GB2383338B - Thermal barrier coating - Google Patents

Thermal barrier coating

Info

Publication number
GB2383338B
GB2383338B GB0230011A GB0230011A GB2383338B GB 2383338 B GB2383338 B GB 2383338B GB 0230011 A GB0230011 A GB 0230011A GB 0230011 A GB0230011 A GB 0230011A GB 2383338 B GB2383338 B GB 2383338B
Authority
GB
United Kingdom
Prior art keywords
barrier coating
thermal barrier
thermal
coating
barrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
GB0230011A
Other languages
English (en)
Other versions
GB0230011D0 (en
GB2383338A (en
Inventor
Kenneth S Murphy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Howmet Corp
Original Assignee
Howmet Research Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Howmet Research Corp filed Critical Howmet Research Corp
Publication of GB0230011D0 publication Critical patent/GB0230011D0/en
Publication of GB2383338A publication Critical patent/GB2383338A/en
Application granted granted Critical
Publication of GB2383338B publication Critical patent/GB2383338B/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/08Oxides
    • C23C14/083Oxides of refractory metals or yttrium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • C23C28/3215Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer at least one MCrAlX layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/325Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with layers graded in composition or in physical properties
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C23C28/3455Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T50/00Aeronautics or air transport
    • Y02T50/60Efficient propulsion technologies, e.g. for aircraft
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12611Oxide-containing component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12611Oxide-containing component
    • Y10T428/12618Plural oxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12931Co-, Fe-, or Ni-base components, alternative to each other
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12944Ni-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24033Structurally defined web or sheet [e.g., overall dimension, etc.] including stitching and discrete fastener[s], coating or bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Physical Vapour Deposition (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Coating By Spraying Or Casting (AREA)
GB0230011A 2001-12-21 2002-12-23 Thermal barrier coating Expired - Lifetime GB2383338B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/024,538 US6689487B2 (en) 2001-12-21 2001-12-21 Thermal barrier coating

Publications (3)

Publication Number Publication Date
GB0230011D0 GB0230011D0 (en) 2003-01-29
GB2383338A GB2383338A (en) 2003-06-25
GB2383338B true GB2383338B (en) 2004-01-21

Family

ID=21821107

Family Applications (1)

Application Number Title Priority Date Filing Date
GB0230011A Expired - Lifetime GB2383338B (en) 2001-12-21 2002-12-23 Thermal barrier coating

Country Status (6)

Country Link
US (1) US6689487B2 (https=)
JP (1) JP4827365B2 (https=)
CA (1) CA2412265C (https=)
DE (1) DE10254209B4 (https=)
FR (1) FR2833971B1 (https=)
GB (1) GB2383338B (https=)

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US6689422B1 (en) * 1994-02-16 2004-02-10 Howmet Research Corporation CVD codeposition of A1 and one or more reactive (gettering) elements to form protective aluminide coating
US20030118873A1 (en) * 2001-12-21 2003-06-26 Murphy Kenneth S. Stabilized zirconia thermal barrier coating with hafnia
US7029232B2 (en) * 2003-02-27 2006-04-18 Rolls-Royce Plc Abradable seals
US7413798B2 (en) * 2003-04-04 2008-08-19 Siemens Power Generation, Inc. Thermal barrier coating having nano scale features
US6982126B2 (en) * 2003-11-26 2006-01-03 General Electric Company Thermal barrier coating
US20050153160A1 (en) * 2004-01-12 2005-07-14 Yourong Liu Durable thermal barrier coating having low thermal conductivity
US7402347B2 (en) * 2004-12-02 2008-07-22 Siemens Power Generation, Inc. In-situ formed thermal barrier coating for a ceramic component
US7416788B2 (en) * 2005-06-30 2008-08-26 Honeywell International Inc. Thermal barrier coating resistant to penetration by environmental contaminants
US7632012B2 (en) * 2005-09-01 2009-12-15 Siemens Energy, Inc. Method of measuring in situ differential emissivity and temperature
WO2007137433A1 (en) * 2006-06-01 2007-12-06 Litens Automotive Partnership Dust shield for a pulley bearing and a pulley with a dust shield
DE102006036520A1 (de) * 2006-08-04 2008-02-07 Mtu Aero Engines Gmbh Gasturbinenbauteil mit einer Wärmedämmschicht, Wärmedämmschicht für ein Gasturbinenbauteil sowie Verfahren zur Herstellung einer Wärmedämmschicht auf einem Gasturbinenbauteil
US20080274336A1 (en) * 2006-12-01 2008-11-06 Siemens Power Generation, Inc. High temperature insulation with enhanced abradability
US8257600B2 (en) 2010-03-01 2012-09-04 United Technologies Corporation Printed masking process
US20110250367A1 (en) * 2010-04-12 2011-10-13 Neal James W Deposition apparatus with preheating chamber having thermal hood
CN102557447B (zh) * 2011-11-07 2013-10-09 中南大学 一种镍合金基体表面热障涂层及制备方法
US10280770B2 (en) 2014-10-09 2019-05-07 Rolls-Royce Corporation Coating system including oxide nanoparticles in oxide matrix
US10047614B2 (en) 2014-10-09 2018-08-14 Rolls-Royce Corporation Coating system including alternating layers of amorphous silica and amorphous silicon nitride
US10106882B2 (en) * 2015-10-12 2018-10-23 United Technologies Corporation Method of forming a multi-layered coating with columnar microstructure and branched columnar microstructure
US20170101874A1 (en) * 2015-10-12 2017-04-13 United Technologies Corporation Multi-layered coating with columnar microstructure and branched columnar microstructure
DE102017206063A1 (de) * 2017-04-10 2018-10-11 Siemens Aktiengesellschaft Teil- und vollstabilisiertes Zirkonoxidpulver als keramische Schicht
DE102018215223A1 (de) * 2018-09-07 2020-03-12 Siemens Aktiengesellschaft Keramisches Material auf der Basis von Zirkonoxid mit weiteren Oxiden und Schichtsystem
GB201918278D0 (en) * 2019-12-12 2020-01-29 Rolls Royce Plc Thermal barrier coating
CN115595577B (zh) * 2022-11-03 2024-08-13 河海大学 一种过流部件抗空蚀阻尼复合金属材料结构及其制备方法

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US4874664A (en) * 1986-11-21 1989-10-17 Toyota Jidosha Kabushiki Kaisha Birefringent plate and manufacturing method for the same
GB2324308A (en) * 1997-04-16 1998-10-21 Dlr Ev Ceramic heat-insullating layers with club-like structure
WO1999035306A2 (en) * 1997-12-09 1999-07-15 N.V. Interturbine Thermal barrier coating ceramic structure
EP0940480A1 (en) * 1998-01-13 1999-09-08 ROLLS-ROYCE plc A metallic article having a thermal barrier coating and a method of application thereof
WO2001043965A1 (en) * 1999-12-14 2001-06-21 The Penn State Research Foundation Thermal barrier coatings and electron-beam, physical vapor deposition for making same
US6251504B1 (en) * 1998-06-04 2001-06-26 Societe Nationale D'etude Et De Construction De Monteurs D'aviation S.N.E.C.M.A. And Snecma Services Ceramic heat barrier coating having low thermal conductivity, and process for the deposition of said coating
EP1249515A2 (en) * 2001-04-12 2002-10-16 General Electric Company Yttria-stabilized zirconia with reduced thermal conductivity

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DE69406963T2 (de) 1993-03-15 1998-05-20 Inoue, Akihisa, Sendai, Miyagi Hochharte Dünnschicht, sowie Verfahren zu deren Herstellung
US5562998A (en) * 1994-11-18 1996-10-08 Alliedsignal Inc. Durable thermal barrier coating
US5716720A (en) * 1995-03-21 1998-02-10 Howmet Corporation Thermal barrier coating system with intermediate phase bondcoat
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US6117560A (en) 1996-12-12 2000-09-12 United Technologies Corporation Thermal barrier coating systems and materials
US5912087A (en) 1997-08-04 1999-06-15 General Electric Company Graded bond coat for a thermal barrier coating system
US6114003A (en) 1997-09-04 2000-09-05 No Fire Technologies, Inc. Insulation blanket having an inner metal core air cell and adjoining outer insulation layers
US5817372A (en) 1997-09-23 1998-10-06 General Electric Co. Process for depositing a bond coat for a thermal barrier coating system
GB9811456D0 (en) * 1998-05-29 1998-07-29 Rolls Royce Plc A metallic article having a thermal barrier coating and a method of application thereof
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4874664A (en) * 1986-11-21 1989-10-17 Toyota Jidosha Kabushiki Kaisha Birefringent plate and manufacturing method for the same
GB2324308A (en) * 1997-04-16 1998-10-21 Dlr Ev Ceramic heat-insullating layers with club-like structure
WO1999035306A2 (en) * 1997-12-09 1999-07-15 N.V. Interturbine Thermal barrier coating ceramic structure
EP0940480A1 (en) * 1998-01-13 1999-09-08 ROLLS-ROYCE plc A metallic article having a thermal barrier coating and a method of application thereof
US6251504B1 (en) * 1998-06-04 2001-06-26 Societe Nationale D'etude Et De Construction De Monteurs D'aviation S.N.E.C.M.A. And Snecma Services Ceramic heat barrier coating having low thermal conductivity, and process for the deposition of said coating
WO2001043965A1 (en) * 1999-12-14 2001-06-21 The Penn State Research Foundation Thermal barrier coatings and electron-beam, physical vapor deposition for making same
EP1249515A2 (en) * 2001-04-12 2002-10-16 General Electric Company Yttria-stabilized zirconia with reduced thermal conductivity

Also Published As

Publication number Publication date
US20030118874A1 (en) 2003-06-26
US6689487B2 (en) 2004-02-10
JP2003239086A (ja) 2003-08-27
DE10254209B4 (de) 2016-09-15
JP4827365B2 (ja) 2011-11-30
GB0230011D0 (en) 2003-01-29
FR2833971A1 (fr) 2003-06-27
GB2383338A (en) 2003-06-25
DE10254209A1 (de) 2003-07-03
CA2412265A1 (en) 2003-06-21
CA2412265C (en) 2012-02-21
FR2833971B1 (fr) 2006-05-26

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Legal Events

Date Code Title Description
732E Amendments to the register in respect of changes of name or changes affecting rights (sect. 32/1977)

Free format text: REGISTERED BETWEEN 20130606 AND 20130612

PE20 Patent expired after termination of 20 years

Expiry date: 20221222