GB2450037A - Dual Metal Schottky Diode - Google Patents

Dual Metal Schottky Diode Download PDF

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Publication number
GB2450037A
GB2450037A GB0817102A GB0817102A GB2450037A GB 2450037 A GB2450037 A GB 2450037A GB 0817102 A GB0817102 A GB 0817102A GB 0817102 A GB0817102 A GB 0817102A GB 2450037 A GB2450037 A GB 2450037A
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GB
United Kingdom
Prior art keywords
metal
schottky diode
layer
barrier layer
metal area
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB0817102A
Other versions
GB0817102D0 (en
GB2450037B (en
Inventor
Richard B Irwin
Tony T Phan
Hong-Ryong Kim
Ming-Yeh Chuang
Jennifer S Dumin
Patrick J Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Texas Instruments Inc
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Texas Instruments Inc
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Filing date
Publication date
Priority claimed from US10/814,673 external-priority patent/US6972470B2/en
Application filed by Texas Instruments Inc filed Critical Texas Instruments Inc
Priority to GB0817102A priority Critical patent/GB2450037B/en
Publication of GB0817102D0 publication Critical patent/GB0817102D0/en
Publication of GB2450037A publication Critical patent/GB2450037A/en
Application granted granted Critical
Publication of GB2450037B publication Critical patent/GB2450037B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
    • H01L21/28512Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table
    • H01L21/28537Deposition of Schottky electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/47Schottky barrier electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66083Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by variation of the electric current supplied or the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. two-terminal devices
    • H01L29/6609Diodes
    • H01L29/66143Schottky diodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/86Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
    • H01L29/861Diodes
    • H01L29/872Schottky diodes

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrodes Of Semiconductors (AREA)

Abstract

A Schottky diode 22 comprising: a semiconductor substrate 3 including silicon (Si), a first metal area 24 including platinum-silicide (PtSi) coupled to the semiconductor substrate, and a second metal area 28 including titanium-silicide (TiSi2), wherein the first metal area includes islands comprised of the first metal. In a further embodiment, a barrier layer 26 including e.g. silicon dioxide (SiO2) or silicon nitride (SiN) may be coupled to the first metal area with the second metal area coupled to the barrier layer.

Description

DUAL METAL SCHOTTKY DIODE
BACKGROUND OF THE INVENTION
This invention relates to the structure and method of making a dual metal Schottky diode.
BRIEF DESCRIPTION OF THE DRAWINGS
FIGS. lA-lB are cross-section views of a partial integrated circuit in accordance with a first embodiment of the present invention.
FIGS. 2-5 are cross-sectional diagrams of a process for forming the dual metal Schottky diode shown in FIG. lB.
FIGS. 6-7 are cross-sectional diagrams of a process for forming a dual metal Schottky diode in accordance with a second embodiment of the present invention.
FIGS. 8-10 are cross-sectional diagrams of a process for forming a dual metal Schottky diode in accordance with a third embodiment of the present invention.
Detailed Description of the Invention
Referring to the drawings, FIG. lA is a cross-section view of a partial integrated circuit 2 in accordance with a first embodiment of the present invention. The integrated circuit is divided into two parts based on the fabrication or process flow: the Front-End-Of -Line (FEOL) section 4 and the Back-End-Of -Line (BEOL) section 5. The section that includes the silicon substrate 3 is called the FEOL of the integrated circuit 2. In general, the FEOL section 4 is the transistor layer formed on (and within) the semiconductor substrate 3. The partial FEOL 4 shown in FIGS. 1A and lB includes a dual metal Schottky diode 22 of the present invention plus a transistor having a gate oxide 6, a gate electrode 7, and source/drain 8, 9; however, it is within the scope of the invention to have any form of logic within the FEOL section 4.
Immediately above the Schottky diode 22 and the transistor is a layer of dielectric insulation 10 containing metal contacts 11 that electrically tie the Schottky diode 22 and the transistor to the other logic elements (not shown) of the FEOL section 4.
Preferably, the dielectric insulation 10 is comprised of Si02 and the contacts 11 are comprised of W. However, the dielectric insulation 10 may be comprised of any suitable material such as SIN, SIC, SiON, or a low-k dielectric. In addition, the contacts may be comprised of any suitable material such as Al, Ti, or Cu.
The BEOL section 5 contains a single damascene metal layer 12 and at least one dual damascene metal layer 13. However, it is within the scope of the invention to have an integrated circuit 2 with only one (single or dual damascene) metal layer. Layers 12 and 13 contain metal lines 14, 15 that properly route electrical signals and power properly throughout the electronic device. Layer 13 also contains viasl6 that properly connect the metal lines of one metal layer (e.g. 14) to the metal lines of another metal layer (e.g. 15). The metal lines 14, 15 may be comprised of any suitable material such as Al. Furthermore, metal lines 14, 15 may be formed by any suitable process such as deposition, plating, or growth.
The single damascene metal layer 12 has dielectric material 17 and possibly a dielectric barrier layer 18 that electrically insulates the metal lines 14. Similarly, the dual damascene layer 13 contains dielectric material 19 and possibly a dielectric barrier layer 20 that electrically insulates metal lines 15 and vias 16.
In accordance with a preferred embodiment of the present invention, the integrated circuit 2 has a dual metal Schottky diode 22, shown in FIG. lB. The Schottky diode 22 consists of a lightly doped semiconductor substrate 3, a metal area (or metal islands) 24, a barrier layer 26, a metal area (or metal layer) 28, and a metal area (or metal layer) 30. The semiconductor substrate 3 may be comprised of any suitable material such as Si, GaAs, or InP (or a composite or layers of those elements) . In addition, the barrier layer 26 may be a Si02 or SIN dielectric film. However, other materials such as a deposited SIC or a spin-on-glass ("SOG") could be used for the barrier layer 26. Furthermore, the barrier layer 26 may be removed during the process of fabricating the Schottky diode 22.
Preferably, the metal islands 24 are comprised of PtS , the metal layer 28 is comprised of TiSi2 and the metal layer 30 is comprised of Ti. However, it is within the scope of the invention to have metal layers 24 and 28 comprised of any suitable materials such as CoSi2, VSI2, NiSi, NiSi2, ZrSi2, WSi2, TaSi2, MoSi2, or NbSi. Moreover, it is within the scope of the invention to omit barrier layer 26 and/or metal layer 30.
Referring again to the drawings, FIGS. 2-5 show the process for manufacturing the dual metal Schottky diode 22 shown in FIG. 13.
Before the dual metal Schottky diode is fabricated, a layer of photoresist (not shown) is applied and patterned using a lithography process. The openings in this photoresist layer define the locations and size of the dual metal Schottky diodes. In a preferred application, a barrier layer 26 is now formed over the entire substrate, The barrier layer may be formed using any manufacturing process such as Chemical Vapor Deposition ("CVD") or Plasma-Enhanced Chemical Vapor Deposition ("PECVD") . In addition, the barrier layer 26 may be formed chemically by reacting the silicon surface with an oxidizer (such as hydrogen peroxide or nitric acid) In this example application, the barrier layer 26 is comprised of Si02 and is 20A (20 nm) thick. However, it is within the scope of the invention to have any suitable barrier layer thickness appropriate for the composition of the dual metal layers 24, 28, the barrier composition, and the desired voltage drop Vf of the final dual metal Schottky diode.
Also as shown in FIG. 2, a first metal layer 23 is formed over the barrier layer 26. In a preferred application, the first metal layer 23 contains Pt and is approximately 300A thick. However, the thickness of the Pt layer 23 may be anything above 150A. In addition, the thickness of the first metal layer 23 may vary depending on the metal composition used.
The semiconductor wafer is now annealed. In the example application, a rapid thermal process ("RTP") is used to heat the wafer to approximately 5750 C for 30-60 seconds in an 02 and a N2 ambient. For example, a horizontal or vertical furnace may by used to heat the wafer to 500 C for 20 minutes in an 02 or a N2 ambient. During the anneal process the barrier layer 26 will limit the diffusion of Pt from the first layer metal 23 into the Si substrate 3.
After annealing, islands of PtSi 24 are formed within the semiconductor substrate 3, as shown in FIG. 3. It is to be noted that the temperature for the anneal process is selected so that the first metal layer 23 reacts with the semiconductor substrate 3 but not other materials such as the field oxides or gate oxides.
In a preferred application, the unreacted Pt layer 23 is now removed with an isotropic chemical etch process. More specifically, a standard chemical bench tool is used to etch Pt layer 23 (e.g. in a chemistry of H20:HC1:HNO for 10 minutes at 75 C). However, it is within the scope of the invention to use any method to remove the unreacted portions of the unreacted first metal layer 23. In addition, it is within the scope of the invention to perform an additional anneal after the removal of the unreacted Pt layer 23.
As shown in FIG. 4, a second metal layer 30 is formed over the semiconductor wafer (i.e. over the barrier layer 26 if the barrier layer is not removed, or over the silicon and first metal islands if the barrier layer is removed) . In a preferred application, the second metal layer 30 contains Ti and is approximately 400A thick.
However, the thickness of the Ti layer 30 may range from 300-800A.
In addition, the thickness of the second metal layer 30 may vary depending on the type of metal used.
The semiconductor wafer is now annealed. In the example application, a rapid thermal process ("RTP") is used to heat the wafer to approximately 625-750 C for 20-40 seconds in a N2 ambient. For example, a horizontal or vertical furnace may by used to heat the wafer to 600-675 C for 30-60 minutes in a N2 ambient.
After annealing, the Si from the semiconductor substrate 3 diffuses into the second metal layer 30 and forms a layer 28 of TIS12 24, as shown in FIG. 5. It is to be noted that the temperature for the anneal process is selected so that the second metal layer 30 reacts with the semiconductor substrate 3 but not other materials such as the field oxides or gate oxides.
In the example application, a step of etching the unreacted second metal layer 30 (or selected portions of that layer) is optional. If the second metal layer 30 is not removed than it may be used as an electrical contact for the dual metal Schottky diode 22. If the second metal layer 30 is removed, any well-known etch process may be used. For example, sulfuric based (piranha) chemistry or a chemistry of H20/H202 (5:1 ratio) at 40-60 C for 30-60 minutes may be used to strip the unreacted Ti (or the selected portions of Ti) . In the example application, a second anneal is now performed; however, this additional anneal is optional. Any standard process may be used for the second anneal.
For example, a Centura RTP could be used at 820-910 C for 10-30 seconds in a N2 ambient, or a furnace could be used to heat the wafer to 750-850 C in a N2 ambient for 30-60 minutes.
At this point, the fabrication of the semiconductor wafer continues until the integrated circuit is complete. That fabrication process would include the formation of contacts 11 shown in FIGS. 1A and lB that electrically connect the dual metal Schottky diode 22 to the proper components of the integrated circuit 2.
It is within the scope of the invention to use any suitable metal for the first metal area 24 and the second metal area 28 of the dual metal Schottky diode 22. As stated above, the metal components 24, 28 of the dual metal Schottky diode may be any suitable metal composition such as PtSi, TiSi2, CoSi2, VSi2, NiSi, ZrSi2, WS12, TaS12, MoSi2, or NbSi.
It is also within the scope of the invention to use one or more masks to create a dual metal Schottky diode 22 in any one of many configurations. An example variation of the dual metal Schottky diode 22 is shown in FIGS. 6-7. A first mask is used to form the areas (i.e. a first amount) of a Pt first metal 32 and a second mask is used to form the areas (i.e. a first amount) of a Ti second metal 34 shown in FIG. 6. After the anneal and subsequent etch of the unreacted metal 32 and 34, the final dual metal Schottky diode structure 22 would contain areas of PtSi 36 and areas of TiSi2 38, as shown in FIG. 7.
Alternatively, a lithography process could be used to create a patterned photoresist mask layer 40 that is then used to create sections of a Pt first metal 42, as shown in FIG. 8. After removing the exposed metal and ashing the semiconductor wafer to remove the photoresist layer 40, the semiconductor wafer is annealed to form areas of reacted PtSi 44, as shown in FIG. 9. In this alternative embodiment, a Ti second metal layer 46 is deposited and the wafer is then annealed to form a layer of reacted TIS12 48, as shown in FIG. 10.
When one or more masks are used to fabricate the Schottky diode in accordance with this invention, it is within the scope of the invention to use a dual metal Schottky diode with the barrier layer 26 removed. If such a diode is desired then the dual metal Schottky diode is fabricated without a barrier layer 26, or the barrier layer 26 is eliminated with the removal of the first unreacted metal or after the removal of the first unreacted metal.
Moreover, it is within the scope of the invention to use photoresist masks to create different dual metal Schottky diodes 22 throughout the integrated circuit 2. For example, patterned photoresist layers could be used throughout the fabrication process to form the dual metal Schottky diode 22 of FIG. 5 and the dual metal Schottky diode 22 of FIG. 10 at different locations within the same integrated circuit 2.
It is to be noted that a variety of structures and metals can be used to create a dual metal Schottky diode having a Vf that is anywhere between the Vf of a Schottky diode containing the first metal and the Vf of a Schottky diode containing the second metal.
Specifically, by using a barrier layer to limit the interaction of the first metal with the substrate, or by using a mask to apportion the area of the diode between the first and second metals, a Schottky diode can be fabricated to have any desired Vf between the Vf levels obtained with Schottky diodes comprised of single metals.
The use of one or more photoresist masks during wafer fabrication also facilitates the incorporation of dual metal Schottky diodes having different voltage drops at different locations throughout the integrated circuit 2.
Various modifications to the invention as described above are within the scope of the claimed invention. As an example, instead of placing the dual metal Schottky diode 22 immediately above the semiconductor substrate 3 as described above, the dual metal Schottky diode 22 may be placed in any location (or various locations simultaneously) within the front end section 4 or back end section 5 of the integrated circuit. Also, the present invention may be used in any integrated circuit configuration, including integrated circuits having different semiconductor substrates, metal layers, barrier layers, dielectric layers, device structures, active elements, passive elements, etc. In addition, barrier layer 26 may be a metal barrier film (TiSiN, TIN, TaN) instead of a dielectric barrier film. Furthermore, the invention can be used on a non-semiconductor substrate by using a deposited silicide formed by Chemical Vapor Deposition (using WSI), Physical Vapor Deposition (using a composite target), or by reactive sputtering. Moreover, the invention is applicable to other semiconductor technologies such as BiCMOS, bipolar, 301, strained silicon, pyroelectric sensors, opto-electronic devices, microelectrical mechanical system ("MEMS"), or SiGe.

Claims (7)

  1. S
    CLAIMS: 1. A Schottky diode comprising: a semiconductor substrate; a first metal area coupled to said semiconductor substrate; and a second metal area coupled to said first metal; wherein said first metal area includes islands comprised of said first metal.
  2. 2. A Schottky diode comprising: a semiconductor substrate; a first metal area coupled to said semiconductor substrate; a barrier layer coupled to said first metal area; and a second metal area coupled to said barrier layer.
    wherein said first metal area includes islands comprised of said first metal.
  3. 3. The Schottky diode of claim 2 wherein said barrier layer includes SiC2.
  4. 4. The Schottky diode of claim 2 wherein said barrier layer includes SiN.
  5. 5. The Schottky diode of any preceding claim, wherein said second metal area includes TiSi2.
  6. 6. The Schottky diode of any preceding claim, wherein said semiconductor substrate includes Si.
  7. 7. The Schottky diode of any preceding claim, wherein said first metal area includes PtSi.
GB0817102A 2004-03-30 2005-03-29 Schottky diode Expired - Fee Related GB2450037B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB0817102A GB2450037B (en) 2004-03-30 2005-03-29 Schottky diode

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/814,673 US6972470B2 (en) 2004-03-30 2004-03-30 Dual metal Schottky diode
GB0817102A GB2450037B (en) 2004-03-30 2005-03-29 Schottky diode
GB0506276A GB2412787B (en) 2004-03-30 2005-03-29 Dual metal schottky diode

Publications (3)

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GB0817102D0 GB0817102D0 (en) 2008-10-29
GB2450037A true GB2450037A (en) 2008-12-10
GB2450037B GB2450037B (en) 2009-05-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010132403A1 (en) * 2009-05-13 2010-11-18 Cree, Inc. Schottky diodes containing high barrier metal islands in a low barrier metal layer and methods of forming the same
CN103904133A (en) * 2014-03-19 2014-07-02 中航(重庆)微电子有限公司 Schottky diode balancing forward voltage drop and reverse leakage current and preparing method
CN104916864A (en) * 2015-05-08 2015-09-16 曾碚凯 Copper and aluminum bimetal bipolar plate type transitional unit lithium battery, high-voltage and low-internal resistance battery stack formed through serially connecting batteries, and packaging method of battery stack

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1188082A (en) * 1967-04-05 1970-04-15 Hitachi Ltd Method of making Semiconductor Device and Semiconductor Device made thereby
GB1289651A (en) * 1970-01-20 1972-09-20
GB1312171A (en) * 1970-05-12 1973-04-04 Siemens Ag Semiconductor arrangements for use as fixed value stores
GB1401554A (en) * 1972-04-14 1975-07-16 Ibm Met-semiconductor junction devices
US4096622A (en) * 1975-07-31 1978-06-27 General Motors Corporation Ion implanted Schottky barrier diode
JPH04365378A (en) * 1991-06-13 1992-12-17 Nec Corp Semiconductor integrated circuit

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1188082A (en) * 1967-04-05 1970-04-15 Hitachi Ltd Method of making Semiconductor Device and Semiconductor Device made thereby
GB1289651A (en) * 1970-01-20 1972-09-20
GB1312171A (en) * 1970-05-12 1973-04-04 Siemens Ag Semiconductor arrangements for use as fixed value stores
GB1401554A (en) * 1972-04-14 1975-07-16 Ibm Met-semiconductor junction devices
US4096622A (en) * 1975-07-31 1978-06-27 General Motors Corporation Ion implanted Schottky barrier diode
JPH04365378A (en) * 1991-06-13 1992-12-17 Nec Corp Semiconductor integrated circuit

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010132403A1 (en) * 2009-05-13 2010-11-18 Cree, Inc. Schottky diodes containing high barrier metal islands in a low barrier metal layer and methods of forming the same
US7915703B2 (en) 2009-05-13 2011-03-29 Cree, Inc. Schottky diodes containing high barrier metal islands in a low barrier metal layer and methods of forming the same
CN103904133A (en) * 2014-03-19 2014-07-02 中航(重庆)微电子有限公司 Schottky diode balancing forward voltage drop and reverse leakage current and preparing method
CN103904133B (en) * 2014-03-19 2017-01-18 中航(重庆)微电子有限公司 Schottky diode balancing forward voltage drop and reverse leakage current and preparing method
CN104916864A (en) * 2015-05-08 2015-09-16 曾碚凯 Copper and aluminum bimetal bipolar plate type transitional unit lithium battery, high-voltage and low-internal resistance battery stack formed through serially connecting batteries, and packaging method of battery stack
CN104916864B (en) * 2015-05-08 2018-01-16 深圳藈花新能源科技有限公司 The height that a kind of bipolar template transitionality unit lithium battery of Cu-Al bimetal and its series connection are formed forces down changeable internal damp bvattery heap and method for packing

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GB0817102D0 (en) 2008-10-29
GB2450037B (en) 2009-05-27

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