GB2430797A - A method of making a photoresistor - Google Patents

A method of making a photoresistor Download PDF

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Publication number
GB2430797A
GB2430797A GB0519746A GB0519746A GB2430797A GB 2430797 A GB2430797 A GB 2430797A GB 0519746 A GB0519746 A GB 0519746A GB 0519746 A GB0519746 A GB 0519746A GB 2430797 A GB2430797 A GB 2430797A
Authority
GB
United Kingdom
Prior art keywords
photosensitive material
photoresistor
electrode
substrate
cadmium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB0519746A
Other versions
GB0519746D0 (en
Inventor
Kelvin Ho Wang Cheng
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MACRON INTERNAT GROUP Ltd
Original Assignee
MACRON INTERNAT GROUP Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MACRON INTERNAT GROUP Ltd filed Critical MACRON INTERNAT GROUP Ltd
Priority to GB0519746A priority Critical patent/GB2430797A/en
Publication of GB0519746D0 publication Critical patent/GB0519746D0/en
Priority to PCT/IB2006/003888 priority patent/WO2008038064A1/en
Publication of GB2430797A publication Critical patent/GB2430797A/en
Withdrawn legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • H01L31/0264Inorganic materials
    • H01L31/0296Inorganic materials including, apart from doping material or other impurities, only AIIBVI compounds, e.g. CdS, ZnS, HgCdTe
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01CRESISTORS
    • H01C17/00Apparatus or processes specially adapted for manufacturing resistors
    • H01C17/06Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base
    • H01C17/075Apparatus or processes specially adapted for manufacturing resistors adapted for coating resistive material on a base by thin film techniques
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/085Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors the device being sensitive to very short wavelength, e.g. X-ray, Gamma-rays
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1828Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof the active layers comprising only AIIBVI compounds, e.g. CdS, ZnS, CdTe

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Thermistors And Varistors (AREA)
  • Chemically Coating (AREA)
  • Apparatuses And Processes For Manufacturing Resistors (AREA)
  • Photoreceptors In Electrophotography (AREA)

Abstract

A method of making a photoresistor by providing a substrate 2 and forming thereon a photosensitive material 3 in a desired pattern 7 by a masking spray method. An electrode (6, fig 3) is subsequently applied to the photosensitive material following the same pattern. The substrate can be a ceramic material, the photosensitive material can be a cadmium compound such as cadmium sulphide or selenide and the electrode can be made from tin. The method reduces the amount of poisonous photosensitive material needed to form the photoresistor.

Description

I
DEPOSITION
The invention relates to deposition, particularly of a relatively poisonous material to form a photoresistor.
A photoresistor is one type of a photoelectric semiconductor component. The electrical resistance of a photoresistor changes as incident light falling on it varies in intensity.
Such a characteristic provides for the photoresistor to act as a circuit control for electrical circuits. The principal material employed in the making of photoresistors are Cadmium Suiphide (CdS) and Cadmium Selenide, (CdSe), which are generally considered to be the best materials for the making of photoresistors. However, Cadmium (Cd) is a poisonous element.
The traditional technique for making photoresistors entails spraying a photosensitive material mainly composed of Cadmium Sulphide (CdS) or Cadmium Selenide (CdSe) onto the surface of a ceramic base. Electrodes are then plated on top of this photosensitive layer. However, this method results in a significant exposed area of uncovered photosensitive material, which can be harmful to users and to the environment.
It is an object of the invention to seek to mitigate this disadvantage.
According to a first aspect, the invention provides a method of making a photoresistor, comprising the steps of providing a substrate, applying a photosensitive material to a portion of the substrate by masking to provide a deposit, and applying an electrode to the photosensitive material deposited in the desired pattern.
Using the invention, the overall level of photosensitive material can be reduced, and the material is substantially covered by the electrode(s). The substrate, or base, may be provided as a ceramic material.
The photosensitive material may comprise a cadmium compound, such as Cadmium Suiphide or Cadmium Selenide.
The step of applying the photosensitive material may comprise using a masking spray method, for example a precipitation spray, a sputtering spray, or a printing method.
These are all relatively simple, and efficient.
The method may comprise applying a tin electrode to the photosensitive material, or any other suitable material such as copper may be used.
According to a second aspect, the invention provides a photoresistor, comprising a substrate, a photosensitive material formed on a portion of the substrate in a desired pattern, and an electrode applied to the photosensitive material in the desired pattern, whereby the photosensitive material and electrode are substantially superimposed.
This provides for a reduction in the amount of photosensitive material which is utilised.
The photosensitive material may comprise Cadmium, e.g. Cadmium Sulphide or Cadmium Selenide.
The substrate may suitably comprise a ceramic, and the electrode may comprise a tin electrode, or a copper or other suitable material electrode.
A method and photoresistor are hereinafter described, by way of example, with reference to the accompanying drawings.
Fig. I is a schematic plan view of a surface a ceramic substrate or base; Fig. 2 is a schematic plan view of the surface of Fig. 1 to which a photosensitive material has been applied in a desired pattern; Fig. 3 is a schematic plan view of the surface of Gigs. 1 and 2 plated with an electrode or electrodes; and Fig. 4 is a side elevational view of overlapped layers of Figs. 2 and 3.
Referring to the drawings, a photoresistor 1 is made by providing a substrate or base 2 such as a ceramic material, and then providing a trace or desired pattern 3 of a photosensitive material such as one comprising Cadmium, for example Cadmium Suiphide or Cadmium Selenide. The material is laid down over a portion of the surface 4 of the ceramic substrate or base 2 by using a masked spray technique, for example in the embodiment by using precipitation, sputtering or printing. An electrode 6, which in the embodiment is of tin, is then provided in the same shape or pattern 7 as that of the photosensitive material and laid down on it by any suitable method for example plating, deposition or by direct physical application to the photosensitive material. Thus the electrode 6 and photosensitive material 3 are substantially superimposed, with the result that there is a reduced area of (poisonous) Cadmium exposed to users and the enviromnent. Thus the overall level of Cadmium in photo-resistive components produced using the method and photoresistor will be reduced as compared to prior methods.
It will be understood that the coated photosensitive layer and the corresponding shape 7 (geometry) of the electrode(s) can be varied to provide a desired pattern e.g. linear, curved or a combination thereof.
Using the invention described hereinbefore with reference to the drawings, it is possible to employ a masked spray to provide the layer of photosensitive material 3 in a desired pattern 7 on the surface 6 of the substrate or base 2, and that only a portion of the functional area of the surface 4 of the substrate or base 2 is coated with the photosensitive material 3, thereby reducing the amount of Cadmium used.

Claims (17)

  1. CLAIMS: 1. A method of making a photoresistor, comprising the steps of
    providing a substrate, applying a photosensitive material to a portion of the substrate by masking to provide a deposit, and applying an electrode to the photosensitive material deposited in the desired pattern.
  2. 2. A method according to Claim 1, the substrate being provided as a ceramic material.
  3. 3. A method according to Claim 1 or Claim 2, the photosensitive material comprising a Cadmium compound.
  4. 4. A method according to Claim 3, the compound comprising Cadmium Suiphide.
  5. 5. A method according to Claim 3, the compound comprising Cadmium Selenide.
  6. 6. A method according to any preceding claim, the step of applying the photosensitive material comprising using a masking spray method.
  7. 7. A method according to Claim 6, the masking spray method comprising a precipitation spray, a sputtering spray, or a printing method.
  8. 8. A method according to any preceding claim, comprising applying a tin electrode to the photosensitive material.
  9. 9. A method according to Claim 1, substantially as hereinbefore described.
  10. 10. A photoresistor, comprising a substrate, a photosensitive material formed on a portion of the substrate in a desired pattern, and an electrode applied to the photosensitive material in the desired pattern, whereby the photosensitive material and electrode are substantially superimposed.
  11. 11. A photosensitive material according to Claim 10, the photosensitive material comprising Cadmium.
  12. 12. A photosensitive material according to Claim 11, the material comprising Cadmium Sulphide.
  13. 13. A photoresistor according to Claim 11, the material comprising Cadmium Selenide.
  14. 14. A photoresistor according to any of Claims 10 to 13, the substrate comprising a ceramic.
  15. 15. A photoresistor according to Claim 14, the electrode comprising a tin electrode.
  16. 16. A photoresistor according to Claim 15, the electrode being applied by plating.
  17. 17. A photoresistor substantially as hereinbefore described with reference to the accompanying drawing.
GB0519746A 2005-09-28 2005-09-28 A method of making a photoresistor Withdrawn GB2430797A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB0519746A GB2430797A (en) 2005-09-28 2005-09-28 A method of making a photoresistor
PCT/IB2006/003888 WO2008038064A1 (en) 2005-09-28 2006-09-28 A method of making a photoresistor and a photoresistor made thereby

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB0519746A GB2430797A (en) 2005-09-28 2005-09-28 A method of making a photoresistor

Publications (2)

Publication Number Publication Date
GB0519746D0 GB0519746D0 (en) 2005-11-09
GB2430797A true GB2430797A (en) 2007-04-04

Family

ID=35394890

Family Applications (1)

Application Number Title Priority Date Filing Date
GB0519746A Withdrawn GB2430797A (en) 2005-09-28 2005-09-28 A method of making a photoresistor

Country Status (2)

Country Link
GB (1) GB2430797A (en)
WO (1) WO2008038064A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1086603A (en) * 1966-03-08 1967-10-11 Gen Precision Inc Photoconductive thin film cell responding to a broad spectral range of light input
JPS5769783A (en) * 1980-10-20 1982-04-28 Nippon Telegr & Teleph Corp <Ntt> Formation of multilayer thin film pattern
US4701997A (en) * 1985-08-08 1987-10-27 Sharp Kabushiki Kaisha Method of making photo-electric converting elements

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55158682A (en) * 1979-05-29 1980-12-10 Matsushita Electric Ind Co Ltd Photoconductive cell and manufacture thereof
JPS59152677A (en) * 1983-02-18 1984-08-31 Matsushita Electric Ind Co Ltd Cds photoconductive cell
JPH03266475A (en) * 1990-03-15 1991-11-27 Komatsu Ltd Exposure sensor
JPH0426165A (en) * 1990-05-22 1992-01-29 Matsushita Electric Works Ltd Cds photoconductive element device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1086603A (en) * 1966-03-08 1967-10-11 Gen Precision Inc Photoconductive thin film cell responding to a broad spectral range of light input
JPS5769783A (en) * 1980-10-20 1982-04-28 Nippon Telegr & Teleph Corp <Ntt> Formation of multilayer thin film pattern
US4701997A (en) * 1985-08-08 1987-10-27 Sharp Kabushiki Kaisha Method of making photo-electric converting elements

Also Published As

Publication number Publication date
GB0519746D0 (en) 2005-11-09
WO2008038064A1 (en) 2008-04-03

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