GB2481446A - Vent head with drain returning liquid to inlet - Google Patents

Vent head with drain returning liquid to inlet Download PDF

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Publication number
GB2481446A
GB2481446A GB1010720.9A GB201010720A GB2481446A GB 2481446 A GB2481446 A GB 2481446A GB 201010720 A GB201010720 A GB 201010720A GB 2481446 A GB2481446 A GB 2481446A
Authority
GB
United Kingdom
Prior art keywords
steam
vent head
baffle
vent
head according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB1010720.9A
Other versions
GB2481446B (en
GB201010720D0 (en
Inventor
Tom Vivian
Joseph Edison Rosagro
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Spirax Sarco Ltd
Original Assignee
Spirax Sarco Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Spirax Sarco Ltd filed Critical Spirax Sarco Ltd
Priority to GB1010720.9A priority Critical patent/GB2481446B/en
Publication of GB201010720D0 publication Critical patent/GB201010720D0/en
Priority to DE102011077928.0A priority patent/DE102011077928B4/en
Priority to US13/168,106 priority patent/US8409313B2/en
Priority to CN201110271926.0A priority patent/CN102434871B/en
Priority to CN201110174076.2A priority patent/CN102297414B/en
Priority to US13/167,874 priority patent/US8425643B2/en
Publication of GB2481446A publication Critical patent/GB2481446A/en
Application granted granted Critical
Publication of GB2481446B publication Critical patent/GB2481446B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00Component parts or details of steam boilers
    • F22B37/02Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
    • F22B37/26Steam-separating arrangements
    • F22B37/30Steam-separating arrangements using impingement against baffle separators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D45/00Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/04Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia
    • B01D45/08Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia by impingement against baffle separators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00Component parts or details of steam boilers
    • F22B37/02Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
    • F22B37/48Devices for removing water, salt, or sludge from boilers; Arrangements of cleaning apparatus in boilers; Combinations thereof with boilers
    • F22B37/54De-sludging or blow-down devices

Abstract

A steam vent head comprises a chamber 26 and has an outlet 14, a steam inlet conduit 16 with a steam outlet 15 that opens into the chamber and a baffle 34 within the chamber and above the steam outlet 15, in use the steam outlet discharging steam into the chamber which impinges on the baffle 34 to separate entrained liquid water from the steam, there being drainage passageways (holes 32) between the chamber and the steam inlet conduit so that in use liquid water collected in the chamber is returned to the steam inlet conduit by the drainage passageways. The baffle has an impingement region (35, fig 4) and a convex portion (40, fig 4). One embodiment has a steam inlet conduit (16, fig 6) with increased thickness.

Description

VENT HEAD
The present invention relates to a vent head for a steam system.
In an industrial and heating process utilising steam, steam is generated in a boiler and transferred through pipework at high temperature and pressure to various industrial processes where the energy in the steam is utilised.
Some steam system components, such as blow down vessels, include open-ended steam vent pipes that are used to vent steam to the atmosphere. It is known to provide the steam vent pipes with a vent head in order to safely discharge steam to the atmosphere at a low velocity.
One type of known vent head comprises a housing containing a baffle which is arranged to intercept steam entering the housing. The baffle causes water entrained within the steam to be separated from the steam. The dry steam is then vented to the atmosphere through an outlet in the housing and the separated water is fed to a drain line where it is drained from the steam system.
Whilst such a vent head is suitable for some applications, there are a number of drawbacks associated with it. For example, it is not capable of separating all of the water that is entrained in the steam. Further, known vent heads can be time consuming to install due to the pipework connections that are necessary.
It is therefore desirable to provide an improved vent head that improves the separation of entrained water from steam and/or is less complicated to install.
According to an aspect of the present invention there is provided a vent head for a steam system, comprising: a body defining a vent head chamber and having a vent head outlet; a steam inlet conduit having a steam outlet that opens into the vent head chamber; a baffle disposed within the vent head chamber and above the steam outlet; and a drainage passageway providing fluid communication between the vent head chamber and the steam inlet conduit; wherein in use the steam outlet discharges steam into the vent head chamber which impinges on the baffle, thereby separating entrained liquid water from the steam, the liquid water being collected in the vent head chamber and returned to the steam inlet conduit via the drainage passageway.
The steam inlet conduit may extend into the vent head chamber. The drainage passageway may comprise a hole provided in the portion of the steam inlet conduit which extends into the vent head chamber. There may be a plurality of drainage passageways, each comprising a hole provided in the portion of the steam inlet conduit which extends into the vent head chamber.
The body may comprise a bottom wall which slopes downwards towards an inlet of the drainage passageway.
The steam inlet conduit may comprise an attachment portion for attaching the steam inlet conduit to an open-ended steam vent pipe. The steam outlet may be arranged such that in use the steam is discharged in a substantially vertical direction.
The baffle may be substantially horizontal in use. The baffle may be substantially planar. The baffle may be substantially circular.
The body may comprise a top wall within which the vent head outlet is provided.
The vent head outlet may be located above the baffle. The baffle may be disposed in the steam flow path between the steam outlet and the vent head outlet. When viewed from above, the baffle may extend beyond the steam outlet.
The baffle may comprise an impingement region, on which in use the steam impinges, and a convex portion disposed between the impingement region and the edge of the baffle. The impingement region may in use be substantially horizontal. The convex portion may have a radius of curvature such that in use water vapour flows around the convex portion to the vent head outlet, and water droplets are discharged from the convex portion into the vent head chamber. The radius of curvature of the convex portion may be between about 4 and 7 mm. The radius of curvature of the convex portion may be about 5 mm. The convex portion may curve upwardly in the direction away from the impingement region, and terminate at the edge of the baffle. When viewed from above, the convex portion may be located in a position beyond the steam outlet.
According to a further aspect of the present invention there is provided a steam system comprising a steam vent pipe having a vent head in accordance with any statement herein.
The invention may comprise any combination of the features and/or limitations referred to herein, except combinations of such features as are mutually exclusive.
Embodiments of the present invention will now be described, by way of example only, with reference to the accompanying drawings, in which: Figure 1 schematically shows a perspective view of a first embodiment of a vent head; Figure 2 schematically shows the vent head of Figure 1 with a section cut-away; Figure 3 schematically shows a cross-sectional view of the vent head of Figure 1; Figure 4 schematically shows two views of the baffle of the vent head of Figure 1; Figure 5 schematically shows an enlarged view of the baffle of the vent head of Figure 1;and Figure 6 schematically shows a cross-sectional view of a second embodiment of a vent head.
As shown in Figure 1, the vent head 10 comprises a body 12 that is provided with a vent head outlet 14, and a steam inlet pipe (or conduit) 16. The steam inlet pipe 16 is provided with a flange 18 that can be used to attach the vent head 10 to an open-ended steam vent pipe that supplies steam that is to be discharged, or vented, to the atmosphere.
With reference to Figures 2 and 3, the body 12 of the vent head 10 comprises a top wall 20, a bottom wall 22, and an annular side wall 24 and therefore the body 12 is substantially cylindrical. The body 12 is made from a first upper part 12a that comprises the top wall 20 and a portion of the annular side wall 24, and a second lower part 12b that comprises the bottom wall 22 and a portion of the annular side wall 24.
The upper and lower parts 12a, 12b are fitted together to form the body 12. The body 12 defines a vent head chamber 26 which is the interior of the body 12.
A steam pipe opening 28 is provided in the bottom wall 22 of the lower part 12b of the body 12 and a collar 30 axially extends from the opening 28. The steam pipe opening 28 and the collar 30 are coaxial with the substantially cylindrical body 12. The steam inlet pipe 16 is located within the opening 28 so that the collar 30 surrounds and is in contact with the outer surface of the steam inlet pipe 16. The steam inlet pipe 16 is provided with an annular shoulder 29 which the edge of the collar 30 abuts. An upper portion of the steam inlet pipe 16 projects into the vent head chamber 26 and the open end of the upper portion constitutes a steam outlet 15. A lower portion of the steam inlet pipe 16 extends outside of the body 12 and the open end of the lower portion constitutes a steam inlet 17. The end of the lower portion of the steam inlet pipe 16 is provided with the flange 18 which allows the vent head 10 to be coupled to the end of a steam outlet pipe (not shown).
The steam inlet pipe 16 is provided with four drainage holes 32 that extend through the thickness of the inlet pipe 16. The drainage holes 32 are level with the bottom wall 22 of the body 12 and are circumferentially spaced from one another by 90°. The bottom wall 22 of the body 12 slopes downwards radially inwardly towards the steam inlet pipe 16 and the drainage holes 32. The drainage holes 32 provide a drainage passageway between the vent head chamber 26 and the steam inlet pipe 16.
The vent head outlet 14 is provided in the top wall 20 of the upper part 12a of the body 12 and is coaxial with the substantially cylindrical body 12. Therefore, the vent head outlet 14 is above the steam inlet pipe outlet 15.
A baffle 34 is disposed within the vent head chamber 26 and is located above the steam outlet 15 and below the vent head outlet 14. The baffle 34 is therefore disposed between the steam outlet 15 and the vent head outlet 14. In this embodiment the baffle 34 is substantially planar and lies in a substantially horizontal plane when in use. The baffle 34 is substantially circular and is coaxial with the cylindrical body 12. The diameter of the circular baffle 12 is larger than the diameter of the steam outlet 15 and therefore, when viewed from above, the edge of the baffle 34 extend beyond the steam outlet 15. In this embodiment, the diameter of the circular baffle 34 is approximately the same as the diameter of the vent head outlet 14.
As shown in detail in Figure 4, the baffle 34 comprises a central impingement region and a convex portion 40 which curves upwards. The convex portion 40 is located between the impingement region 35 and the edge of the baffle 34. In this embodiment the convex portion 40 is the annular edge of the baffle 34 which is curved upwardly.
The radius of curvature of the convex portion 40 in this embodiment is approximately 5mm. However, the radius of curvature may be between 4 and 7 mm in other embodiments. The purpose of the convex portion 40 will be described below.
The baffle 34 is provided with three supporting members 36 that are attached to the edge of the baffle 34 and are circumferentially spaced from one another by 120°. The supporting members 36 extend in the axial direction and each supporting member 36 comprises a lip 38 that projects radially outwardly from the end of the supporting member 36. The supporting members 36 are used to attach the baffle 34 to and support the baffle 34 from the body 12. As shown in Figures 2 and 3, the lips 38 of the supporting members 36 engage with the edge of vent head outlet 14 and rest on the top wall 20 of the body 12, thereby supporting the baffle 34 from the body 12.
In use, the vent head 10 is attached to the open end of a steam vent pipe (not shown) by means of the flange 18. The steam vent pipe may be the steam vent pipe of any part of a steam system where steam is discharged, or vented, to the atmosphere.
Examples include, but are not limited to, the steam vent pipe of a blow-down vessel, a hotwell tank, a feed tank or a pressure-powered pump.
Steam is introduced into the vent head 10 through the steam inlet 17 of the steam inlet pipe 16. The steam is then discharged in a substantially vertical direction into the vent head chamber 26 from the steam outlet 15 of the steam inlet pipe 16.
As shown in Figure 5, the steam exiting the steam outlet 15 impinges on the impingement region 35 of the horizontal baffle 34 which is disposed directly above the steam outlet 15. As the steam impinges on the baffle 34, water droplets that are entrained in the steam flow adhere to the surface of the baffle due to surface tension and are therefore separated from the steam flow. Due to the pressure drop between the vent head chamber 26 and the atmosphere, the steam flows towards the vent head outlet 14 and therefore flows radially outwards over the surface of the baffle 34. The flow of steam over the surface of the baffle 34 drags the water droplets that are adhered to the surface of the baffle 34 by surface tension radially outwards over the surface of the baffle 34 towards the edge of the baffle 34.
As the steam approaches the convex portion 40 of the baffle 34 the water vapour is attracted to the convex portion 40 of the baffle 34 and therefore flows around it and exits the vent head 10 through the vent head outlet. The water vapour flows around the convex portion 40 by virtue of the Coandà effect. However, the water droplets adhered to the baffle surface are too heavy to be dragged around the convex portion by the steam flow and therefore are discharged from the convex portion 40. Since the convex portion 40 is located outside of the steam outlet 15, these water droplets are collected in the bottom of the vent head chamber 26 which is separated from the steam flow by the steam inlet pipe 16 which projects into the vent head chamber 26.
The water separated from the steam by the baffle 34 flows radially inwards along the downwardly sloped bottom wall 22 of the baffle 26 towards the steam inlet pipe 16.
The separated water then flows through the drainage holes (drainage passageway) 32 in the steam inlet pipe 16 into the interior of the pipe 16. The water is then caused to flow down the internal wall of the steam inlet pipe 16 and is returned to the steam system.
The distance h between the steam outlet 15 and the impingement region 35 of the baffle 34 is chosen so as to minimise acoustic noise generated by the steam impinging on the baffle 34, whilst still ensuring that the steam flow is directed against the centre of the baffle 34. In order to minimise noise, it is important that the area Al of the steam outlet 14 of the pipe 16 is approximately the same as the area A2 of the annular passageway between the steam outlet 14 and the baffle 34, ±10%.
The vent head 10 allows the safe discharge of steam to the atmosphere. This is because the baffle 34 slows down the velocity of the steam, and a large proportion of the water droplets entrained within the steam is separated from the steam by the baffle.
This results in substantially dry steam being discharged from the vent head outlet.
Returning the liquid water separated from the steam to the steam system provides a number of benefits. The water used in the steam system contains various treatment chemicals that help to improve the performance of the system. If water is lost from the system then it is necessary to replenish that water with fresh water which must be treated with these chemicals. Therefore, reducing the amount of water that is lost from the steam system reduces the amount of fresh treatment chemicals that must be added to the system. This provides a cost saving. Further, water lost from the steam system contains useful heat and therefore returning the liquid water separated from the steam by the baffle improves the energy efficiency of the system.
A further benefit is that it is not necessary to provide an external drain line connection to the vent head 10 since the separated water is returned to the steam system down the steam inlet pipe 16. This reduces the amount of pipework and external connections that is required and therefore results in a less expensive and a quicker installation.
The convex portion 40 of the baffle 34 extracts (or separates) more liquid water from the steam that can be achieved with conventional baffles. This is at least partly due to the Coandá effect which causes the water vapour to be attracted to and flow around the convex portion 40, whilst forcing water droplets to be discharged into the vent head chamber 26. The radius of curvature of the convex portion 40 is chosen such that the flow of water vapour across the baffle 34 is attracted to the convex portion 40 and therefore flows around it, whilst water droplets are discharged from the convex portion 40.
Figure 6 shows a second embodiment of a vent head 10. This embodiment is similar to the first embodiment except the upper portion of the steam inlet pipe 16 has an increased thickness. Further, the lower portion of the steam inlet pipe 16 is riot provided with a flange and is therefore coupled to a steam vent pipe by alternative means.

Claims (22)

  1. CLAIMS: 1. A vent head for a steam system, comprising: a body defining a vent head chamber and having a vent head outlet; a steam inlet conduit having a steam outlet that opens into the vent head chamber; a baffle disposed within the vent head chamber and above the steam outlet; and a drainage passageway providing fluid communication between the vent head chamber and the steam inlet conduit; wherein in use the steam outlet discharges steam into the vent head chamber which impinges on the baffle, thereby separating entrained liquid water from the steam, the liquid water being collected in the vent head chamber and returned to the steam inlet conduit via the drainage passageway.
  2. 2. A vent head according to claim 1, wherein the steam inlet conduit extends into the vent head chamber.
  3. 3. A vent head according to claim 2, wherein the drainage passageway comprises a hole provided in the portion of the steam inlet conduit which extends into the vent head chamber.
  4. 4. A vent head according to claim 3, wherein there are a plurality of drainage passageways, each comprising a hole provided in the portion of the steam inlet conduit which extends into the vent head chamber.
  5. 5. A vent head according to any preceding claim, wherein the body comprises a bottom wall which slopes downwards towards an inlet of the drainage passageway.
  6. 6. A vent head according to any preceding claim, wherein the steam inlet conduit comprises an attachment portion for attaching the steam inlet conduit to an open-ended steam vent pipe.
  7. 7. A vent head according to any preceding claim, wherein the steam outlet is arranged such that in use the steam is discharged in a substantially vertical direction.
  8. 8. A vent head according to any preceding claim, wherein the baffle is substantially horizontal in use.
  9. 9. A vent head according to any preceding claim, wherein the baffle is substantially planar.
  10. 10. A vent head according to any preceding claim, wherein the baffle is substantially circular.
  11. 11. A vent head according to any preceding claim, wherein the body comprises a top wall within which the vent head outlet is provided.
  12. 12. A vent head according to any preceding claim, wherein the vent head outlet is located above the baffle.
  13. 13. A vent head according to any preceding claim, wherein the baffle is disposed in the steam flow path between the steam outlet and the vent head outlet.
  14. 14. A vent head according to any preceding claim, wherein, when viewed from above, the baffle extends beyond the steam outlet.
  15. 15. A vent head according to any preceding claim, wherein the baffle comprises an impingement region, on which in use the steam impinges, and a convex portion disposed between the impingement region and the edge of the baffle.
  16. 16. A vent head according to claim 15, wherein the convex portion has a radius of curvature such that in use water vapour flows around the convex portion to the vent head outlet, and water droplets are discharged from the convex portion into the vent head chamber.
  17. 17. A vent head according to claim 16, wherein the radius of curvature of the convex portion is between about 4 and 7 mm.
  18. 18. A vent head according to claim 17, wherein the radius of curvature of the convex portion is about 5 mm.
  19. 19. A vent head according to any of claims 15-18, wherein the convex portion curves upwardly in the direction away from the impingement region, and terminates at the edge of the baffle.
  20. 20. A vent head according to any of claims 15-19, wherein, when viewed from above, the convex portion is located in a position beyond the steam outlet.
  21. 21. A steam system comprising a steam vent pipe having a vent head in accordance with any preceding claim attached thereto.
  22. 22. A vent head substantially as described herein with reference to the accompanying drawings.*::r: INTELLECTUAL . ... PROPERTY OFFICE Application No: GB 1010720.9 Examiner: Terence Newhouse Claims searched: 1-21 Date of search: 15 October 2010 Patents Act 1977: Search Report under Section 17 Documents considered to be relevant: Category Relevant Identity of document and passage or figure of particular relevance to claims A -US5114445A ATLANTIC RICHFIELD, see figs noting convex baffle 60 suitable as vent head A -GB1520631A CURWEN & NEWBERRY, note baffles 18 in vent head 9 A -JP2004347231 A TAKUMA, see also WPI Abstract Accession No. 2005-005095 [01] and figs 1 & 6 noting steam separator with baffles 6,7 & water return pipe 4 Categories: X Document indicating lack of novelty or inventive A Document indicating technological background and/or state step of the art.Y Document indicating lack of inventive step if P Document published on or after the declared priority date but combined with one or more other documents of before the filing date of this invention.same category.& Member of the same patent family E Patent document published on or after, but with priority date earlier than, the filing date of this application.Field of Search:Search of GB, EP. WO & US patent documents classified in the following areas of the UKCX Worldwide search of patent documents classified in the following areas of the IPC F22B The following online and other databases have been used in the preparation of this search report WPI, EPODOC International Classification: Subclass Subgroup Valid From F22B 0037/30 01/01/2006 F22B 0037/54 01/01/2006 Intellectual Property Office is an operating name of the Patent Office www.ipo.gov.uk
GB1010720.9A 2010-06-25 2010-06-25 Vent head with drain returning liquid to inlet Active GB2481446B (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
GB1010720.9A GB2481446B (en) 2010-06-25 2010-06-25 Vent head with drain returning liquid to inlet
DE102011077928.0A DE102011077928B4 (en) 2010-06-25 2011-06-21 Vent head
CN201110174076.2A CN102297414B (en) 2010-06-25 2011-06-24 Steam vent head
CN201110271926.0A CN102434871B (en) 2010-06-25 2011-06-24 Vent head
US13/168,106 US8409313B2 (en) 2010-06-25 2011-06-24 Vent head
US13/167,874 US8425643B2 (en) 2010-06-25 2011-06-24 Vent head

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1010720.9A GB2481446B (en) 2010-06-25 2010-06-25 Vent head with drain returning liquid to inlet

Publications (3)

Publication Number Publication Date
GB201010720D0 GB201010720D0 (en) 2010-08-11
GB2481446A true GB2481446A (en) 2011-12-28
GB2481446B GB2481446B (en) 2017-11-29

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Family Applications (1)

Application Number Title Priority Date Filing Date
GB1010720.9A Active GB2481446B (en) 2010-06-25 2010-06-25 Vent head with drain returning liquid to inlet

Country Status (3)

Country Link
CN (2) CN102297414B (en)
DE (1) DE102011077928B4 (en)
GB (1) GB2481446B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106110771A (en) * 2015-05-06 2016-11-16 通用汽车环球科技运作有限责任公司 Device for deposit liquid from gas
FR3043566A1 (en) * 2015-11-16 2017-05-19 Dcns SYSTEM FOR PURIFYING A FLUID, STEAM GENERATOR AND ELECTRIC POWER GENERATION PLANT
EP3366974A1 (en) * 2017-02-27 2018-08-29 Strahman Valves, Inc. Direct diffuse vapor separator - steam trap system

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2481446B (en) * 2010-06-25 2017-11-29 Spirax-Sarco Ltd Vent head with drain returning liquid to inlet
CN102927554A (en) * 2011-08-07 2013-02-13 斯普瑞斯-萨克有限公司 Evacuation cap

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US5114445A (en) * 1991-06-18 1992-05-19 Atlantic Richfield Company Flare vent head
JP2004347231A (en) * 2003-05-22 2004-12-09 Takuma Co Ltd Steam separator

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GB1520631A (en) * 1975-08-07 1978-08-09 Curwen & Newberry Ltd Steam pressure exhaust heads
US5114445A (en) * 1991-06-18 1992-05-19 Atlantic Richfield Company Flare vent head
JP2004347231A (en) * 2003-05-22 2004-12-09 Takuma Co Ltd Steam separator

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106110771A (en) * 2015-05-06 2016-11-16 通用汽车环球科技运作有限责任公司 Device for deposit liquid from gas
FR3043566A1 (en) * 2015-11-16 2017-05-19 Dcns SYSTEM FOR PURIFYING A FLUID, STEAM GENERATOR AND ELECTRIC POWER GENERATION PLANT
EP3366974A1 (en) * 2017-02-27 2018-08-29 Strahman Valves, Inc. Direct diffuse vapor separator - steam trap system
US10550999B2 (en) 2017-02-27 2020-02-04 Strahman Valves, Inc. Direct diffuse vapor separator—steam trap system

Also Published As

Publication number Publication date
CN102434871A (en) 2012-05-02
CN102297414B (en) 2014-07-16
DE102011077928B4 (en) 2021-07-29
CN102434871B (en) 2014-12-24
GB2481446B (en) 2017-11-29
GB201010720D0 (en) 2010-08-11
DE102011077928A1 (en) 2011-12-29
CN102297414A (en) 2011-12-28

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