GB2455294A - Skin or hair wash formulation - Google Patents

Skin or hair wash formulation Download PDF

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Publication number
GB2455294A
GB2455294A GB0723610A GB0723610A GB2455294A GB 2455294 A GB2455294 A GB 2455294A GB 0723610 A GB0723610 A GB 0723610A GB 0723610 A GB0723610 A GB 0723610A GB 2455294 A GB2455294 A GB 2455294A
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United Kingdom
Prior art keywords
oil
formulation according
formulation
ingredients
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB0723610A
Other versions
GB2455294B (en
GB0723610D0 (en
Inventor
Pauline Hili
Dharmini Dhushyanthan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEAL S YARD
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NEAL S YARD
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Publication date
Application filed by NEAL S YARD filed Critical NEAL S YARD
Priority to GB0723610.2A priority Critical patent/GB2455294B/en
Publication of GB0723610D0 publication Critical patent/GB0723610D0/en
Priority to PCT/GB2008/051152 priority patent/WO2009071945A2/en
Publication of GB2455294A publication Critical patent/GB2455294A/en
Application granted granted Critical
Publication of GB2455294B publication Critical patent/GB2455294B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

The formulation is homogeneous, has a pH in the range from 6 to 8, and comprises the following (in which all percentages indicated are by weight): ```at least 50% of at least one fixed oil; ```at least 15% of an alkali metal amphoacetate; ```at least 5% of a lauryl betaine; ```at least 0.1% of a gelling agent; and ```an emulsifying amount of an organic emulsifying agent; ```a dermatologically acceptable amount of an organic acid such as citric acid, in an amount to ensure that the pH is in the range indicated above, and, ```optionally, one or more perfume agents, viscosity modifiers, sensory feel enhancers, and other additives conventionally included in such formulations, the balance being either incidental ingredients or non-deleterious ingredients, such that the formulation is in the form of a water-dilutable cream.

Description

Skin and hair wash preparation The present invention concerns skin and hair wash preparations such as conditioning shampoos, body washes and shower gels, and in particular formulations which permit replenishment of the natural oils present in hair and skin.
Many types of formulations for shampoos, body washes and shower gels have been proposed over the years. Shampoo formulations in particular should be easy to rinse, provide a good finish after washing hair, result in minimal skin or eye irritation, or damage to hair, and should have low toxicity.
Over the last few years it has been of increasing concern to provide shampoo and skin wash formulations which consist primarily of natural ingredients, in order to avoid deleterious effects on either the skin or hair of the user, or indeed on the environment, bearing in mind that all skin wash preparations and shampoos ultimately have to enter a watercourse.
Many known shampoo formulations tend, to greater or lesser degrees, to strip hair and scalp of the natural vital oils which are normally to be found in or on healthy hair.
Known skin wash formulations can also undesirably strip oils and the like.
It is an object of the present invention to provide a skin or hair wash formulation having a high proportion of oils, especially natural oils, such that use of the formulation avoids undesirable stripping of natural oils from hair of a user.
According to the invention, therefore, there is provided a homogeneous skin or hair wash formulation having a pH in the range from 6 to 8, which formulation comprises the following (in which all percentages indicated are by weight): at least 50% of at least one fixed oil; at least 15 % of an alkali metal amphoacetate; at least 5 % of a lauryl betaine; at least 0.1% of a gelling agent; and an emulsifying amount of an organic emulsifying agent; a dermatologically acceptable amount of an organic acid such as citric acid, in an amount to ensure that the pH is in the range indicated above, and, optionally, one or more perfume agents, viscosity modifiers, sensory feel enhancers, and other additives conventionally included in shampoos or skin wash formulations, the balance being either incidental ingredients or non-deleterious ingredients, such that the formulation is in the form of a water-dilutable cream.
The fixed oil is typically a lipophilic long chain vegetable oil of edible quality. Such an oil may be saturated or unsaturated (and if unsaturated may be mono-unsaturated or polyunsaturated). Such vegetable oils typically have from 12 to 20 carbon atoms and may be derived from one or more of nuts, flowers or the like. Examples of suitable such oils include sunflower oil, jojoba oil, almond oil, hazelnut oil and the like. The oil employed is preferably of certifiable organic quality, such as one meeting the Soil Association certification standard and preferably includes a blend of such vegetable oils. The fixed oil is preferably present in an amount of at least 60% of the formulation.
The alkali metal amphoacetate is typically a sodium salt. Examples of suitable amphoacetates which may be employed in the formulation according to the present invention include cocoamphocarboxy-propionates, cocoamphoglycinates, coco-amphopropionates, cocoamphocarboxyglycinates, lauroamphocarboxypropionates, lauroamphocarboxyglycinates, lauroamphocarboxypropionates and lauroampho-glycinates The emulsifying agent is organic (that is, not inorganic) and is further preferably of certifiable organic quality, such as one meeting the Soil Association certification standard. The emulsifying agent may be, for example, cetyl glucoside and/or stearyl glucoside. A preferred such emulsifying agent is cetearyl glucoside (that is, a combination of cetyl and stearyl glucosides). Such an emulsifying agent co-operates with the lauryl betaine present in the formulation in order to ensure a stable formulation which works effectively as a skin or hair wash preparation Cetearyl glucoside has been found to work effectively at low concentrations (such as no more than 1.5%) and is able to handle base oils at high percentages (such as more than 20%). If other emulsifying agents such as sucrose stearate or cetearyl alcohol are used, they may need to be added in considerably larger amounts to handle large proportions of oils.
The lauryl betaine is preferably present in an amount of up to 15% by weight (more preferably up to 10%); it is present in an amount such that the skin or hair wash preparation is a white cream in the absence of colouring agents. If attempts are made to use too little of the lauryl betaine, then the formulation may be disadvantageously yellow in colour. If other apparently similar betaines, such as cetyl betaine or cocoamidopropyl betaine, are tried instead of lauryl betaine, then a cream-like product is not formed. Rather, a disadvantageous thin yellow liquid is formed.
The gelling agent is typically a natural gum, such as xanthan gum or the like. Such a gelling agent is preferably present in an amount not exceeding 2%.
An optional further ingredient is glycerine, typically present in an amount of up to 5% of the skin or hair wash formulation.
Other ingredients, such as aloe vera powder, calendula tincture which are not essential for the basic function of a skin or hair wash formulation may be included.
Such ingredients may, however, give an enhanced sensory effect or enhance the perceived goodness' of the formulation.
In some embodiments, all the ingredients in the hair or skin wash formulation may be of food-grade quality. It is further particularly preferred that all ingredients should be of certifiably organic quality.
The skin or hair wash formulation according to the invention is generally stable both physically and microbially; and lacks undesirable physical attributes such as harshness and oiliness.
The following Example of a formulation according to the invention is given by way of example only, in which all percentages are by weight.
Example
A shampoo formulation was made with the following proportions: 69.4% of organic jojoba oil; 18 % of a sodium amphoacetate; 5 % of a lauryl betaine; 0.1% of an organic (that is, of organic quality) xanthan gum gelling agent; 1.5% cetearyl glucoside; 2% citric acid; and 4% glycerine.
The shampoo formulation was used to wash 50 heads in a professional salon and compared against a leading baby shampoo (Johnson and Johnson).
The shampoo formulation according to the invention produced a rich creamy lather. It was slower to lather up than the comparative shampoo and had less volume, but it was noticeably creamier and rinsed out easily.
After rinsing and towel drying the shampoo formulation according to the invention left the hair feeling cleaner than the comparative shampoo but was equally easy to comb. Tangle removal was moderately easy. Neither of the shampoos was considered to give much conditioning to wet hair.
After drying and styling the hair there were no significant differences between the two shampoos and both products left the hair feeling clean and in good condition although flyway was not completely eliminated. In either case Skin and hair wash preparation The present invention concerns skin and hair wash preparations such as conditioning shampoos, body washes and shower gels, and in particular formulations which permit replenishment of the natural oils present in hair and skin.
Many types of formulations for shampoos, body washes and shower gels have been proposed over the years. Shampoo formulations in particular should be easy to rinse, provide a good finish after washing hair, result in minimal skin or eye irritation, or damage to hair, and should have low toxicity.
Over the last few years it has been of increasing concern to provide shampoo and skin wash formulations which consist primarily of natural ingredients, in order to avoid deleterious effects on either the skin or hair of the user, or indeed on the environment, bearing in mind that all skin wash preparations and shampoos ultimately have to enter a watercourse.
Many known shampoo formulations tend, to greater or lesser degrees, to strip hair and scalp of the natural vital oils which are normally to be found in or on healthy hair.
Known skin wash formulations can also undesirably strip oils and the like.
It is an object of the present invention to provide a skin or hair wash formulation having a high proportion of oils, especially natural oils, such that use of the formulation avoids undesirable stripping of natural oils from hair of a user.
According to the invention, therefore, there is provided a homogeneous skin or hair wash formulation having a pH in the range from 6 to 8, which formulation comprises the following (in which all percentages indicated are by weight): at least 50% of at least one fixed oil; at least 15 % of an alkali metal amphoacetate; at least 5 % of a lauryl betaine; at least 0.1% of a gelling agent; and an emulsifying amount of an organic emulsifying agent; a dermatologically acceptable amount of an organic acid such as citric acid, in an amount to ensure that the pH is in the range indicated above, and, optionally, one or more perfume agents, viscosity modifiers, sensory feel enhancers, and other additives conventionally included in shampoos or skin wash formulations, the balance being either incidental ingredients or non-deleterious ingredients, such that the formulation is in the form of a water-dilutable cream.
The fixed oil is typically a lipophilic long chain vegetable oil of edible quality. Such an oil may be saturated or unsaturated (and if unsaturated may be mono-unsaturated or polyunsaturated). Such vegetable oils typically have from 12 to 20 carbon atoms and may be derived from one or more of nuts, flowers or the like. Examples of suitable such oils include sunflower oil, jojoba oil, almond oil, hazelnut oil and the like. The oil employed is preferably of certifiable organic quality, such as one meeting the Soil Association certification standard and preferably includes a blend of such vegetable oils. The fixed oil is preferably present in an amount of at least 60% of the formulation.
The alkali metal amphoacetate is typically a sodium salt. Examples of suitable amphoacetates which may be employed in the formulation according to the present invention include cocoamphocarboxy-propionates, cocoamphoglycinates, coco-amphopropionates, cocoamphocarboxyglycinates, lauroamphocarboxypropionates, lauroamphocarboxyglycinates, lauroamphocarboxypropionates and lauroampho-glycinates The emulsifying agent is organic (that is, not inorganic) and is further preferably of certifiable organic quality, such as one meeting the Soil Association certification standard. The emulsifying agent may be, for example, cetyl glucoside and/or stearyl glucoside. A preferred such emulsifying agent is cetearyl glucoside (that is, a combination of cetyl and stearyl glucosides). Such an emulsifying agent co-operates with the lauryl betaine present in the formulation in order to ensure a stable formulation which works effectively as a skin or hair wash preparation Cetearyl glucoside has been found to work effectively at low concentrations (such as no more than 1.5%) and is able to handle base oils at high percentages (such as more than 20%). If other emulsifying agents such as sucrose stearate or cetearyl alcohol are used, they may need to be added in considerably larger amounts to handle large proportions of oils.
The lauryl betaine is preferably present in an amount of up to 15% by weight (more preferably up to 10%); it is present in an amount such that the skin or hair wash preparation is a white cream in the absence of colouring agents. If attempts are made to use too little of the lauryl betaine, then the formulation may be disadvantageously yellow in colour. If other apparently similar betaines, such as cetyl betaine or cocoamidopropyl betaine, are tried instead of lauryl betaine, then a cream-like product is not formed. Rather, a disadvantageous thin yellow liquid is formed.
The gelling agent is typically a natural gum, such as xanthan gum or the like. Such a gelling agent is preferably present in an amount not exceeding 2%.
An optional further ingredient is glycerine, typically present in an amount of up to 5% of the skin or hair wash formulation.
Other ingredients, such as aloe vera powder, calendula tincture which are not essential for the basic function of a skin or hair wash formulation may be included.
Such ingredients may, however, give an enhanced sensory effect or enhance the perceived goodness' of the formulation.
In some embodiments, all the ingredients in the hair or skin wash formulation may be of food-grade quality. It is further particularly preferred that all ingredients should be of certifiably organic quality.
The skin or hair wash formulation according to the invention is generally stable both physically and microbially; and lacks undesirable physical attributes such as harshness and oiliness.
The following Example of a formulation according to the invention is given by way of example only, in which all percentages are by weight.
Example
A shampoo formulation was made with the following proportions: 69.4% of organic jojoba oil; 18 % of a sodium amphoacetate; 5 % of a lauryl betaine; 0.1% of an organic (that is, of organic quality) xanthan gum gelling agent; 1.5% cetearyl glucoside; 2% citric acid; and 4% glycerine.
The shampoo formulation was used to wash 50 heads in a professional salon and compared against a leading baby shampoo (Johnson and Johnson).
The shampoo formulation according to the invention produced a rich creamy lather. It was slower to lather up than the comparative shampoo and had less volume, but it was noticeably creamier and rinsed out easily.
After rinsing and towel drying the shampoo formulation according to the invention left the hair feeling cleaner than the comparative shampoo but was equally easy to comb. Tangle removal was moderately easy. Neither of the shampoos was considered to give much conditioning to wet hair.
After drying and styling the hair there were no significant differences between the two shampoos and both products left the hair feeling clean and in good condition although flyway was not completely eliminated. In either case

Claims (8)

  1. Claims 1. A homogeneous skin or hair wash formulation having a pH in the range from 6 to 8, which comprises the following (in which all percentages indicated are by weight): at least 50% of at least one fixed oil; at least 15 % of an alkali metal amphoacetate; at least 5 % of a lauryl betaine; at least 0.1% of a gelling agent; and an emulsifying amount of an organic emulsifying agent; a dermatologically acceptable amount of an organic acid, in an amount to ensure that the pH is in said range, and, optionally, one or more shampoo additives of known type, the balance being either incidental ingredients or non-deletenous ingredients, such that the formulation is in the form of a water-dilutable cream.
  2. 2 A formulation according to claim 1, in which the fixed oil is a lipophilic long chain vegetable oil of edible quality.
  3. 3 A formulation according to claim 2, wherein said oil has 12 to 20 carbon atoms
  4. 4 A formulation according to claim 1, wherein the oil is sunflower oil, jojoba oil, almond oil or hazelnut oil
  5. 5 A formulation according to any of claims I to 4, wherein the alkali metal amphoacetate is a sodium salt.
  6. 6 A formulation according to any of claims I to 5, wherein the emulsifying agent is cetyl glucoside and/or stearyl glucoside.
  7. 7 A formulation according to any of claims I to 6, wherein all the ingredients in are of food-grade quality.
  8. 8 A formulation according to any of claims I to 7, further containing glycerine.
    8 A formulation according to any of claims I to 7, further containing glycerine.
    Claims 1. A homogeneous skin or hair wash formulation having a pH in the range from 6 to 8, which comprises the following (in which all percentages indicated are by weight): at least 50% of at least one fixed oil; at least 15 % of an alkali metal amphoacetate; at least 5 % of a lauryl betaine; at least 0.1% of a gelling agent; and an emulsifying amount of an organic emulsifying agent; a dermatologically acceptable amount of an organic acid, in an amount to ensure that the pH is in said range, and, optionally, one or more shampoo additives of known type, the balance being either incidental ingredients or non-deletenous ingredients, such that the formulation is in the form of a water-dilutable cream.
    2 A formulation according to claim 1, in which the fixed oil is a lipophilic long chain vegetable oil of edible quality.
    3 A formulation according to claim 2, wherein said oil has 12 to 20 carbon atoms 4 A formulation according to claim 1, wherein the oil is sunflower oil, jojoba oil, almond oil or hazelnut oil 5 A formulation according to any of claims I to 4, wherein the alkali metal amphoacetate is a sodium salt.
    6 A formulation according to any of claims I to 5, wherein the emulsifying agent is cetyl glucoside and/or stearyl glucoside.
    7 A formulation according to any of claims I to 6, wherein all the ingredients in are of food-grade quality.
GB0723610.2A 2007-12-03 2007-12-03 Skin and hair wash preparation Expired - Fee Related GB2455294B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB0723610.2A GB2455294B (en) 2007-12-03 2007-12-03 Skin and hair wash preparation
PCT/GB2008/051152 WO2009071945A2 (en) 2007-12-03 2008-12-03 Skin and hair wash preparation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB0723610.2A GB2455294B (en) 2007-12-03 2007-12-03 Skin and hair wash preparation

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Publication Number Publication Date
GB0723610D0 GB0723610D0 (en) 2008-01-09
GB2455294A true GB2455294A (en) 2009-06-10
GB2455294B GB2455294B (en) 2011-12-21

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WO (1) WO2009071945A2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011138179A3 (en) * 2010-05-05 2012-05-24 Unilever Plc Specific mild low surfactant, high emollient systems which retain foaming and phase stability
US9655821B2 (en) 2013-04-05 2017-05-23 The Procter & Gamble Company Personal care composition comprising a pre-emulsified formulation
US9993404B2 (en) 2015-01-15 2018-06-12 The Procter & Gamble Company Translucent hair conditioning composition
US10806688B2 (en) 2014-10-03 2020-10-20 The Procter And Gamble Company Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation
US10912723B2 (en) 2016-01-20 2021-02-09 The Procter And Gamble Company Hair conditioning composition comprising monoalkyl glyceryl ether

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5994280A (en) * 1991-10-11 1999-11-30 The Procter & Gamble Company Cleansing compositions comprising an anionic surfactant and amphoteric surfactant mixture
GB9913408D0 (en) * 1999-06-10 1999-08-11 Albright & Wilson Uk Ltd Personal care formulations
DE10205296A1 (en) * 2002-02-08 2003-08-21 Cognis Deutschland Gmbh Washing preparations with vegetable oils
US6797683B2 (en) * 2002-03-04 2004-09-28 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Ordered liquid crystalline cleansing composition with benefit agent particles
US7256164B2 (en) * 2002-08-13 2007-08-14 Mcintyre Group, Ltd. High concentration surfactant compositions and methods
US7541320B2 (en) * 2004-01-23 2009-06-02 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Mild, viscous cleansing composition with versatile compatibility and enhanced conditioning

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011138179A3 (en) * 2010-05-05 2012-05-24 Unilever Plc Specific mild low surfactant, high emollient systems which retain foaming and phase stability
EA023606B1 (en) * 2010-05-05 2016-06-30 Унилевер Н.В. Specific mild low surfactant, high emollient systems which retain foaming and phase stability
US9655821B2 (en) 2013-04-05 2017-05-23 The Procter & Gamble Company Personal care composition comprising a pre-emulsified formulation
US10806688B2 (en) 2014-10-03 2020-10-20 The Procter And Gamble Company Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation
US9993404B2 (en) 2015-01-15 2018-06-12 The Procter & Gamble Company Translucent hair conditioning composition
US10912723B2 (en) 2016-01-20 2021-02-09 The Procter And Gamble Company Hair conditioning composition comprising monoalkyl glyceryl ether

Also Published As

Publication number Publication date
GB2455294B (en) 2011-12-21
GB0723610D0 (en) 2008-01-09
WO2009071945A2 (en) 2009-06-11
WO2009071945A3 (en) 2009-07-23

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