DE10205296A1 - Washing preparations with vegetable oils - Google Patents

Abstract

Washing preparations containing surfactants with at least 25% by weight of a vegetable oil and the use of mixtures containing alkyl and / or alkenyl oligoglycosides, amphoteric surfactants and, if appropriate, cation polymers for the preparation of washing preparations with at least 25% by weight of vegetable oils are proposed. DOLLAR A The washing preparations are characterized by good moisturizing and moisturizing properties, a high level of physico-chemical stability and a pleasant feeling on the skin after use.

Description

Field of the Invention

The invention relates to cosmetic preparations containing vegetable oils from the field of Washing products that contain selected surfactant mixtures and the use of special surfactant mixtures for the production of stable vegetable oil-containing washing products.

State of the art

Notwithstanding the fact that frequent washing of skin and hair is the natural, deprives protective grease film, leads to increased dehydration and skin and hair so that it is vulnerable to external influences, frequent washes still correspond to that today's ideal of purity.

The company tries to counteract the susceptibility to damaging environmental influences Cosmetics industry with a wide variety of auxiliaries and additives in washing preparations reduce increased risk of dehydration. Two principles are followed. On the one hand, hygroscopic substances that are found in the stratum corneum store and bind water, the moisture of the skin is kept. The binding capacity of the stratum corneum regarding these substances during the washing process however, be critically questioned. On the other hand, the skin is occluded Lipophilic basics keep the body's water in the skin longer. Especially well-tolerated and biodegradable lipophilic bases are oils of vegetable origin. However, larger amounts of vegetable oils often lead to instability Washing formulations, to reduce the washing capacity or to one uncomfortable feeling on the skin after application.

In the European patent EP 0 744 936 B1 skin and Hair treatment agent with alkyl polyglycosides, a polymer and a vegetable oil discloses a combined, especially in the form of hair aftertreatment Use of various active ingredients to enable the wet and Improve dry combability, are effective against split ends and to a better one Color distribution of hair dyes lead. In these formulations up to 5% by weight Processed vegetable oils.

Wax-containing shampoos with small amounts of vegetable oils are also described in EP 0 505 616 A1 described.

The object of the present invention was to include washing preparations to provide large amounts of vegetable oils that are good physical and have chemical stability. The preparations should be well tolerated, one have a good washing effect, protect the skin and scalp from drying out and after leave a pleasant feeling on the skin.

Description of the invention

The invention relates to detergent-containing washing preparations containing at least 25% by weight vegetable oils.

Another object of the invention is the use of surfactant mixtures, containing alkyl and / or alkenyl oligoglycosides, amphoteric surfactants and optionally Cation polymers for the production of washing preparations with at least 25% by weight Vegetable oil.

Due to the stable incorporation of large amounts of vegetable oil, the skin dries out and scalp effectively reduced even with frequent washing and the moisture in the Skin held back. The washing preparations are characterized by good moisturizing and moisturizing properties. Surprisingly, it was found that the Preparations according to the invention an excellent despite the high oil content Wash performance, after use have a pleasant feeling on the skin without noticeable Leave a lubricating film and have good physical and chemical stability.

The combination of nonionic and amphoteric surfactants enables Physicochemically stable incorporation of large amounts of vegetable oils.

If you continue to use cationic in washing products for hair cosmetic use Polymers too, the conditioning effect, the combability and the stylability of the Hair improved even more sustainably.

surfactants

Nonionic, anionic, cationic and / or Amphoteric or zwitterionic surfactants may be included, their share in the agents usually about 10 to 90% by weight, preferably 20 to 70 and preferably 30 to Is 50% by weight. Typical examples of anionic surfactants are soaps, Alkyl benzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, α- Methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, Glycerol ether sulfates, fatty acid ether sulfates, hydroxy mixed ether sulfates, monoglyceride (ether) sulfates, Fatty acid amide (ether) sulfates, mono- and dialkyl sulfosuccinates, mono- and Dialkyl sulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, Fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, N-acylamino acids, such as for example acyl lactylates, acyl tartrates, acyl glutamates and acyl aspartates, Alkyl oligoglucoside sulfates, protein fatty acid condensates (especially vegetable products based on wheat) and alkyl (ether) phosphates. If the anionic surfactants contain polyglycol ether chains, they can be a conventional one, but preferably a restricted one Show homolog distribution. Typical examples of nonionic surfactants are Fatty alcohol polyglycol ether, alkyl phenol polyglycol ether, fatty acid polyglycol ester, Fatty acid amide polyglycol ether, fatty amine polyglycol ether, alkoxylated triglycerides, mixed ethers or mixed formals, optionally partially oxidized alk (en) yl oligoglycosides or Glucoronic acid derivatives, fatty acid N-alkylglucamides, protein hydrolyzates (in particular vegetable products based on wheat), polyol fatty acid esters, sugar esters, sorbitan esters, Polysorbates and amine oxides. If the nonionic surfactants contain polyglycol ether chains, they can be a conventional one, but preferably a restricted one Show homolog distribution. Typical examples of cationic surfactants are quaternary Ammonium compounds and ester quats, especially quaternized fatty acid trialkanolamine ester salts.

vegetable oils

Among the vegetable oils used - in contrast to volatile essential oils - understood fatty oils with a high proportion of di- and triglycerides. The vegetable oils mostly mentioned in EP 0 744 936 B1 come as examples Almond oil, walnut oil, peach kernel oil, avocado oil, soybean oil, sesame oil, sunflower seed oil, Tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango kernel oil, cuckoo flower oil, Safflower oil, macadamia nut oil, grape seed oil, apricot kernel oil, babassu oil, olive oil, Wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, jojoba oil, canola oil, sasanqua Oil, calendula oil, passion flower oil, Shorea Stenoptera butter and Shea butter as vegetable Oils into consideration.

Soybean oil, almond oil, jojoba oil, olive oil, sunflower seed oil, sesame oil, evening primrose oil, safflower oil and wheat germ oil are preferred among them. Soybean oil is particularly preferred.

At least 25% by weight, preferably at least 35% by weight and particularly preferably even at least 45% by weight Vegetable oils - based on the washing preparations used.

Alkyl and / or alkenyl oligoglycosides

Alkyl and alkenyl oligoglycosides are known nonionic surfactants which follow the formula (I)

R ¹ O- [G] _p (I)

in which R ^{1 is} an alkyl and / or alkenyl radical having 4 to 22 carbon atoms, G is a sugar radical having 5 or 6 carbon atoms and p is a number from 1 to 10. They can be obtained according to the relevant preparative organic chemistry methods. Representative of the extensive literature here is the review by Biermann et al. in Starch /force 45, 281 (1993), B. Salka in Cosm. Toil. 108, 89 (1993) and J. Kahre et al. in SÖFW-Journal issue 8, 598 (1995).

The alkyl and / or alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably glucose. The preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides. The index number p in the general formula (I) indicates the degree of oligomerization (DP), ie the distribution of mono- and oligoglycosides, and stands for a number between 1 and 10. While p must always be an integer in a given compound and especially here can assume the values p = 1 to 6, the value p for a specific alkyl oligo-glycoside is an analytically determined arithmetic parameter, which usually represents a fractional number. Alkyl and / or alkenyl oligoglycosides with an average degree of oligomerization p of 1.1 to 3.0 are preferably used. From an application point of view, preference is given to those alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and is in particular between 1.2 and 1.4. The alkyl or alkenyl radical R ¹ can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, capronic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as are obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxosynthesis. Alkyl oligoglucosides of chain length C ₈ -C ₁₀ (DP = 1 to 3) are preferred, which are obtained as a preliminary step in the separation of technical C ₈ -C ₁₈ coconut fatty alcohol by distillation and with a proportion of less than 6% by weight of C ₁₂ - Alcohol can be contaminated and alkyl oligoglucosides based on technical C _9/11 oxo alcohols (DP = 1 to 3). The alkyl or alkenyl radical R ¹ can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms. Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and the technical mixtures described above, which can be obtained as well as their technical mixtures. Alkyl oligoglucosides based on hardened C _12/14 coconut alcohol with a DP of 1 to 3 are preferred.

The alkyl oligoglucosides are used in amounts of 0.5 to 20% by weight, preferably 2.5 to 15 and particularly preferably 5 to 10% by weight, based on the washing preparation.

Amphoteric surfactants

Typical examples of amphoteric - also listed under "zwitterionic surfactants" - are Alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines. The surfactants mentioned are exclusively known Links. With regard to the structure and manufacture of these substances, the relevant Review articles for example J. Falbe (ed.), "Surfactants in Consumer Products", Springer Verlag, Berlin, 1987, pp. 54-124 or J. Falbe (ed.), "Catalysts, Surfactants and Mineral Oil Additives ", Thieme Verlag, Stuttgart, 1978, pp. 123-217 directed.

Betaine

Betaines are known surfactants which are predominantly prepared by carboxyalkylation, preferably carboxymethylation, of aminic compounds. The starting materials are preferably condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, one mol of salt being formed per mole of betaine. The addition of unsaturated carboxylic acids, such as acrylic acid, is also possible. Regarding the nomenclature and in particular the distinction between betaines and "real" amphoteric surfactants, reference is made to the contribution by U. Ploog in Seifen-Öle-Fette-Wwachs, 108, 373 (1982). Further overviews on this topic can be found, for example, by A. O'Lennick et al. in HAPPI, Nov. 70 (1986), S. Holzman et al. in tens. Surf. Det. 23, 309 (1986), R. Bibo et al. in Soap Cosm. Chem. Spec., Apr. 46 (1990) and P. Ellis et al. in Euro Cosm. 1, 14 (1994). Examples of suitable betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow the formula (II)


in which R ² for alkyl and / or alkenyl radicals with 6 to 22 carbon atoms, R ³ for hydrogen or alkyl radicals with 1 to 4 carbon atoms, R ⁴ for alkyl radicals with 1 to 4 carbon atoms, n for numbers from 1 to 6 and X for a Alkali and / or alkaline earth metal or ammonium. Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, De-cyldimethylamin, dodecylmethylamine, dodecyldimethylamine, Dodecylethylmethylamin, C _12/14 -Kokosalkyldimethylamin, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, Stearylethylmethyl-amine, oleyl dimethyl amine, C _16/18 tallow alkyl dimethyl amine, and their technical mixtures.

Carboxyalkylation products of amidoamines which follow the formula (III) are also suitable,


in which R ⁵ CO represents an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, m represents numbers from 1 to 3 and R ³ , R ⁴ , n and X have the meanings given above. Typical examples are reaction products of fatty acids with 6 to 22 carbon atoms, namely caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, arenachic acid, gadoleic acid, gadoleic acid, gadoleic acid, galenic acid and erucic acid and their technical mixtures, with N, N-dimethylaminoethylamine, N, N-dimethylaminopropylamine, N, N-diethylaminoethylamine and N, N-diethylaminopropylamine, which are condensed with sodium chloroacetate. It is preferred to use a condensation product of C _8/18 coconut fatty acid N, N-dimethylaminopropylamide with sodium chloroacetate.

Furthermore, suitable starting materials for the betaines to be used in accordance with the invention are also imidazolines which follow the formula (IV)


in which R ^{6 is} an alkyl radical having 5 to 21 carbon atoms, R ^{7 is} a hydroxyl group, an OCOR ⁶ or NHCOR ⁷ radical and m is 2 or 3. These substances are also known substances which can be obtained, for example, by cyclizing condensation of 1 or 2 moles of fatty acid with polyhydric amines, such as, for example, aminoethylethanolamine (AEEA) or diethylene triamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are condensation products of the above-mentioned fatty acids with AEEA, preferably imidazolines based on lauric acid or again C _12/14 coconut fatty acid, which are subsequently betainized with sodium chloroacetate.

The preferred amphoteric surfactants for the purposes of the present invention are Betaines of the cocamidopropyl betaine type and sodium cocoamphoacetate. The Amphoteric surfactants are used in amounts of 0.5 to 30% by weight, preferably 2.5 to 20% by weight. and particularly preferably 9 to 19% by weight, based on the washing preparations, used.

cationic polymers

Suitable cationic polymers are, for example, cationic cellulose derivatives, such as. B. a quaternized hydroxyethyl cellulose, which is marketed under the name Polymer JR 400® by Amerchol is available, cationic starch, copolymers of diallylammonium salts and Acrylamides, quaternized vinyl pyrrolidone / vinyl imidazole polymers, such as. B. Luviquat® (BASF), condensation products of polyglycols and amines, quaternized Collagen polypeptides such as Lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®L / Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic Silicone polymers such as e.g. B. amidomethicones, copolymers of adipic acid and Dimethylaminohydroxypropyldiethylenetriamine (Cartaretine® / Sandoz), copolymers of acrylic acid with Dimethyldiallyl ammonium chloride (Merquat® 550 / Chemviron), polyaminopolyamides, such as B. described in FR-A 2252840 and its crosslinked water-soluble polymers, cationic chitin derivatives, such as, for example, quaternized chitosan, if appropriate microcrystalline distributed, condensation products from dihaloalkylene, such as. B. dibromobutane with bisdialkylamines, such as. B. bis-dimethylamino-1,3-propane, cationic guar gum, such as z. B. Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese, quaternized Ammonium salt polymers, such as. B. Mirapol® A-15, Mirapol® AD-1, Mirapol® A2-1 from the company Miranol.

Cation polymers are used in the agents according to the invention in amounts of 0.02 to 5% by weight, preferably 0.05 to 3% by weight and particularly preferably in amounts of 0.1 to 2% by weight used. For optimal implementation of the positive synergistic Conditioning effect of the combination of cation polymers and predispersed Wax dispersions should average the molecular weights of the cationic polymers between 5000 and 1,000,000, preferably between 8,000 and 500,000, and especially preferably between 10,000 and 400,000.

Cationic guar gum and / or quaternized are particularly preferred as cation polymers Ammonium salt polymers.

Cation polymers are used in the washing preparations according to the invention in amounts of 0.1 up to 5% by weight, preferably 0.5 to 4% by weight and particularly preferably 1 to 3% by weight - based on the washing preparations used.

wax dispersions

Predispersed wax dispersions in amounts from 0 to 5% by weight, preferably 0.005 to 3.5% by weight and particularly preferably in amounts of 0.01 up to 3.1 wt .-% are used.

The proportion of the wax bodies contained in the wax dispersions is 10 to 40% by weight, preferably 15 to 35 wt .-% and particularly preferably 20 to 30 wt .-% - based on the predispersed wax dispersion. The wax dispersions come in as wax bodies Question: alkylene glycol esters, fatty acid alkanolamides, partial glycerides, esters of polyvalent, optionally hydroxy-substituted carboxylic acids, fatty alcohols, fatty ketones, fatty aldehydes, Fat ethers, fat carbonates, ring opening products of olefin epoxides and their Mixtures.

The alkylene glycol esters which form the preferred wax bodies are usually mono- and / or diesters of alkylene glycols which follow the formula (V)

R ⁸ CO (OA) _n OR ⁹ (V)

in which R ⁸ CO is a linear or branched, saturated or unsaturated acyl radical having 6 to 22 carbon atoms, R ^{9 is} hydrogen or R ⁸ CO and A is a linear or branched alkylene radical having 2 to 4 carbon atoms and n is a number from 1 to 5 stands. Typical examples are mono- and / or diesters of ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, triethylene glycol or tetraethylene glycol with fatty acids with 6 to 22, preferably 12 to 18 carbon atoms as there are: caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid , Myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures. The use of ethylene glycol mono- and / or distearate is particularly preferred.

water content

Due to the high oil and surfactant content, the water content of the formulations must be relative be small. A good physico-chemical stability of the washing preparations has been achieved achieved when the pure water content is at most 55% by weight, preferably at most 45% by weight and particularly preferably at most 35% by weight, based on the washing preparation was.

Industrial applicability

The vegetable oil-containing washing preparations according to the invention are predominantly, however not used exclusively in the field of cosmetic products.

• a) mindestens 25 Gew.-% Pflanzenöle,
• b) 0,5 bis 20 Gew.-% Alkylpolyglycoside,
• c) 0,5 bis 20 Gew.-% amphotere Tenside und
• d) maximal 55 Gew.-% Wasser,

bevorzugt enthalten die erfindungsgemäßen Waschzubereitungen

• a) mindestens 35 Gew.-% Pflanzenöle,
• b) 2,5 bis 15 Gew.-% Alkylpolyglycoside,
• c) 2,5 bis 20 Gew.-% amphotere Tenside und
• d) maximal 45 Gew.-% Wasser

besonders bevorzugt enthalten sie

• a) mindestens 45 Gew.-% Pflanzenöle,
• b) 5 bis 10 Gew.-% Alkylpolyglycoside,
• c) 9 bis 19 Gew.-% amphotere Tenside und
• d) maximal 35 Gew.-% Wasser,

bevorzugter

• a) mindestens 45 Gew.-% Pflanzenöle,
• b) 5 bis 10 Gew.-% Alkylpolyglycoside,
• c) 9 bis 19 Gew.-% amphotere Tenside,
• d) maximal 35 Gew.-% Wasser,
• e) 0,1 bis 5 Gew.-% Kationpolymere,

speziell bevorzugt

• a) mindestens 45 Gew.-% Pflanzenöle,
• b) 5 bis 10 Gew.-% Alkylpolyglycoside,
• c) 9 bis 16 Gew.-% Betaine,
• d) maximal 35 Gew.-% Wasser,
• e) 1 bis 3 Gew. Kationpolymere und
• f) 0,005 bis 3,5 Gew.-% Wachsdispersionen

mit der Maßgabe, dass sich die Angaben mit Wasser und gegebenenfalls weiteren üblichen Hilfs- und Zusatzstoffen zu 100 Gew.-% addieren. Embodiments of the washing preparations according to the invention contain:

• a) at least 25% by weight of vegetable oils,
• b) 0.5 to 20% by weight of alkyl polyglycosides,
• c) 0.5 to 20 wt .-% amphoteric surfactants and
• d) a maximum of 55% by weight of water,

the washing preparations according to the invention preferably contain

• a) at least 35% by weight of vegetable oils,
• b) 2.5 to 15% by weight of alkyl polyglycosides,
• c) 2.5 to 20 wt .-% amphoteric surfactants and
• d) a maximum of 45% by weight of water

they particularly preferably contain

• a) at least 45% by weight of vegetable oils,
• b) 5 to 10% by weight of alkyl polyglycosides,
• c) 9 to 19% by weight of amphoteric surfactants and
• d) a maximum of 35% by weight of water,

preferred

• a) at least 45% by weight of vegetable oils,
• b) 5 to 10% by weight of alkyl polyglycosides,
• c) 9 to 19% by weight of amphoteric surfactants,
• d) a maximum of 35% by weight of water,
• e) 0.1 to 5% by weight of cation polymers,

especially preferred

• a) at least 45% by weight of vegetable oils,
• b) 5 to 10% by weight of alkyl polyglycosides,
• c) 9 to 16% by weight betaines,
• d) a maximum of 35% by weight of water,
• e) 1 to 3 wt. cation polymers and
• f) 0.005 to 3.5 wt .-% wax dispersions

with the proviso that the information with water and possibly other customary auxiliaries and additives add up to 100% by weight.

The preparations according to the invention can be used as cosmetic and / or pharmaceutical Preparations such as hair shampoos, solid bars of soap, washing lotions, Foam baths, shower baths and preferably oil baths are used.

As further auxiliaries and additives, they can also contain emulsifiers, further oil bodies, Pearlescent waxes, consistency enhancers, superfatting agents, stabilizers, other polymers, Silicone compounds, lecithins, phospholipids, biogenic agents, antioxidants, Antidandruff agents, film formers, hydrotropes, solubilizers, preservatives, Perfume oils, dyes and the like included.

emulsifiers

• - Anlagerungsprodukte von 2 bis 30 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare Fettalkohole mit 8 bis 22 C-Atomen, an Fettsäuren mit 12 bis 22 C-Atomen, an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe sowie Alkylamine mit 8 bis 22 Kohlenstoffatomen im Alkylrest;
• - Anlagerungsprodukte von 1 bis 15 Mol Ethylenoxid an Ricinusöl und/oder gehärtetes Ricinusöl;
• - Anlagerungsprodukte von 15 bis 60 Mol Ethylenoxid an Ricinusöl und/oder gehärtetes Ricinusöl;
• - Partialester von Glycerin und/oder Sorbitan mit ungesättigten, linearen oder gesättigten, verzweigten Fettsäuren mit 12 bis 22 Kohlenstoffatomen und/oder Hydroxycarbonsäuren mit 3 bis 18 Kohlenstoffatomen sowie deren Addukte mit 1 bis 30 Mol Ethylenoxid;
• - Partialester von Polyglycerin (durchschnittlicher Eigenkondensationsgrad 2 bis 8), Polyethylenglycol (Molekulargewicht 400 bis 5000), Trimethylolpropan, Pentaerythrit, Zuckeralkoholen (z. B. Sorbit), Alkylglucosiden (z. B. Methylglucosid, Butylglucosid, Laurylglucosid) sowie Polyglucosiden (z. B. Cellulose) mit gesättigten und/oder ungesättigten, linearen oder verzweigten Fettsäuren mit 12 bis 22 Kohlenstoffatomen und/oder Hydroxycarbonsäuren mit 3 bis 18 Kohlenstoffatomen sowie deren Addukte mit 1 bis 30 Mol Ethylenoxid;
• - Mischester aus Pentaerythrit, Fettsäuren, Citronensäure und Fettalkohol gemäß DE 11 65 574 PS und/oder Mischester von Fettsäuren mit 6 bis 22 Kohlenstoffatomen, Methylglucose und Polyolen, vorzugsweise Glycerin oder Polyglycerin.
• - Mono-, Di- und Trialkylphosphate sowie Mono-, Di- und/oder Tri-PEG-alkylphosphate und deren Salze;
• - Wollwachsalkohole;
• - Polysiloxan-Polyalkyl-Polyether-Copolymere bzw. entsprechende Derivate;
• - Block-Copolymere z. B. Polyethylenglycol-30 Dipolyhydroxystearate;
• - Polymeremulgatoren, z. B. Pemulen-Typen (TR-1, TR-2) von Goodrich;
• - Polyalkylenglycole sowie
• - Glycerincarbonat.

In addition to the preferred surfactants mentioned above, suitable emulsifiers are, for example, nonionic substances from at least one of the following groups:

• - Adducts of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear fatty alcohols with 8 to 22 carbon atoms, with fatty acids with 12 to 22 carbon atoms, with alkylphenols with 8 to 15 carbon atoms in the alkyl group and Alkylamines with 8 to 22 carbon atoms in the alkyl radical;
• - Adducts of 1 to 15 moles of ethylene oxide with castor oil and / or hydrogenated castor oil;
• - Adducts of 15 to 60 moles of ethylene oxide with castor oil and / or hydrogenated castor oil;
• Partial esters of glycerol and / or sorbitan with unsaturated, linear or saturated, branched fatty acids with 12 to 22 carbon atoms and / or hydroxycarboxylic acids with 3 to 18 carbon atoms and their adducts with 1 to 30 mol of ethylene oxide;
• - Partial esters of polyglycerol (average degree of self-condensation 2 to 8), polyethylene glycol (molecular weight 400 to 5000), trimethylolpropane, pentaerythritol, sugar alcohols (e.g. sorbitol), alkyl glucosides (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) as well as polyglucosides B. cellulose) with saturated and / or unsaturated, linear or branched fatty acids with 12 to 22 carbon atoms and / or hydroxycarboxylic acids with 3 to 18 carbon atoms and their adducts with 1 to 30 moles of ethylene oxide;
• - Mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol according to DE 11 65 574 PS and / or mixed esters of fatty acids with 6 to 22 carbon atoms, methyl glucose and polyols, preferably glycerol or polyglycerol.
• - Mono-, di- and trialkyl phosphates as well as mono-, di- and / or tri-PEG-alkyl phosphates and their salts;
• - wool wax alcohols;
• - Polysiloxane-polyalkyl-polyether copolymers or corresponding derivatives;
• - Block copolymers e.g. B. Polyethylene glycol 30 dipolyhydroxystearate;
• - polymer emulsifiers, e.g. B. Pemulen types (TR-1, TR-2) from Goodrich;
• - Polyalkylene glycols as well
• - glycerine carbonate.

Ethylene Oxide

The adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols or with castor oil are known, commercially available products. These are mixtures of homologs, the average degree of alkoxylation of which is the ratio of the amounts of ethylene oxide and / or propylene oxide and substrate, with which the addition reaction is carried out. C _12/18 - fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE 20 24 051 PS as refatting agents for cosmetic preparations.

partial glycerides

Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, Hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, Oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid moglyceride, ricinoleic acid diglyceride, Linoleic acid monoglyceride, linoleic acid diglyceride, linolenic acid monoglyceride, Linolenic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, Tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, Citric diglyceride, malic acid monoglyceride, malic acid diglyceride and their technical Mixtures that are subordinate to the manufacturing process still have small amounts May contain triglyceride. Addition products from 1 to 30 are also suitable, preferably 5 to 10 moles of ethylene oxide to the partial glycerides mentioned.

sorbitan

Sorbitan monoisostearate, sorbitan sesquusostearate, Sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, Sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, Sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diricinoleate, Sorbitan triricinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, Sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, Sorbitan sesqui-tartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, Sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, Sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and their technical Mixtures. Addition products of 1 to 30, preferably 5, are also suitable up to 10 moles of ethylene oxide to the sorbitan esters mentioned.

polyglycerol

Typical examples of suitable polyglycerol esters are polyglyceryl-2 Dipolyhydroxystearate (Dehymuls® PGPH), polyglycerol-3-diisostearate (Lameform® TGI), polyglyceryl-4 isostearate (Isolan® GI 34), polyglyceryl-3 oleate, diisostearoyl Polyglyceryl-3 diisostearate (Isolan® PDI), Polyglyceryl-3 methylglucose distearate (Tego Care® 450), Polyglyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether (Chimexane® NL), Polyglyceryl-3 distearate (Cremophor® GS 32) and Polyglyceryl Polyricinoleate (Admul® WOL 1403) Polyglyceryl Dimerate Isostearate and their mixtures. examples for further suitable polyol esters are those optionally with 1 to 30 moles of ethylene oxide implemented mono-, di- and triesters of trimethylolpropane or pentaerythritol with Lauric acid, coconut fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, Behenic acid and the like.

Anionic emulsifiers

Typical anionic emulsifiers are aliphatic fatty acids with 12 to 22 Carbon atoms, such as, for example, palmitic acid, stearic acid or behenic acid, and dicarboxylic acids with 12 to 22 carbon atoms, such as azelaic acid or sebacic acid.

oil body

In addition to the obligatory oils of vegetable origin, smaller amounts of other oil bodies can also be used in the washing preparations according to the invention, such as Guerbet alcohols based on fatty alcohols with 6 to 18, preferably 8 to 10 carbon atoms, esters of linear C ₆ -C ₂₂ fatty acids with linear or branched C ₆ -C ₂₂ fatty alcohols or esters of branched C ₆ -C ₁₃ carboxylic acids with linear or branched C ₆ -C ₂₂ fatty alcohols, such as. B. myristyl myristate, myristyl palmitate, myristyl stearate, Myristylisostearat, myristyl, Myristylbehenat, Myristylerucat, cetyl myristate, cetyl palmitate, cetyl stearate, Cetylisostearat, cetyl oleate, cetyl behenate, Cetylerucat, Stearylmyristat, stearyl palmitate, stearyl stearate, Stearylisostearat, stearyl oleate, stearyl behenate, Stearylerucat, isostearyl, isostearyl palmitate, Isostearylstearat, isostearyl isostearate, Isostearyloleat, isostearyl behenate, Isostearyloleat, oleyl, oleyl palmitate, oleyl stearate, oleyl isostearate, oleate, Oleylbehenat, oleyl, behenyl myristate, behenyl, behenyl, Behenylisostearat, behenyl oleate, behenyl, erucyl, erucyl, erucyl, erucyl, erucyl, erucyl, erucyl behenate and erucyl. In addition, esters of linear C ₆ -C ₂₂ fatty acids with branched alcohols, in particular 2-ethylhexanol, esters of C ₁₈ -C ₃₈ alkylhydroxycarboxylic acids with linear or branched C ₆ -C ₂₂ fatty alcohols are suitable (cf. DE 197 56 377 A1 ), especially dioctyl malates, esters of linear and / or branched fatty acids with polyhydric alcohols (such as propylene glycol, dimer diol or trimer triol) and / or Guerbet alcohols, triglycerides based on C ₆ -C ₁₀ fatty acids, liquid mono- / di - / Triglyceride mixtures based on C ₆ -C ₁₈ fatty acids, esters of C ₆ -C ₂₂ fatty alcohols and / or Guerbet alcohols with aromatic carboxylic acids, especially benzoic acid, esters of C ₂ -C ₁₂ dicarboxylic acids with linear or branched alcohols with 1 up to 22 carbon atoms or polyols with 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, branched primary alcohols, substituted cyclohexanes, linear and branched C ₆ -C ₂₂ fatty alcohol carbonates, such as. B. dicaprylyl carbonates (Cetiol® CC), Guerbet carbonates based on fatty alcohols with 6 to 18, preferably 8 to 10 C atoms, esters of benzoic acid with linear and / or branched C ₆ -C ₂₂ alcohols (e.g. Finsolv® TN), linear or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as. B. dicaprylyl ether (Cetiol® OE), ring opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicones, silicon methicone types, etc.) and / or aliphatic or naphthenic hydrocarbons, such as. B. like squalane, squalene or dialkylcyclohexanes.

pearlescent

Pearlescent waxes, for example, are: alkylene glycol esters, specifically ethylene glycol; Fatty acid alkanolamides, especially coconut fatty acid diethanolamide; Partial glycerides, especially stearic acid monoglyceride; Esters of polyvalent, if necessary hydroxy-substituted carboxylic acids with fatty alcohols with 6 to 22 carbon atoms, especially long chain esters of tartaric acid; Fatty substances, such as fatty alcohols, Fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, totaling at least 24 Have carbon atoms, especially lauron and distearyl ether; Fatty acids like Stearic acid, hydroxystearic acid or behenic acid, ring opening products of olefin epoxides with 12 to 22 carbon atoms with fatty alcohols.

Consistency agents and thickeners

The main consistency agents are fatty alcohols or hydroxy fatty alcohols from 12 to 22 and preferably 16 to 18 carbon atoms and in addition partial glycerides, fatty acids or hydroxy fatty acids. A combination of these substances with is preferred Alkyl oligoglucosides and / or fatty acid N-methylglucamides of the same chain length and / or Polyglycerol poly-12-hydroxy stearates. Suitable thickeners are, for example Aerosil types (hydrophilic silicas), polysaccharides, especially xanthan gum, agar Agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl and Hydroxypropyl cellulose, also higher molecular weight polyethylene glycol mono- and diesters of Fatty acids, polyacrylates, (e.g. Carbopole® and Pemulen types from Goodrich; Synthalene® from Sigma; Keltrol types from Kelco; Seppic Sepigel types; Salcare types from Allied Colloids), polyacrylamides, polymers, polyvinyl alcohol and polyvinyl pyrrolidone. As special Bentonites, such as B. Bentone® Gel VS-5PC (Rheox) which is a mixture of cyclopentasiloxane, disteardimonium hectorite and Is propylene carbonate. Surfactants such as ethoxylated are also suitable Fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or Trimethylolpropane, fatty alcohol ethoxylates with a narrow homolog distribution or Alkyl oligoglucosides as well as electrolytes such as table salt and ammonium chloride.

superfatting

Substances such as lanolin and lecithin as well as polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, Monoglycerides and fatty acid alkanolamides are used, the latter also serve as foam stabilizers.

stabilizers

Metal salts of fatty acids, such as. B. magnesium, aluminum and / or zinc stearate or ricinoleate can be used.

polymers

The preferred polymers are the cation polymers already described. However, it can other polymers can also be used.

Coming as anionic, zwitterionic, amphoteric and nonionic polymers for example vinyl acetate / crotonic acid copolymers, vinyl pyrrolidone / vinyl acrylate copolymers, Vinyl acetate / butyl maleate / isobornyl acrylate copolymers, Methyl vinyl ether / maleic anhydride copolymers and their esters, uncrosslinked and crosslinked with polyols Polyacrylic acids, acrylamidopropyltrimethylammonium chloride / acrylate copolymers, Octylacrylamide / Methylmeth acrylate / tert.Butylaminoethylmethacrylat / 2 Hydroxypropylmethacrylat- Copolymers, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, Vinylpyrrolidone / dimethylaminoethyl methacrylate / vinylcaprolactam terpolymers and optionally derivatized cellulose ethers and silicones in question. Other suitable polymers and Thickeners are in Cosm. Toil. 108, 95 (1993).

silicone compounds

Suitable silicone compounds are, for example, dimethylpolysiloxanes, Methylphenylpolysiloxanes, cyclic silicones as well as amino, fatty acid, alcohol, polyether, epoxy, fluorine, glycoside and / or alkyl modified silicone compounds, which in Room temperature can be both liquid and resinous. Also suitable are simethicones, which are mixtures of dimethicones with a average chain length of 200 to 300 dimethylsiloxane units and hydrogenated Silicates. A detailed overview of suitable volatile silicones can be found also by Todd et al. in cosm. Toil. 91, 27 (1976).

Biogenic agents

Examples of biogenic active ingredients are tocopherol, tocopherol acetate, Tocopherol palmitate, ascorbic acid, (deoxy) ribonucleic acid and their Fragmentation products, β-glucans, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts, such as B. Prunus extract, Bambaranus extract and vitamin complexes to understand.

film formers

Common film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or their Salts and similar compounds.

Antidandruff agents

Piroctone olamine (1-hydroxy-4-methyl-6- (2,4,4- trimythylpentyl) -2- (1H) -pyridinone monoethanolamine salt), Baypival® (Climbazole), Ketoconazol®, (4-acetyl-1 - {- 4- [2- (2.4-dichlorophenyl) r-2- (1H-imidazol-1-ylmethyl) -1,3- dioxylan-c-4-ylmethoxyphenyl} piperazine, ketoconazole, elubiol, selenium disulfide, sulfur colloidal, sulfur polyethylene glycol sorbitan monooleate, sulfur ricinole polyoxyethylene, Sulfur tar distillates, salicylic acid (or in combination with hexachlorophene), Undexylenic acid monoethanolamide sulfosuccinate sodium salt, Lamepon® UD (protein Undecylenic acid condensate), zinc pyrithione, aluminum pyrithione and Magnesium pyrithione / dipyrithione magnesium sulfate in question.

hydrotropes

• - Glycerin;
• - Alkylenglycole, wie beispielsweise Ethylenglycol, Diethylenglycol, Propylenglycol, Butylenglycol, Hexylenglycol sowie Polyethylenglycole mit einem durchschnittlichen Molekulargewicht von 100 bis 1.000 Dalton;
• - technische Oligoglyceringemische mit einem Eigenkondensationsgrad von 1,5 bis 10 wie etwa technische Diglyceringemische mit einem Diglyceringehalt von 40 bis 50 Gew.-%;
• - Methyolverbindungen, wie insbesondere Trimethylolethan, Trimethylolpropan, Trimethylolbutan, Pentaerythrit und Dipentaerythrit;
• - Niedrigalkylglucoside, insbesondere solche mit 1 bis 8 Kohlenstoffen im Alkylrest, wie beispielsweise Methyl- und Butylglucosid;
• - Zuckeralkohole mit 5 bis 12 Kohlenstoffatomen, wie beispielsweise Sorbit oder Mannit,
• - Zucker mit 5 bis 12 Kohlenstoffatomen, wie beispielsweise Glucose oder Saccharose;
• - Aminozucker, wie beispielsweise Glucamin;
• - Dialkoholamine, wie Diethanolamin oder 2-Amino-1,3-propandiol.

Hydrotropes such as ethanol, isopropyl alcohol or polyols can also be used to improve the flow behavior. Polyols that come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols can also contain further functional groups, in particular amino groups, or be modified with nitrogen. Typical examples are

• - glycerin;
• - Alkylene glycols, such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons;
• technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10 such as technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight;
• - Methyl compounds, such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
• - Lower alkyl glucosides, especially those with 1 to 8 carbons in the alkyl radical, such as methyl and butyl glucoside;
• Sugar alcohols having 5 to 12 carbon atoms, such as sorbitol or mannitol,
• - Sugar with 5 to 12 carbon atoms, such as glucose or sucrose;
• - aminosugars such as glucamine;
• - Dialcohol amines, such as diethanolamine or 2-amino-1,3-propanediol.

preservative

Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, Parabens, pentanediol or sorbic acid as well as those under the name Surfacine® known silver complexes and those in Appendix 6, Parts A and B of the Cosmetics Ordinance listed further substance classes.

Perfume oils and flavors

Perfume oils include mixtures of natural and synthetic fragrances.

Natural fragrances are extracts of flowers (lily, lavender, roses, jasmine, neroli, ylang- Ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, Caraway, juniper), fruit peels (bergamot, lemon, oranges), roots (mace, Angelica, Celery, Cardamom, Costus, Iris, Calmus), Woods (Pine, Sandal, Guaiac, Cedarwood, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), needles and twigs (spruce, fir, pine, mountain pine), resins and balsams (Galbanum, Elemi, Benzoin, myrrh, olibanum, opoponax). Animal raw materials are also possible, such as for example civet and castoreum. Typical synthetic fragrance compounds are Products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Fragrance compounds of the ester type are e.g. B. benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate, phenylethyl acetate, Linalyl benzoate, benzyl formate, ethyl methylphenyl glycinate, allyl cyclohexyl propionate, Styrallyl propionate and benzyl salicylate. The ethers include, for example, benzyl ethyl ether, to the aldehydes e.g. B. the linear alkanals with 8 to 18 carbon atoms, citral, Citronellal, Citronellyloxyacetaldehyde, Cyclamenaldehyde, Hydroxycitronellal, Lilial and Bourgeonal, to the ketones z. B. the Jonone, α-isomethylionone and methylcedryl ketone the alcohols anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, Phenylethyl alcohol and terpineol, the hydrocarbons mainly include the terpenes and balms. However, mixtures of different fragrances are preferably used, which together create an appealing fragrance. Also essential oils less Volatility, which are mostly used as aroma components, are suitable as perfume oils, z. B. sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, Juniper berry oil, vetiver oil, ofiban oil, galbanum oil, labolanum oil and lavandin oil. Bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, Phenylethyl alcohol, α-hexyl cinnamaldehyde, geraniol, benzylacetone, cyclamenaldehyde, linalool, Boisambrene Forte, Ambroxan, Indole, Hedione, Sandelice, lemon oil, mandarin oil, Orange oil, allylamyl glycolate, cyclover valley, lavandin oil, muscatel sage oil, β-damascone, Geranium oil bourbon, cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, Evernyl, Iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilllate, irotyl and Floramat used alone or in mixtures.

For example, peppermint oil, spearmint oil, anise oil, star anise oil, Caraway oil, eucalyptus oil, fennel oil, lemon oil, wintergreen oil, clove oil, menthol and the like in question.

dyes

Suitable dyes are those which are suitable and approved for cosmetic purposes are used, such as those used in the publication "Cosmetic Colorants" the dye commission of the German Research Foundation, publisher Chemie, Weinheim, 1984, pp. 81-106 are compiled. Examples are cooking ale red A (C.I. 16255), Patent Blue V (C.I. 42051), Indigotin (C.I. 73015), Chlorophyllin (C.I. 75810), Quinoline yellow (C.I. 47005), titanium dioxide (C.I. 77891), indanthrene blue RS (C.I. 69800) and Madder varnish (C.I. 58000). Luminol may also be present as the luminescent dye. This Dyes are usually used in concentrations of 0.001 to 0.1% by weight the whole mixture.

Examples Oil shower bath with soybean oil

manufacturing

The production takes place at room temperature. All substances become homogeneous together mixed.

Claims (10)

1. Containing surfactant-containing washing preparations at least 25% by weight of a vegetable oil 2. Washing preparations according to claim 1, characterized in that they are used as surfactants nonionic and / or anionic and / or cationic and / or amphoteric and / or contain zwitterionic surfactants. 3. washing preparations according to claims 1 and / or 2, characterized in that they contain alkyl and / or alkenyl oligoglycosides of the formula (I) as nonionic surfactants,

R ¹ O- [G] _p (I)

in which R ^{1 is} an alkyl and / or alkenyl radical having 4 to 22 carbon atoms, G is a sugar radical having 5 or 6 carbon atoms and p is a number from 1 to 10. 4. washing preparations according to at least one of claims 1 to 3, characterized characterized that they act as amphoteric surfactants betaines and / or amphoacetates contain. 5. washing preparations according to at least one of claims 1 to 4, characterized characterized in that they contain cation polymers as a further component. 6. washing preparations according to at least one of claims 1 to 5, characterized characterized that they contain wax dispersions. 7. washing preparations according to at least one of claims 1 to 6, characterized characterized that they contain a maximum of 55 wt .-% water. 8. washing preparations according to at least one of claims 1 to 7, characterized characterized in that they contain vegetable oils selected from the group consisting of is formed from soybean oil, almond oil, jojoba oil, olive oil, sunflower seed oil, sesame oil, Evening primrose oil, safflower oil and wheat germ oil. 9. washing preparations according to at least one of claims 1 to 8, characterized in that they a) at least 25% by weight of vegetable oils, b) 0.5 to 20% by weight of alkyl and / or alkenyl oligoglycosides, c) 0.5 to 30% by weight of amphoteric surfactants, d) 0 to 5 wt .-% cation polymers with the proviso that the information with water and other usual auxiliaries and additives add up to 100% by weight. 10. Use of mixtures containing alkyl and / or alkenyl oligoglycosides, amphoteric surfactants and optionally cationic polymers for the production of Washing preparations with at least 25% by weight of vegetable oils.