIG 9 is a schematic view showing a trinintg machine according to the present invention. I0
FIG 10 is a schematic view showing a dual-side coating machine according to the present invention.
FIG 11 is a schematic view showing an automatic leveling machine according to the present invention.
FIG 12 is a schematic view showing a front surface coating machine according to the present invention.
FIG 13 is a schematic view showing a dry type baking oven according to the present invention.
FIG 14 is a schematic view showing a back surface coating machine according to the present invention.
FIG 15 is a schematic view showing a paper rolling machine according to the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
The following descriptions are exemplary embodiments only, and are not intended to limit the scope, applicability or configuration of the invention in any way. Rather, the following description provides a convenient illustration for implementing exemplary embodiments of the invention. Various changes to the described embodiments may be made in the function and arrangement of the elements described without departing from the scope of the invention as set forth in the appended claims.
Referring to FIGS. 1-9, the present invention provides a method for manufacturing recyclable mineral paper, which has a composition comprising 60-85wt% natural inorganic mineral powders (such as calcium carbonate (including light calcium carbonate, heavy calcium carbonate, eolloid calcium carbonate, active heavy calcium carbonate), pulverized coal powder, calcium sulfate, barium sulfate, kaolin, mica powder, zinc oxide, dolomite powder, calcium silicate, glass fiber, hollow micro-particle of glass, silica powder, chalk powder, talcum powder, pigment, titanium dioxide, silicon dioxide, bentonite, clay, diatomite, and mixtures thereof (which is or is not subjected to ealcination)) as a primary constituent; 15-4Owt% polypropylene (PP) (which comprises a mixture of polylactie acid (PLA) or PP and polyethylene (PE)); and 1-Swt% assisting agents. The material of PP used may comprise a combination of PP and low density PE, ethylene vinyl acetate (EVA), and PLA. The assisting agents may include one or more of coupling agent, slipping agent (dispersing agent), anti-static agent, solid softening agent, activating agent, promoter, aging prevention agent, scorch prevention agent, bonding agent, heat resisting agent, initiator agent, polymerization catalyst, dispersing agent, eniulsifying agent, plasticizer, heat/light stabilizer, fire retardant, and mold release agent. The coupling agent may include di(dioctyl phosphate)ethylene and/or 13-{3,4-epoxyeyclohexyl)ethyltrimethoxysilane).
The slipping agent may include gelatin and/or methyl cellulose. The anti-static agent may include octadecyldiethanolaminc.
The composition of the mineral paper does not need to be processed for formation of raw material mother particles and, instead, can be directly deposited into a compression and extension paper making device 10.
(Trimmed residuals may also be directly fed back to the machine for compression and extension, so that no waste may be generated.) The compression and extension paper making device 10 comprises an automatic metering machine 11, an automatic stirring and mixing machine 12, a combined sheet forming machine 13, a high-density squeezing machine 14, a five-roller compression and extension machine 15, a cooling and shaping machine 16, an automatic roll-winding machine 17, and a trimming machine 18. The manufacturing method comprises the following steps: Step one: the automatic metering machine 11 performs automatic feeding and mixing of the constituents of the composition according to the ratios of the constituents to be then supplied to the automatic stirring and mixing machine 12; Step two: the automatic stirring and mixing machine 12 performs continuous mixture and stirring of the composition to realize uniform mixture of the compositional constituents; Step three: the well mixed composition is then directly fed to the combined sheet forming machine 13 to be subjected to combined pressing so as to cause bi-directional extension of the compositional constituents and uniform mbbing and kneading to form a sheet of the compositional constituents in a bonded condition; Step four: the uniformly mbbed arid kneaded sheet is passed through the high density squeezing machine 14 for fuñiher mixing and pressing the sheet, so as to provide the sheet with proper hardness and proper tension; Step five: the five-roller compression and extension machine 15 is used for reversely turning and shaping the sheet and to realize bi-directional extension of the sheet in both lateral and longitudinal directions; Step six: the cooling and shaping machine 16 is used to perform continuous compression and extension on the sheet to induce further hi-directional extension of the sheet in both lateral and longitudinal direction and to control thickness of the sheet; Step seven: the roll-winding machine 17 is used to automatically roll the paper sheet up in the form of a paper roll; and Step eight: the trimming machine 18 is used to trim the paper sheet into a planar piece of paper of a desired size.
As such, the composition of paper according to the present invention comprises 60-85wt% natural inorganic mineral powders, 15-4Owt% PP (which comprises a ntture of PLA or PP and PE) and l-5wt% assisting agents, whereby depending upon the assisting agents used, the paper can be biodegradable, which is decomposed in the nature by microorganisms into carbon dioxide and water, or photo-degradable, which can be decomposed by exposure to ultraviolet components contained in the sun light to have main chains of large molecules thereof broken, or oxidation decomposable, which is decomposed through oxidation of the constituent materials thereof with oxygen to form oxides. Thus, any disposed paper can be recycled for regeneration and only the constituent of g which is of a minor fraction, will be consumed in combustion, so as not to generate high temperature, smoke, and toxicant gases and to allow the residuals that are primarily the natural inorganic minerals that are of a major fraction to return to the earth and the nature after combustion, making the present invention perfectly fit to the requirement of environmental protection. Further, the composition of the mineral paper according to the present invention can be automatically fed and metered according to the ratios of the constituent components thereof and requiring no formation of particles, which leads to a reduction of cost for mixture of the components and formation of raw material mother particles.
The five-roller compression and extension machine 15 used in the fifth step is operated by employing high temperature compression and extension and the temperature employed can be adjusted according to the characteristics of the composition formula of the desired mineral paper so as to effectively realize melting, mixture, and bi-directional extension of the composition of mineral paper. The cooling and shaping machine 16 used in the sixth step is adjustable for compression time according to the desired thickness and product property of the mineral paper. Th the previous process, if the desired form of final paper product is a paper roll, then the eighth step can be omitted.
In an embodiment of the method for manufacturing recyclable mineral paper according to the present invention, the composition of the mineral paper comprises 73w1% calcium carbonate, 1 7wt% PP, 7wt% low density PE, lwt% coupling agent OL-T95 1, lwt% stearic acid, lwt% other assisting agents.
All these constituents adding together are lOOwt%, and are subjected to mixture, squeezing, and compounding, and then deposited into the compression and extension paper making device 10 for manufacture of recyclable paper sheets of a thickness of 0.1mm according to the desired product thickness.
In another embodiment of the method for manufacturing recyclable mineral paper according to the present invention, the composition of the mineral paper comprises 72wt% talcum powder, l7wt% PP, 8wt% low density PE, lwt% coupling agent NDZ-101, lwt% calcium stearate, lwt% other assisting agents.
All these constituents adding together are lOOwt%, and are subjected to mixture, squeezing, and compounding, and then deposited into the compression and extension paper making device for manufacture of recyclable paper sheets of a thickness of 0.3mm according to the desired product thickness.
Further, according to paper thickness and property, the mineral paper made according to the method of the present invention can be used, afier further and proper processing, to make monthly calendar, almanac, hanging scroll, map, notebook, instruction leaflet, business log, letter paper, book1 commercial marks, poster, label, various hand-canying bags, wrapping paper, art and craft material, wall paper, surface cover for woven bag, release paper, heat-sealing package bag, backing adhesive label paper, surface bonding material, atlas, self-adhesive mark, surface bonding material for plastic tablet, shopping bag, various hand bags, wall paper, newspaper and loose leaf paper, notebook, book, desk calendar, envelope, sitning paper, instmction leaflet, education material, festival and celebration card, three-dimensional cards, playing cards, business card, name plate, hanging card, painting, book cover, various package boxes, shoe box, cigarette box, tea leaf box, meal pad, window curtain, hanging plate, frozen foodstuff plate for food package, disposable dining utensil, meal box, sun shade for automobile, art lantern decoration, frozen commodity indication plate for convenience stores, three-dimensional paper sculpture, coupon, scoring card, product catalog, cup coaster, plastic floor tile, large-sized advertisement, lantem box advertisement, as well as paper for culture purposes, such as paper for culture purposes, paper for printing, paper for writing, and paper for computer character making, and paper for decoration purposes and paper for packaging purposes. The paper can be used directly and thither processing is perfornTied to make a coating on a surface of the paper to form a frosted surface or a shining surface.
Referring to FIGS. 10-15, the recyclable mineral paper according to the present invention can be processed to form a coating layer on a surface thereof, and the coating can be formed of a water-based solution or an oil-based solution. For the case where a water-based solution is used to form the coating, the composition of the water-based coating solution may comprise acrylic resin, isoprophy alcohol, polyvinyl alcohol, clay, anti-static agent, 28% ammonia liquor, pure water, and vinyl acetate. A dual-side coating machine is used to deposit a non-coated paper sheet into an automatic leveling machine 21 to have the sheet dragged and leveled for subsequent performance of corona treatment, whereby the two surfaces of the paper sheet, after being treated with high voltage discharging, form a plurality of tiny voids, which help improving bonding force for the coating applied to the surface (the surface treatment being selectively thermal ifision coating, fluent spraying, flame spraying, plasma spraying, and electrostatic spraying). The paper IS sheet is conveyed to a front surface coating machine 22 for initial coating, and then the paper sheet is conveyed to a dry type baking oven 23 to have the surfaces thereof dried for subsequent coating on the opposite surface. A back surface coating machine 24 uses a plurality of spraying nozzles to control the amount of coating solution sprayed and realize coating on the opposite surface.
The paper sheet is then conveyed to the dry type baking oven 23 to dry the coated surface, whereby under the condition of being heated, the coated surface of the paper sheet can be quickly dried and shows a shining face on the paper surface. Further, for frosting treatment of the coated surface of the paper sheet, a frosting roller is employed to compress the paper sheet so that the dried smooth coated surface of the paper sheet is converted into a frosted surface. Then, a paper rolling machine 25 is used to roll up the coated paper sheet into a paper roll.
It will be understood that each of the elements described above, or two or more together may also find a useful application in other types of methods differing from the type described above.
While certain novel features of this invention have been shown and described and are pointed out in the annexed claim, it is not intended to be limited to the details above, since it will be understood that various omissions, modifications, substitutions and changes in the forms and details of the device illustrated and in its operation can be made by those skilled in the art without departing in any way from the spirit of the present invention.
Claims (6)
- I CLAIM: 1. A method for manufacturing recyclable mineral paper, which has a composition comprising 60-85wt% natural inorganic mineral powders, 5-4Owt% polypropylene (PP) (which comprises a ntture of polylactic acid (PLA) or PP and polyethylene (PE)),and l-Swt% assisting agents, wherein the composition of the mineral paper does not need to be processed for formation of raw material mother particles and is directly deposited into a compression and extension paper making device, which comprises an automatic metering machine, an automatic stirring and mixing machine, a combined sheet forming machine, a high-density squeezing machine, a five-roller compression and extension machine, and a cooling and shaping machine, the method comprising the following steps: step one: the automatic metering machine performs automatic feeding and mixing of the constituents of the composition according to the ratios of the constituents to be then supplied to the automatic stirring and mixing machine; step two: the automatic stirring and mixing machine performs continuous mixture and stirring of the composition to realize uniform mixture of the compositional constituents; step three: the well mixed composition is then directly fed to* the combined sheet forming machine to be subjected to combined pressing so as to cause bi-directional extension of the compositional constituents and uniform rubbing and kneading to form a sheet of the compositional constituents in a bonded condition; step four: the uniformly rubbed and kneaded sheet is passed through the high density squeezing machine for further mixing and pressing the sheet, so as to provide the sheet with proper hardness and proper tension; step five: the five-roller compression and extension machine is used for reversely turning and shaping the sheet and to realize bi-directional extension of the sheet in both lateral and longitudinal directions; and step six: the cooling and shaping machine is used to perform continuous compression and extension on the sheet to induce further bi-directional extension of the sheet in both lateral and. longitudinal direction and to control thickness of the sheet.
- 2. The method according to claim 1, wherein the compression and extension paper making device further comprises an automatic roll-winding machine and a trimming machine, whereby the sheet formed in step six is wound by using the automatic roll-winding machine and the trimmed to a planar piece of paper of desired size by the trimming machine.
- 3. The method according to claim 1, wherein the five-roller compression and extension machine of step five is operated by employing high temperature compression and extension and the temperature employed is adjustable according to the characteristics of the composition of the mineral paper so as to effectively realize melting, mixture, and bi-directional extension of the composition of mineral paper.
- 4. The method according to claim 1, wherein the cooling and shaping machine of step six is adjustable for compression time according to desired thickness and product property of the mineral paper.
- 5. The method according to claim 1, wherein the sheet formed in step six is further subjected to surface coating of an oil-based coating solution.
- 6. The method according to claim 1, wherein the sheet formed in step six is further subjected to surface coating of a water-based coating solution through use of a dual-side coating machine to deposit a non-coated paper sheet into an automatic leveling machine to have the sheet dragged and leveled for subsequent performance of corona treatment, whereby two surfaces of the paper sheet, after being treated with high voltage discharging, form a plurality of tiny voids, which help improving bonding force for the coating applied to the surface (the surface treatment being selectively thermal fusion coating, fluent spraying, flame spraying, plasma spraying, and electrostatic spraying); the paper sheet is conveyed to a front surface coating machine for initial coating, and then the paper sheet is conveyed to a dry type baking oven to have the surfaces thereof dried for subsequent coating on the opposite surface; a back surface coating machine uses a plurality of spraying nozzles to control the amount of coating solution sprayed and realize coating on the opposite surface; and the paper sheet is then conveyed to the dry type baking oven to dry the coated surface, whereby under the condition of being heated, the coated surface of the paper sheet is quickly dried and shows a shining face on the paper surface.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW099129634A TWI460333B (en) | 2010-09-02 | 2010-09-02 | Recyclable stone paper manufacturing method |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB201113597D0 GB201113597D0 (en) | 2011-09-21 |
| GB2483335A true GB2483335A (en) | 2012-03-07 |
| GB2483335B GB2483335B (en) | 2012-10-31 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1113597.7A Expired - Fee Related GB2483335B (en) | 2010-09-02 | 2011-08-08 | Method for manufacturing recyclable mineral paper |
Country Status (7)
| Country | Link |
|---|---|
| AU (1) | AU2011211331B2 (en) |
| BR (1) | BRPI1103976B8 (en) |
| DE (1) | DE102011110059B4 (en) |
| FR (1) | FR2964395B3 (en) |
| GB (1) | GB2483335B (en) |
| RU (1) | RU2476632C1 (en) |
| TW (1) | TWI460333B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103132396A (en) * | 2013-02-07 | 2013-06-05 | 天津大福兄弟包装科技有限公司 | Environment-friendly stone ore fiber colorized coating liner paper |
| CN104589557A (en) * | 2014-12-30 | 2015-05-06 | 成都新柯力化工科技有限公司 | Molding process of stone paper |
| CN107696589A (en) * | 2017-10-08 | 2018-02-16 | 刘道灵 | A kind of cooling and shaping device in environmentally-friendly stone paper production embossed technology |
| US11643536B2 (en) | 2017-09-21 | 2023-05-09 | Tbm Co., Ltd. | Thermoplastic resin composition and formed article formed by using thermoplastic resin composition |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103450564B (en) * | 2013-09-03 | 2015-12-09 | 昆明钢铁控股有限公司 | Callable stone paper packaging vessel of a kind of easily degraded and preparation method thereof |
| CN105503119B (en) * | 2014-09-25 | 2018-01-30 | 国家电网公司 | A kind of stone paper and preparation method based on waste and old electric power ceramic insulator |
| ITUA20162410A1 (en) * | 2016-04-08 | 2017-10-08 | Gd Spa | Method and inspection unit of a heating element for electronic cigarette. |
| CN110761111A (en) * | 2018-07-27 | 2020-02-07 | 东加塑胶有限公司 | Oyster paper and its making method |
| CN110803882B (en) * | 2019-11-13 | 2021-11-09 | 山西宇皓环保纸业有限公司 | Method for producing stone paper by using stone paper leftover material and regenerated stone paper |
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| US6284177B1 (en) * | 1996-10-15 | 2001-09-04 | William D. Ewing | Recyclable printable media |
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- 2011-08-10 FR FR1157286A patent/FR2964395B3/en not_active Expired - Lifetime
- 2011-08-10 AU AU2011211331A patent/AU2011211331B2/en not_active Ceased
- 2011-08-10 RU RU2011133503/05A patent/RU2476632C1/en active
- 2011-08-12 DE DE102011110059.1A patent/DE102011110059B4/en not_active Expired - Fee Related
- 2011-08-29 BR BRPI1103976A patent/BRPI1103976B8/en not_active IP Right Cessation
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| EP0773094A1 (en) * | 1995-11-16 | 1997-05-14 | Nan Ya Plastics Corporation | Synthetic paper and method for its manufacture |
| US6284177B1 (en) * | 1996-10-15 | 2001-09-04 | William D. Ewing | Recyclable printable media |
| EP0945244A1 (en) * | 1998-03-25 | 1999-09-29 | Lung Meng Environmental Friendly Paper Products Hong Kong (Holdings) Limited | Process for the manufacture of environmental friendly papers and compositions therefore |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103132396A (en) * | 2013-02-07 | 2013-06-05 | 天津大福兄弟包装科技有限公司 | Environment-friendly stone ore fiber colorized coating liner paper |
| CN104589557A (en) * | 2014-12-30 | 2015-05-06 | 成都新柯力化工科技有限公司 | Molding process of stone paper |
| CN104589557B (en) * | 2014-12-30 | 2016-08-24 | 成都新柯力化工科技有限公司 | A kind of moulding process of stone paper |
| US11643536B2 (en) | 2017-09-21 | 2023-05-09 | Tbm Co., Ltd. | Thermoplastic resin composition and formed article formed by using thermoplastic resin composition |
| CN107696589A (en) * | 2017-10-08 | 2018-02-16 | 刘道灵 | A kind of cooling and shaping device in environmentally-friendly stone paper production embossed technology |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2964395A3 (en) | 2012-03-09 |
| GB201113597D0 (en) | 2011-09-21 |
| TWI460333B (en) | 2014-11-11 |
| AU2011211331B2 (en) | 2012-08-23 |
| DE102011110059A1 (en) | 2012-04-26 |
| BRPI1103976B1 (en) | 2020-04-07 |
| AU2011211331A1 (en) | 2012-03-22 |
| GB2483335B (en) | 2012-10-31 |
| TW201211352A (en) | 2012-03-16 |
| DE102011110059B4 (en) | 2017-12-28 |
| BRPI1103976B8 (en) | 2021-03-09 |
| BRPI1103976A2 (en) | 2013-01-08 |
| RU2476632C1 (en) | 2013-02-27 |
| FR2964395B3 (en) | 2012-10-05 |
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