GB2481002A - Gate insulating layer thickness measurement - Google Patents
Gate insulating layer thickness measurement Download PDFInfo
- Publication number
- GB2481002A GB2481002A GB1009408.4A GB201009408A GB2481002A GB 2481002 A GB2481002 A GB 2481002A GB 201009408 A GB201009408 A GB 201009408A GB 2481002 A GB2481002 A GB 2481002A
- Authority
- GB
- United Kingdom
- Prior art keywords
- area
- electrical property
- layer
- indicator
- underlying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B7/00—Measuring arrangements characterised by the use of electric or magnetic techniques
- G01B7/02—Measuring arrangements characterised by the use of electric or magnetic techniques for measuring length, width or thickness
- G01B7/06—Measuring arrangements characterised by the use of electric or magnetic techniques for measuring length, width or thickness for measuring thickness
- G01B7/08—Measuring arrangements characterised by the use of electric or magnetic techniques for measuring length, width or thickness for measuring thickness using capacitive means
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B7/00—Measuring arrangements characterised by the use of electric or magnetic techniques
- G01B7/02—Measuring arrangements characterised by the use of electric or magnetic techniques for measuring length, width or thickness
- G01B7/06—Measuring arrangements characterised by the use of electric or magnetic techniques for measuring length, width or thickness for measuring thickness
-
- H10W46/00—
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Measurement Of Length, Angles, Or The Like Using Electric Or Magnetic Means (AREA)
- Testing Or Measuring Of Semiconductors Or The Like (AREA)
- Testing Of Individual Semiconductor Devices (AREA)
- Measurement Of Resistance Or Impedance (AREA)
Abstract
The capacitance between a conductive layer 20 overlying conductive electrodes 8 (&6) and 12 is measured to determine the thickness of the gate insulating layer 18 which lies between the conductive layer and the electrodes. The capacitive effects of the variability of the overlap between the conductive layer and the electrodes is compensated by subtracting the capacitance value measured between the electrode 12 and the overlying conductive layer 20 from the capacitance value measured between the electrode 8,6 and the conductive layer. The capacitance between the electrode 6 and the overlying conductive layer is largely independent with respect to changes in overlap of the conductive layer 20 with respect to the underlying conductive electrodes 8 & 12. Therefore, the thickness of the gate dielectric layer 18 can be determined accurately.
Description
DETERMINING LAYER THICKNESS
The present invention relates to a technique for determining the thickness of a layer using electrical measurements. In one embodiment, the present invention relates to a technique for measuring the thickness of a layer in one or more devices produced by a mass production process as part of a quality monitoring process.
One technique for measuring the thickness of a layer in a device having at least some dieectdc properties is to incorporate into the device two conductive elements on opposite sides of the layer whose thickness is to be measured. If the area of overlap between the two conductive elements via said layer is known, then a measurement of the capacitance between the two conductive elements is an indicator of the thickness of the layer.
However, in order to facilitate the measurement of the capacitance between the two conductive elements, the underlying one of the two conductive elements is arranged such that it extends beyond the edge of the overlying one of the two conductive elements in order to facilitate the application of a measuring probe to the underlying conductive element. The inventors have identified the problem that even though the respective total areas of the two conductive elements may be known to a high degree of accuracy, uncontrollable variations in the extent to which the overlying element overlaps with the partially underlying conductive element can reduce the reliability of the capacitance measurement as an indicator of the thickness of the target layer. Such uncontrollable variations can result, for example, from misalignment of the overlying conductive element in relation to the partially underlying conductive element, and/or distortions in the device after the formation of the two conductive elements.
It is an aim of the present invention to provide a technique by which it is possible to measure the thickness of a layer with a high degree of reliability despite some uncontrollable variation in the extent to which the overlying element overlaps with the partially underlying conductive element.
The present invention provides a method comprising: producing a plurality of devices according to a common production process; and determining the thickness of a layer of one of said plurality of devices using an indicator of a first electrical property dependent on the area of overlap between a first element of the device and a second element of the device partially underlying said first element via said layer, wherein the method further comprises: additionally using an indicator of a second electrical property dependent on the area of overlap between said first element of the device and a third element of the device also partially underlying said first element via said layer, wherein (a) the difference between (i) a measured indicator of said first electrical property, and (ii) a measured indicator of said second electrical property provides a more reliable indicator of the thickness of said layer than (b) an indicator of said first electrical property.
In one embodiment, said first eJectrical property is the capacitance between said first element and said second element; and said second electrical property is the capacitance between said first element and said third element.
In one embodiment, said third element of the device is configured such that there is (a) a non-zero area difference between the respective areas of the parts of the second and third elements underlying the first element, and wherein the production process produces less variation between said plurality of devices in said non-zero area difference (a) than the production process produces variation within said plurality of devices in (b) the area of overlap between said first and second elements.
In one embodiment, the method further comprises determining the thickness of the layer based on (i) a predetermined value for said non-zero area difference and (ii) the difference between a measured indicator of the capacitance between said first element and said second element, and a measured indicator of the capacitance between said first element and said third element.
In one embodiment, said non-zero area difference is subject to substantially zero variation.
In one embodiment, said second and third elements have portions of substantial identical area underlying an edge portion of said first element and portions of differing area underlying a more inner portion of said first element.
The present invention also provides a plurality of devices produced according to a common production process, wherein each device comprises a layer and first and second measuring elements partially underlying a third element via said layer, wherein (a) the difference between (i) a measured indicator of a first electrical property dependent on the area of overlap between said first element and said third element, and (ii) a measured indicator of a second electrical property dependent on the area of overlap between said second element and said third element provides a more reliable indicator of the thickness of said layer than (b) an indicator of said first electrical property.
In one embodiment, said first electrical property is the capacitance between said first element and said second element; and said second electrical property is the capacitance between said first element and said third element.
In one embodiment, there is (a) a non-zero area difference between the areas of the parts of the first and second elements underlying the third element, which non-zero area difference (a) is subject to less variation within said plurality of devices than (b) the area of overlap between said first and third elements.
In one embodiment, the non-zero area difference is subject to substantially zero variation.
In one embodiment, said first and second measuring elements have portions of substantial identical area underlying an edge portion of said third element and portions of differing area underlying a more inner portion of said third element.
An embodiment of the present invention is described hereunder, by way of example only, with reference to the attached Figure 1 which illustrates an example of a test structure for use in the embodiment.
Figures 1(a) shows a perspective view of a section of an electronic device including a test structure according to an embodiment of the present invention.
Figure 1(b) is cross-sectional view taken through line A-A of Figure 1; and Figure 1(c) is a plan view. In both Figures 1(a) and 1(c), parts that are in fact hidden below overlying layers are also shown for the purpose of better illustrating the embodiment.
Figure 1 shows a small-section of an electronic device produced in large numbers according to a common mass production process.
A substrate 16 has formed thereon an electrically insulating layer 18 which serves an electronic function in the electronic device; for example, it defines the gate dielectric elements of an array ofTFTs (not shown). At one edge portion of the insulating layer 18 are provided measuring elements 1, 2 and 20 for use in determining the thickness of the insulating layer 18. The measuring elements include two separate lower conductive elements 2 and 4 underlying the insulating layer and an upper conductive element 20 overlying the insulating layer 18. The lower conductive elements 2, 4 are formed by photolithographic patterning of a continuous deposit of conductive material on the substrate 16. The insulating layer 18 overlies the whole of the two lower conductive elements 2,4 except for an outer portion of the two lower conductive elements including measurement pads 10 and 14 for the application of a measurement probe. The overlying conductive element 20 is formed so as to lie within the bounds of the underlying insulating layer 18. The upper conductive element 20 also overlies the whole of the lower conductive elements 2 and 4 except for an outer portion of the lower conductive elements 2, 4 including the measurement pads 10 and 14.
Each of the lower conductive elements 2 and 4 comprises a measurement pad 10, 14 and a line 8, 12 extending under the insulating layer 18 and upper conductive element 20. The measurement pad and lines of each lower conductive element 2,4 are designed to have exactly the same size, shape and orientation; in particular, the lines 8, 12 extend in parallel in a direction substantially perpendicular to the edge of the upper conductive element 20 and have a common width. Only one of the two lower conductive elements has an extra portion 6 whose area is known to a high degree of accuracy and which is located such that it is certain to underlie the upper conductive element 20 regardless of the precise location of the edge of the upper conductive element within the uncontrollable variation range associated with the mass production process used to produce the devices.
When determining the thickness of the insulating layer 18, a measurement is made of the capacitance between the first lower conductive element 2 and the upper conductive element 20, and a measurement is made of the capacitance between the second lower conductive element 4 and the upper conductive element 20. The difference between these two measurements is taken to be the capacitance between extra portion 6 of the first lower conductive element 2 and the upper conductive element 20. Because the area of overlap between the extra portion 6 and the upper conductive element is accurately known to a high degree of reliability (because of the above-mentioned certainty of extra portion 6 being entirely overlapped by the upper conductive element 20), the value of the capacitance between the extra portion 6 and the upper conductive element 20 is a reliable indicator of the thickness of the insulating layer 18.
The difference between the above-mentioned two capacitance measurements is exactly the capacitance between extra portion 6 of the first lower conductive element 2 and the upper conductive element 20 only if the edge of the upper conductive element 20 runs exactly perpendicular to the direction of the lines 8 and 12 (i.e. only if the area of overlap between line 8 and the upper conductive element is exactly the same as the area of overlap between line 12 and the upper conductive element). However, even if the mass production process produces some uncontrollable variation in the angle between the direction of the edge of the upper conductive element 20 and the direction of lines 8 and 12, the above-described technique can still provide a relatively reliable determination of the thickness of the dielectric layer 18 provided that (a) the range of variation of the area difference between (i) the area of overlap between line 8 and the upper conductive element 20 and (ii) the area of overlap between line 12 and the upper conductive element 20, is less than the range of variation of the area of overlap between the line 8 and the upper conductive element 20. The variation range (a) is the difference between the smallest area difference and largest area difference that could result from the production process; and the variation range (b) is the difference between the smallest area of overlap and the largest area of overlap that could result from the production process. In other words, the above-described technique can still provide a relatively reliable determination of the thickness of the dielectric layer 18 provided that (a) the range of variation of the difference between (I) the area of overlap between line 8 and the upper conductive element 20 and (ii) the area of overlap between line 12 and the upper conductive element 20, is known to a greater degree of accuracy than (b) the area of overlap between the line 8 and the upper conductive element 20.
For the description of the above embodiment, we have chosen the example of an insulating layer as the layer whose thickness is to be determined. However, the same technique is also useful for determining the thickness of other types of layers that have at least some dielectric properties, such as semiconductor layers.
Also, for the description of the above embodiment, we have chosen the example of determining the layer thickness on the basis of capacitance measurements. However, the same kind of technique is also applicable, for example, in the case where the layer thickness is determined based on measurement(s) of other electrical properties dependent on the area of overlap between two conductive elements, such as measurement(s) of the vertical area specific conductivity between two conductive elements separated by a conductive or semiconductive layer having a relatively high resistance (low conductivity).
In addition to any modifications explicitly mentioned above, it will be evident to a person skilled in the art that various other modifications of the described embodiment may be made within the scope of the invention.
Claims (11)
- CLAIMS1. A method comprising: producing a plurality of devices according to a common production process; and determining the thickness of a layer of one of said plurality of devices using an indicator of a first electrical property dependent on the area of overlap between a first element of the device and a second element of the device partially underlying said first element via said layer, wherein the method further comprises: additionally using an indicator of a second electrical property dependent on the area of overlap between said first element of the device and a third element of the device also partially underlying said first element via said layer, wherein (a) the difference between (I) a measured indicator of said first electrical property, and (ii) a measured indicator of said second electrical property provides a more rehable indicator of the thickness of said layer than (b) an indicator of said first electrical property.
- 2. A method according to claim 1, wherein said first electrical property is the capacitance between said first element and said second element; and said second electrical property is the capacitance between said first element and said third element.
- 3. A method according to claim 2, wherein said third element of the device is configured such that there is (a) a non-zero area difference between the respective areas of the parts of the second and third elements underlying the first element, and wherein the production process produces less variation between said plurality of devices in said non-zero area difference (a) than the production process produces variation within said plurality of devices in (b) the area of overlap between said first and second elements.
- 4. A method according to claim 3, comprising determining the thickness of the layer based on (i) a predetermined value for said non-zero area difference and (ii) the difference between a measured indicator of the capacitance between said first element and said second element, and a measured indicator of the capacitance between said first element and said third element.
- 5. A method according to claim 3 or claim 4, wherein said non-zero area difference is subject to substantially zero variation.
- 6. A method according to any preceding claim, wherein said second and third elements have portions of substantial identical area underlying an edge portion of said first element and portions of differing area underlying a more inner portion of said first element.
- 7. A plurality of devices produced according to a common production process, wherein each device comprises a layer and first and second measuring elements partially underlying a third element via said layer, wherein (a) the difference between (i) a measured indicator of a first electrical property dependent on the area of overlap between said first element and said third element, and (ii) a measured indicator of a second electrical property dependent on the area of overlap between said second element and said third element provides a more reliable indicator of the thickness of said layer than (b) an indicator of said first electrical property.
- 8. A plurality of devices according to claim 7, wherein said first electrical property is the capacitance between said first element and said second element; and said second electrical property is the capacitance between said first element and said third element.
- 9. A plurality of devices according to claim 8, wherein there is (a) a non-zero area difference between the areas of the parts of the first and second elements underlying the third element, which non-zero area difference (a) is subject to less variation within said plurality of devices than (b) the area of overlap between said first and third elements.
- 10. A plurality of devices according to claim 9, wherein the non-zero area difference is subject to substantially zero variation.
- 11. A plurality of devices according to claim 9 or claim 10, wherein said first and second measuring elements have portions of substantial identical area underlying an edge portion of said third element and portions of differing area underlying a more inner portion of said third element.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1009408.4A GB2481002B (en) | 2010-06-04 | 2010-06-04 | Determining layer thickness |
| DE112011101900T DE112011101900T5 (en) | 2010-06-04 | 2011-06-03 | Layer thickness determination |
| CN201180035976.7A CN103026169B (en) | 2010-06-04 | 2011-06-03 | Method of measuring thickness of layers in multiple devices and produced devices |
| KR1020137000293A KR101922194B1 (en) | 2010-06-04 | 2011-06-03 | Determining layer thickness |
| JP2013512940A JP5995840B2 (en) | 2010-06-04 | 2011-06-03 | Measurement of layer thickness |
| US13/701,785 US9035665B2 (en) | 2010-06-04 | 2011-06-03 | Determining layer thickness |
| PCT/EP2011/059222 WO2011151459A1 (en) | 2010-06-04 | 2011-06-03 | Determining layer thickness |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1009408.4A GB2481002B (en) | 2010-06-04 | 2010-06-04 | Determining layer thickness |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB201009408D0 GB201009408D0 (en) | 2010-07-21 |
| GB2481002A true GB2481002A (en) | 2011-12-14 |
| GB2481002B GB2481002B (en) | 2015-01-14 |
Family
ID=42471194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1009408.4A Expired - Fee Related GB2481002B (en) | 2010-06-04 | 2010-06-04 | Determining layer thickness |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9035665B2 (en) |
| JP (1) | JP5995840B2 (en) |
| KR (1) | KR101922194B1 (en) |
| CN (1) | CN103026169B (en) |
| DE (1) | DE112011101900T5 (en) |
| GB (1) | GB2481002B (en) |
| WO (1) | WO2011151459A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105336729A (en) * | 2014-07-18 | 2016-02-17 | 上海和辉光电有限公司 | Capacitance testing structure and testing method for monitoring dielectric film thickness |
| CN105448763B (en) * | 2014-09-30 | 2018-06-01 | 中芯国际集成电路制造(上海)有限公司 | Measure the semiconductor structure of gate dielectric layer thickness and gate dielectric layer method for measuring thickness |
| CN104808072A (en) * | 2015-04-29 | 2015-07-29 | 京东方科技集团股份有限公司 | Film structure, testing method thereof, display substrate and testing method and production method thereof |
| CN105806206B (en) * | 2016-03-25 | 2019-01-08 | 威海华菱光电股份有限公司 | Thickness detection apparatus |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5801538A (en) * | 1995-08-22 | 1998-09-01 | Hyundai Electronics Industries Co., Ltd. | Test pattern group and a method of measuring an insulation film thickness utilizing the same |
| US6465267B1 (en) * | 2001-04-02 | 2002-10-15 | Advanced Micro Devices, Inc. | Method of measuring gate capacitance to determine the electrical thickness of gate dielectrics |
| US6841832B1 (en) * | 2001-12-19 | 2005-01-11 | Advanced Micro Devices, Inc. | Array of gate dielectric structures to measure gate dielectric thickness and parasitic capacitance |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2528970B1 (en) * | 1982-06-22 | 1985-09-27 | Flonic Sa | DEVICE FOR CHECKING THICKNESS OF DIELECTRIC SHEET MATERIAL |
| JPS6170403A (en) * | 1984-09-14 | 1986-04-11 | Toshiba Corp | Method for measuring film thickness of inter-layer insulating layer of multi-layer wired substrate |
| JPS61181195A (en) * | 1985-02-07 | 1986-08-13 | 日本電気株式会社 | Interlamella thickness detection for multilayer printed wiring board |
| JPH01223303A (en) * | 1988-03-02 | 1989-09-06 | Nec Corp | Apparatus for measuring thickness of membrane |
| JPH02307002A (en) | 1989-05-23 | 1990-12-20 | Mitsubishi Electric Corp | Method for measuring thickness of semiconductor substrate |
| JPH0752083B2 (en) * | 1990-02-16 | 1995-06-05 | 株式会社村田製作所 | Paper thickness detector |
| US5198777A (en) * | 1990-02-14 | 1993-03-30 | Murata Mfg. Co., Ltd. | Paper thickness detecting apparatus having a resonator with a resonance point set by a capacitance detecting unit |
| DE4031210A1 (en) * | 1990-10-04 | 1992-04-09 | Bosch Gmbh Robert | CAPACITIVE SENSOR FOR MEASURING A FUEL WALL FILM |
| JP2922376B2 (en) * | 1992-12-26 | 1999-07-19 | キヤノン株式会社 | Sheet thickness measuring device |
| US5840936A (en) * | 1995-06-07 | 1998-11-24 | Magainin Pharmaceuticals Inc. | Aminosterol compounds useful as inhibitors of the sodium/proton exchanger (NHE) |
| CN2249889Y (en) * | 1995-11-13 | 1997-03-19 | 北京昌顺物业管理有限责任公司 | Position shift detector |
| EP0924518B1 (en) * | 1997-12-19 | 2006-11-08 | Uster Technologies AG | Apparatus for measuring characteristics of a textile product |
| MY140780A (en) * | 2004-10-11 | 2010-01-15 | Silterra Malaysia Sdn Bhd | Via etch monitoring |
| EP1720135A1 (en) * | 2005-05-06 | 2006-11-08 | BEB Industrie-Elektronik AG | Apparatus for measuring thickness and thickness variations |
-
2010
- 2010-06-04 GB GB1009408.4A patent/GB2481002B/en not_active Expired - Fee Related
-
2011
- 2011-06-03 WO PCT/EP2011/059222 patent/WO2011151459A1/en not_active Ceased
- 2011-06-03 DE DE112011101900T patent/DE112011101900T5/en not_active Withdrawn
- 2011-06-03 KR KR1020137000293A patent/KR101922194B1/en not_active Expired - Fee Related
- 2011-06-03 CN CN201180035976.7A patent/CN103026169B/en not_active Expired - Fee Related
- 2011-06-03 US US13/701,785 patent/US9035665B2/en not_active Expired - Fee Related
- 2011-06-03 JP JP2013512940A patent/JP5995840B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5801538A (en) * | 1995-08-22 | 1998-09-01 | Hyundai Electronics Industries Co., Ltd. | Test pattern group and a method of measuring an insulation film thickness utilizing the same |
| US6465267B1 (en) * | 2001-04-02 | 2002-10-15 | Advanced Micro Devices, Inc. | Method of measuring gate capacitance to determine the electrical thickness of gate dielectrics |
| US6841832B1 (en) * | 2001-12-19 | 2005-01-11 | Advanced Micro Devices, Inc. | Array of gate dielectric structures to measure gate dielectric thickness and parasitic capacitance |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011151459A1 (en) | 2011-12-08 |
| JP5995840B2 (en) | 2016-09-21 |
| KR101922194B1 (en) | 2018-11-26 |
| CN103026169A (en) | 2013-04-03 |
| CN103026169B (en) | 2016-11-16 |
| KR20140015237A (en) | 2014-02-06 |
| US9035665B2 (en) | 2015-05-19 |
| GB2481002B (en) | 2015-01-14 |
| JP2013527465A (en) | 2013-06-27 |
| GB201009408D0 (en) | 2010-07-21 |
| US20130141120A1 (en) | 2013-06-06 |
| DE112011101900T5 (en) | 2013-03-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9594041B2 (en) | Capacitive humidity sensor | |
| US7659727B2 (en) | Multilayer wiring board and method for testing the same | |
| US7656166B2 (en) | Multilayer wiring board and method for testing the same | |
| US7934430B2 (en) | Die scale strain gauge | |
| US20160047699A1 (en) | Sensorelement, Thermometer sowie Verfahren zur Bestimmung einer Temperatur | |
| US9035665B2 (en) | Determining layer thickness | |
| JP2011080833A (en) | Humidity detection sensor | |
| US20130038336A1 (en) | Probe Calibration Device and Calibration Method | |
| JP3197515U (en) | Liquid level sensor | |
| TWI526132B (en) | Correction film structure | |
| US20080252306A1 (en) | Displacement detection pattern for detecting displacement between wiring and via plug, displacement detection method, and semiconductor device | |
| US9995639B2 (en) | Sensor element, thermometer as well as method for determining a temperature | |
| JP3756348B2 (en) | Misalignment detection pattern | |
| JP2020521975A (en) | Strain gauges and metal strips with such strain gauges | |
| KR20000026196A (en) | Test structure for measuring minimum area design and method therefor | |
| JP6994186B2 (en) | Semiconductor devices and semiconductor device design methods | |
| JP4229110B2 (en) | Contact misalignment detection method | |
| KR20210011871A (en) | Probing Module Adapted for Testing Multi-units Having Inclined Conductive Contacts | |
| KR100816192B1 (en) | Semiconductor device with alignment marks | |
| KR20070005321A (en) | Test pattern for measuring contact resistance of metal wiring | |
| RU2688849C1 (en) | Deformation measuring device | |
| KR100248207B1 (en) | Test pattern for semiconductor device | |
| US10147765B2 (en) | Test structures for manufacturing process of organic photo diode imaging array | |
| KR20060077872A (en) | Contact Resistance Test Pattern | |
| TW201939031A (en) | Humidity detection device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| S30Z | Assignments for licence or security reasons |
Free format text: APPLICANTSTATE CORPORATION; RUSSIAN CORPORATION OF NANOTECHNOLOGIES |
|
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20210604 |