GB2300299A - Operation of a semiconductor device - Google Patents
Operation of a semiconductor device Download PDFInfo
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- GB2300299A GB2300299A GB9508466A GB9508466A GB2300299A GB 2300299 A GB2300299 A GB 2300299A GB 9508466 A GB9508466 A GB 9508466A GB 9508466 A GB9508466 A GB 9508466A GB 2300299 A GB2300299 A GB 2300299A
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- 239000004065 semiconductor Substances 0.000 title description 10
- 230000003287 optical effect Effects 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 19
- 230000005669 field effect Effects 0.000 claims abstract description 13
- 239000000969 carrier Substances 0.000 claims abstract description 7
- 238000005513 bias potential Methods 0.000 claims abstract description 6
- 238000010521 absorption reaction Methods 0.000 description 38
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 20
- 230000007935 neutral effect Effects 0.000 description 20
- 230000004888 barrier function Effects 0.000 description 19
- 238000005253 cladding Methods 0.000 description 18
- 230000007704 transition Effects 0.000 description 14
- 125000006850 spacer group Chemical group 0.000 description 11
- 230000001965 increasing effect Effects 0.000 description 8
- 239000002184 metal Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 238000001228 spectrum Methods 0.000 description 5
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- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910004613 CdTe Inorganic materials 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002488 metal-organic chemical vapour deposition Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000001451 molecular beam epitaxy Methods 0.000 description 2
- 238000000206 photolithography Methods 0.000 description 2
- 238000000103 photoluminescence spectrum Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001902 propagating effect Effects 0.000 description 2
- SBIBMFFZSBJNJF-UHFFFAOYSA-N selenium;zinc Chemical compound [Se]=[Zn] SBIBMFFZSBJNJF-UHFFFAOYSA-N 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 229910000980 Aluminium gallium arsenide Inorganic materials 0.000 description 1
- -1 GaInP/A1GaInP Inorganic materials 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
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- 230000009467 reduction Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000005533 two-dimensional electron gas Effects 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/015—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on semiconductor elements having potential barriers, e.g. having a PN or PIN junction
- G02F1/017—Structures with periodic or quasi periodic potential variation, e.g. superlattices, quantum wells
- G02F1/01708—Structures with periodic or quasi periodic potential variation, e.g. superlattices, quantum wells in an optical wavequide structure
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/015—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on semiconductor elements having potential barriers, e.g. having a PN or PIN junction
- G02F1/025—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on semiconductor elements having potential barriers, e.g. having a PN or PIN junction in an optical waveguide structure
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- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biophysics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Junction Field-Effect Transistors (AREA)
Abstract
A method for operating an optical modulator 1 concerns a modulator comprising a quantum well layer 27 in a field effect transistor arrangement for altering the density of free carriers within the quantum well layer 27. The arrangement includes a gate electrode 13 and source 15 and drain 17 contacts. Optionally, a first potential is applied across the source and drain 15,17. A second variable bias potential is applied between the gate 13 and drain 17. The bias potential is varied such that the modulator 1 is substantially transparent to incident light 19 when the free carrier density in the well layer 27 is zero or negligible. When there is a finite carrier density in the well layer, the modulator 1 is substantially opaque to incident light 19.
Description
OPERATION OF A SEMICONDUCTOR DEVICE
The present invention relates to a new mode of operation of a semiconductor device and in particular, of an optical modulator.
An optical modulator is an electro-optic device where the intensity of a transmitted optical beam is switched between lower and higher values by a controlling applied voltage. An efficient optical modulator must have a large contrast between the transparent and opaque states, as well as having low loss in the transparent state.
US Patent No. US-A-4 872744 describes and claims an optical modulator comprising a quantum well layer and means in the form of a field effect transistor for altering the density of free carriers within the well layer. The field effect transistor is in the general form of a high electron mobility transistor (HEMT) but configured to guide light through a central region of the well layer. The bias applied to the gate electrode makes the device relatively transparent or opaque to the light in transit.
The device according to the aforementioned US patent, when operated as described, still absorbs some radiation in the transparent state, even though it absorbs more in the opaque state. This has a number of disadvantages. First, it impairs the contrast between the opaque and transparent states. Second, it results in higher power being required for the optical input beam. The absorption of the transparent state also restricts the overall length of a waveguide than can be formed containing the device as an integral element, which limits its use in an integrated optical circuit.
It has now been discovered that these disadvantages can be overcome by operating the device in a new mode, in accordance with the present invention, which provides a method of operating an optical modulator which comprises a quantum well layer in a field effect transistor arrangement for altering the density of free carriers within the quantum well layer, which field effect transistor includes a gate electrode and source and drain contacts, the method comprising applying a variable bias potential between the gate and drain electrodes, and varying the bias potential applied to the gate electrode such that the modulator is substantially transparent to incident light when the carrier density in the quantum well layer is zero or negligible and substantially opaque to incident light when there is a finite carrier density in the quantum well layer.
Optionally, a fixed potential difference is also applied between the source and drain contacts.
The method of the present invention thus overcomes the disadvantages of the mode of operation described in US-A-4 872744 since the absorption in the transparent state is greatly reduced. The absorption in the transparent state of this device has two origins. Firstly, there is the residual valence-to-conduction band absorption remaining when excess electrons are added to the quantum well. Secondly, the excess electrons in the well cause absorption due to intra- and interconduction band transitions. With the present invention, the transparent state is formed with negligible excess electron density in the quantum well, thereby almost eliminating intra- and inter-conduction band absorption by excess electrons in the transparent state.Indeed, the intra- and interconduction band absorption is significant only for the opaque state, thereby enhancing the transparent/opaque contrast ratio. Furthermore, the residual valence band-to-conduction band absorption in the transparent state is also reduced since the device is operated at a photon energy below the bandedge neutral exciton line at zero electron density, where the quantum well will be nearly transparent.
Optical excitation of electrons in semiconductors from the valence to conduction band results in a continuum of optical transitions, with a threshold photon energy equal to the bandgap of the material. It is known, that the electron in the conduction band and the "hole" it leaves behind in the valence band feel a mutual Coulombic attraction due to their opposite charge. The interaction leads to an electron-hole bound state being formed (consisting of one electron and one hole), referred to as a (neutral) exciton.
These neutral excitons produce sharp resonances in the absorption spectrum at a photon energy below the threshold energy of the valence band-to-conduction band continuum The difference in the continuum threshold and lowest-energy, discrete excitonic transition energy is approximately equal to the binding energy of the electron and hole due to their mutual attraction. For a semiconductor quantum well the interband absorption threshold (at zero electron density) is due to the (neutral) exciton formed between the first electron and hole subbands.
It has been argued in the aforementioned US Patent that the absorption at the neutral excitonic transition energy is reduced by adding excess electrons to the quantum well. The absorption has two main components, (1) the ground state neutral exciton and (2) the continuum transition. The reduction in the continuum absorption relies upon the fact that transitions to the bottom of the conduction band are blocked by these states being occupied by electrons. Hence as the electron Fermi energy increases, the effective bandedge threshold is shifted to higher energy (the
Burstein-Moss effect).
As pointed out in the US Patent, the continuum absorption is not completely removed, leaving some residual absorption in the transparent state. In fact, this problem is much worse than anticipated in that document, since the quantum well bandgap shifts to lower energy with increasing electron density, cancelling most of the shift of the effective absorption edge to higher transition energy. Hence the absorption of the device of the US Patent in its "transparent" state would be actually quite significant.
Another source of loss in the transparent state in the device of the
US patent arises from the intra- and inter-conduction band absorption processes, which are also not discussed in that document. This absorption is caused by excess electrons in the conduction band being excited to higher energy states in the same or higher conduction bands. An excess electron density excess electron density of 1012 cam~2 has been estimated to be required to produce the transparent state according to the mode of operation in US-A-4 872744. That corresponds to a 3D density of 1018 cm-3 in a 100 A wide quantum well. Adachi, "GaAs and Related
Materials", (World Scientific, Singapore, 1994), p441) gives a plot of the absorption coefficient due to inter-conduction band processes in doped bulk GaAs.From this plot the absorption coefficient below the fundamental gap for a density of 1018 cam~2 can be estimated to be roughly 10 cm-l.
Although not wishing to be bound by any particular theory or explanation, the applicants believe that the key differences between the mode of operation described in US-A-4 872744 and that of the present invention are two-fold. First, the device as described in the US Patent operates at the energy of the neutral band edge exciton in amplitude modulation mode and operation according to the present invention is at an energy below this. Furthermore, for operation according to the US Patent, the transparent and opaque states are formed with finite and negligible electron density in the quantum well, respectively. With the present invention this situation is reversed.
The description hereinbelow of one embodiment of a method according to the present invention concerns a device which consists of a waveguide with a central region containing a quantum well layer whose density of free electrons can be varied by application of a voltage between the Schottky gate and drain of an integral field effect transistor. The light propagating through the waveguide is chosen to have an energy below the neutral excitonic absorption of the quantum well when depleted of excess electrons. Hence when the Schottky gate is biased such that there are no electrons in the quantum well, the light can propagate through the waveguide with relatively little attenuation. This corresponds to the transparent state of the device.When excess electrons are added to the quantum well, by changing the gate voltage, the photon energy required for excitonic absorption in the quantum well is lowered, thereby increasing the absorption of the light and turning the device into its opaque state.
There will also be some enhancement of the light absorption when excess electrons are added to the quantum well (opaque state for the present invention) due to inter- and intra-conduction band transitions.
Also, when excess electrons are added to the quantum well, the photoexcited electron and hole can bind a second excess electron, forming a bound complex consisting of two electrons and one hole, referred to as a negatively-charged exciton. The transition energy of the negativelycharged exciton is lower than that of the neutral exciton by an amount roughly equal to the binding energy of the second excess electron to the electron/hole core of the exciton.
Fig. 7 of the accompanying drawings shows the absorption of the quantum well with a negligibly small (solid line) and finite (dashed) electron density in the quantum well. It can be seen that the device is operated at a photon energy below the neutral excitonic energy at zero electron density. Adding excess electrons to the quantum well causes oscillator strength to be removed from the neutral exciton and transferred to the negatively charged exciton, which lies to lower energy and lies close to the operating photon energy. Hence adding excess electrons increases the absorption at the operating photon energy and turns the device into its opaque state.
Hence, the method according to the present invention relies on the ability to increase the absorption of the quantum well by introducing excess electrons to it. The operating photon energy is chosen to be below the neutral exciton resonance with negligible electron density in the quantum well (solid line in Fig. 7 < Adding excess electrons (by changing the gate voltage) to the quantum well enhances the formation of negatively-charged excitons and thereby increases the absorption at the operating photon energy (dashed line in Fig. 7).
With the method according to the present invention, in order to achieve the strongest absorption in the opaque state, the device should be operated (in the opaque state) at the electron density, where the absorption of the negatively-charged exciton is strongest. This will be achieved at a moderate electron density, which can be estimated as follows. A negatively-charged exciton is formed when a photon is absorbed in the vicinity of an excess electron. Hence as the excess electron density increases, the absorption strength of the negatively-charged excitons increases at the expense of the neutral ones, as the excess electrons cover an increasingly large area of the quantum well.The electron density where the negatively-charged exciton will be formed in nearly all areas of the quantum well, and therefore have maximum absorption strength, can be roughly estimated from the reciprocal of the area of the negatively-charged exciton in the quantum well plane.
Taking the example of a GaAs quantum well and a rough estimate of the in-plane radius of the negatively charged to be twice that of a 3D neutral exciton, yields an excess electron density of about 3 x 1010 cam~2.
This gives a rough estimate of the optimum electron density for the opaque state, which may be improved by a more detailed theoretical analysis and by taking account of the effect of localisation of the electrons by spatial inhomogenities.
It will be appreciated that the mode of operation of the present invention can be utilised with devices exactly as described in US-A-4 872 744, choosing an appropriate gate bias to obtain a sufficiently low electron density in the well layer to allow utilisation of negatively-charged excitons.
However, other appropriate structures can be envisaged.
Generally speaking, any heterostructure can be used which allows induction of a so-called two-dimensional electron gas in a quantum well or active layer by virtue of carriers derived from a doped layer, and in which light can be transmitted through the well region. Optionally, an undoped spacer layer is located between the doped and quantum well layers.
However, as the present invention relies on lower electron densities in the quantum well, as compared with the mode of operation described in US
A-4 872 744, the presence of a spacer layer is preferred. Therefore, such a spacer layer may be relatively thick, e.g. 30-100 nm.
Although this discussion of the present invention is in terms of adding excess electrons to the quantum well, it should be noted that optical modulation can also be achieved by introducing excess holes instead. In this case the doped barrier regions close to the quantum well in the fieldeffect transistor contains a surplus of acceptors rather than donors. This facilitates the density of excess holes in the quantum well to be varied via the gate-drain voltage. Again the operating photon energy is chosen so to be less than the bandedge excitonic transition with negligible excess hole density in the quantum well (transparent state). Increasing the excess holes density, by altering the gate-drain voltage, causes positively-charged excitons (bound complexes of two holes and one electron) to form in the quantum well.These have a lower transition energy than the neutral excitons, thereby increasing the absorption of the quantum well at the operating photon energy and forming the opaque state of the device. If the hole effective mass is larger than that of the electron, which is the case for most semiconductors, the binding energy of the second hole in a positively-charged exciton will be larger than that of the second electron in a negatively-charged exciton. Hence a device operating with excess holes may provide a larger transparent/opaque contrast ratio than one with excess electrons.
Preferred embodiments described hereinbelow are in the form of a field effect transistor with source and drain regions contacting the quantum well layer. A Schottky metal gate electrode overlies the quantum well layer between source and drain regions such that a bias voltage applied to the gate controls switching between the transparent and opaque states. The well, spacer and doped layers are disposed between respective cladding layers.
The preferred embodiments are based on a GaAs/A1,Gal,xAs heterostructure and the doped layer is n-type. However, the layers could be formed from a number of different materials. Nevertheless, those with strong bandedge excitonic resonances are preferred, e.g.
InP/InxGal As, InxGa1-xAs/InyAl1-yAs, InP/InxcAIl xAs, InxGal xAs/GaAs, GaInP/A1GaInP, CdTe/CdxZn 1 xTe, CdTe/CdxMn1,xTe, ZnSe/Zn 1 vcMnxSe, Zn1 xCdxSe/ZnSe, ZnSySe 1 -y" 1 xCdxSe, etc.
Various modifications to this basic structure are possible, for example:
(1) The device described in the embodiments produces amplitude modulation where the absorption coefficient is changed at the operating photon energy. However, the principles outlined here can also be employed to produce a device working on the principle of phase modulation, relying on a small change in the refractive index. In this case a smaller operating photon energy is used which lies within the forbidden gap of the quantum well so reducing the absorption losses even further. On the other hand, such a device has the potential disadvantage that longer device lengths are required to produce comparable modulation.
(2) The metal Schottky gate could be replaced by a doped semiconductor layer grown epitaxially along with the rest of the structure.
(3) The dopant atoms could be placed in the AlxGal xAs layer below, rather than above, the quantum well.
(4) The structure could have a doped semiconductor back gate instead of (or additional to) the front gate for the purpose of changing the electron density in the quantum well, i.e. below the waveguide structure.
(5) The undoped spacer layer can be omitted.
(6) p-type dopants could be used instead of n-type. In this case excess holes are supplied to the quantum well, leading to the formation of positively-charged excitons.
(7) The upper cladding layer can be omitted or replaced by a dielectric with smaller refractive index than the guided region. This may be preferable if the AlxGa1 .xAs cladding layer has a large background impurity concentration.
(8) A short-period superlattice structure (e.g. 50 periods in
GaAs(25 )/Alo 3Gao 7As (25 A) for the GaAs structure outlined here) can be grown before the quantum well layer, in order to improve the quality of the quantum well layer.
The modulator in use may be incorporated into a waveguide structure for use as a discrete device or integrated into an optical circuit.
The semiconductor layers of the device can be produced by a number of different methods, although epitaxial growth methods such as
MOVPE, MOCVD, MBE, etc., are preferred.
The present invention will now be explained in more detail by way of the following description of preferred embodiments and with reference to the accompanying drawings, in which:
Figure 1 shows a schematic partial cross-sectional view of a first embodiment of an optical modulator for operation in accordance with the present invention;
Figure 2 shows a schematic cross-sectional view of the guided region waveguide structure of the modulator shown in Figure 1;
Figure 3 shows details of the layer structure of the modulator shown in Figures 1 and 2;
Figure 4 shows a schematic plan view of a second embodiment of an optical modulator for operation in accordance with the present invention;
Figure 5 shows a cross-sectional view of the modulator shown in
Figure 4;
Figure 6 shows details of the layer structure of the modulator shown in Figures 4 and 5;;
Figure 7 shows the absorption profile of a quantum well with negligible (solid line) and finite (dashed line) excess electron density in the quantum well; and
Figure 8 shows photoluminescence spectra obtained using the device shown in Figures 4-6 at different gate bias voltages.
Figure 1 shows the basic structure of a first embodiment of an optical modulator 1 for operation according to the present invention. The modulator 1 comprises a lower cladding layer 3 above which is situated a waveguide region 5. Above the waveguide region 5 is an upper cladding layer 7.
The upper cladding layer 7 is selectively etched to produce a raised ridge 9 and a metal Schottky gate electrode 13 is formed over the ridge 9.
Respectively on either side of the ridge 9 are formed by conventional techniques, a source ohmic contact 15 and a drain ohmic contact 17 which penetrate the upper cladding layer 7 to permit electrical contact with the quantum well in the guided region 5 of the waveguide.
As will be explained in more detail hereinbelow, a light beam indicated by arrow 19 travels through a propagation region 21 of the waveguide region 5, directly under the ridge 9 and Schottky gate, parallel to and between the source and drain ohmic contacts 15,17. The intensity and/or phase of the beam 19 exiting from the face (not shown) remote from the entry face 23 is modulated according to means of applied potentials.
The layer structure of the waveguide region 5 is shown in Figure 2.
It comprises a lower undoped barrier 25 below a quantum well or active layer 27. A middle undoped barrier or spacer layer 29 (which can be omitted) is situated above the quantum well layer 27 and a doped barrier layer 31 is formed over the middle undoped barrier layer 29. Finally, an upper undoped barrier layer 33 (which can be omitted) is situated above the doped barrier layer 31.
Figure 3 shows the full layer arrangement of the structure shown in
Figure 1, including the structure details of the waveguide region as shown in Figure 2. However, Figure 3 also shows that the structure of Figure 1 is formed on a substrate 35, a buffer layer 37 is interposed between the substrate 35 and the lower cladding layer 3, and that a GaAs layer (11) caps the growth after the upper cladding layer (7). The composition and thickness of each layer shown in Figure 3, is as listed in Table 1 hereinbelow.
TABLE1
STRUCTURE OF DEVICE SHOWN IN FIG. 3
IMPURITY LAYER MATERIAL THICKNESS CONC (cm-3) Capping layer 11 GaAs 10nm Upper cladding layer 7 AlyG1-yAS 0.5 m
Upper barrier layer 33 AIxGa1 xAs 40nm
Doped barrier layer 31 AIxGa1 xAs 0.2Rm Si 1017
Middle barrier (spacer)
layer 29 AIxGal xAs 60nm
Quantum well layer 27 GaAs 20nm
Lower barrier layer 25 AlxGa1xAs 0.3 m
Lower cladding layer 3 AlyGa-yAs 2 m
Buffer layer 37 GaAs lRm Substrate 35 GaAs unspec.
In Table 1 x = 0.3; y = 0.5
The complete structure is fabricated using a conventional epitaxial growth method. The thickness of the quantum well layer 27 is chosen to provide sharp excitonic resonances and with this particular heterostructure, could be any thickness from 3nm - 50nm. The carriers in the quantum well layer are of course induced by the doped barrier layer 33. Therefore, the thickness of the spacer layer 29 and of the doped barrier layer 33, as well as the impurity concentration of the latter, are chosen to allow the electron density to be varied between zero and the value for maximum absorption in the opaque state.
Referring again to Figure 2, the waveguide structure 5 consists of a central guided region sandwiched above and below by cladding layers 3,7 with a smaller refractive index than the average refractive of the guided region. For the GaAs/AlxGa 1 .xAs heterostructure illustrated here, this can be achieved by composing the cladding regions 3,7 of AlxGal xAs having a larger average Al concentration (e.g. x=0.5) than in the guided central region. For optimum performance the thickness of the central region should be kept sufficiently narrow that only the fundamental optical mode is supported and with the quantum well layer 27 at the maximum intensity of the optical mode. The cladding layers 3,7 should be sufficiently thick so as to prevent significant leakage of the optical mode from the guided region.
The cladding layers 3,7 on top of and below the guided region confine the optical mode in the direction normal to the layer planes.
Figure 2 illustrates just one possible method of confining the optical mode in the direction perpendicular to the growth direction, i.e. in a structure commonly referred to as a stripe waveguide. The processing steps required to form a stripe waveguide are well known and need not be detailed here. However, other waveguide structures, known to those skilled in the art, are also suitable.
The stripe is etched into the upper cladding layer 7 using dry or wetetching through a photolithographical mask. Since the refractive index within the stripe region is larger than that in the adjacent etched region, the optical mode will be confined under the stripe region. The stripe can be about 1 - 5 Rm wide and the etch depth is such that about 0.3 ,um of the upper cladding layer 7 remains in the etched region.
The Schottky metal contact 13 is evaporated on top of the stripe using standard techniques in order to act as the gate for the field effect transistor. The ohmic source and drain contacts 15,17 to the electron gas in the quantum well layer 27 are made using standard techniques on either side of the stripe forming the source and the drain of the field effect transistor. The electron density in the quantum well is varied by applying a voltage between the Schottky and drain contacts of the device. A second (optional) voltage is also supplied between the source and drain ohmic contacts so as to enhance the drift velocity of electrons travelling in the quantum well channel. This reduces the transit time for the electrons from the quantum well to the ohmic contact when a Schottky bias is applied so as to deplete the quantum well and thereby enhances the speed of the device.Maximum drift velocity is achieved in GaAs for an electric field of about 3.5 kV/cm
Figures 4 and 5 show a general schematic of a second embodiment of an optical modulator 41 for operation according to the present invention. It is generally analogous to the device shown in Figures 1 and 2.
A Schottky metal gate 43 is formed over the central area of a mesa region 45 and source 47 and drain 49 are formed at either end of the mesa 45 outside the gate 43 as ohmic contacts to a buried quantum well layer which will be described in more detail hereinbelow.
The mesa 45 is formed on a wafer 51 by defining a masked area using standard photolithography and then etching the exposed semiconductor to a depth below the quantum well layer. Photolithography is employed to deposit NiGeAu metal at either end of the mesa 45 which is then annealed to form the ohmic contacts 47,49 to the electrons in the quantum well layer.
A semi-transparent Au layer is evaporated onto the central region of the mesa 45 to form the Schottky gate 43.
As illustrated and described1 this device does not include a waveguide structure. However, it is to be understood that for operation as a modulator, a waveguide structure should also be incorporated, in the manner of the first embodiment.
Details of the layer structure within the mesa 45 are shown in Figure 6. The order of growth on a substrate 51 is as follows: lower buffer layer 53, middle buffer layer 55, upper buffer layer 57, lower barrier layer 59, quantum well layer 61, undoped spacer layer 63, n-doped layer 65 and finally, capping layer 67. The composition and thickness of each layer as shown in Figure 6 is listed in Table 2 hereinbelow.
TABLE 2
STRUCTURE OF DEVICE SHOWN IN FIG. 6
IMPURITY MATERIAL THICKNESS CONC (cm-3)
Capping layer 67 GaAs 17nm
Doped barrier layer 65 AIxGal xAs 200nm Si 1017
Spacer layer 63 AlxGa1-xAS 60nm
Quantum well layer 61 GaAs 30nm
Lower barrier layer 59 AlxGa1xAs 20nm
Upper buffer layer 57 GaAs 0.5 m
Middle buffer layer 55 Superlattice* 0.511m Lower buffer layer 53 GaAs 1. lem Substrate 51 GaAs unspec.
In Table 2, x = 0.33. The superlattice * is GaAs (2.5nm)/AlGaAs (2.5nm) The device of this second embodiment can be seen to be similar to that of the first embodiment. In particular, it has similar quantum well, undoped spacer and doped layers. The layers were grown by molecular beam epitaxy on a (100) oriented GaAs substrate. None of the layers were intentionally doped, except for the 2000 A doped AlO.33Ga0.67As layer.
The layer thicknesses and doping concentrations in Fig. 6 are the nominal values determined from the growth flux rates.
Waveguide cladding layers are omitted from Fig. 6 but these do not affect the light absorbing properties, although they will alter the operating voltage. The thickness of the back barrier layer is thinner than in the first embodiment. However, similar performance was obtained with samples with a thicker back barrier layer.
The excess electron density in the quantum well can be varied by biasing the Schottky gate with respect to the ohmic contacts. A negative applied gate voltage is required to deplete nearly all the electrons from the quantum well.
Fig. 8 plots photoluminescence spectra measured on this structure with different voltages applied to the gate relative to the source and drain contacts which are held at the same potential. The spectra are offset vertically for clarity. The measurements were taken with the incident and emitted light propagating almost normal to the layers. This is purely for investigative purposes. Operation as a modulator would require a waveguide structure to be incorporated and the incident beam to be directed as in the first embodiment. The incident light was at an energy below the bandgap of the AlO.33Ga0.67As barriers. Evidence for the formation of negatively-charged excitons and enhancement of the optical transition strength below the energy of the zero-electron density bandedge exciton can be deduced from Fig. 8.
It can be seen in Figure 8 that at the lowest gate bias (i.e. - 1 .24V), corresponding to the smallest excess electron density in the quantum well, the spectrum is dominated by a single peak due to the neutral exciton (marked X in Fig. 8). As the gate bias is increased, so filling the quantum well with excess electrons, the neutral exciton line declines in intensity, while concurrently a transition to distinctly lower transition energy, due to the negatively-charge exciton (X-), is seen to strengthen and eventually dominate the spectrum (at -1.13V).
The present invention is designed to operate near the photon energy of the negatively-charged exciton seen at larger gate biases.
The spectra in Fig. 8 demonstrate that increasing the excess electron density in the quantum well causes a quenching of the absorption strength of the bandedge neutral exciton, with concurrent strengthening of the negatively charged exciton to lower photon energy. Furthermore, electroreflectance spectra recorded on the sample showed a qualitatively similar behaviour for the neutral and negatively-charged excitons with increasing excess electron density.
The present invention provides operation near the photon energy of the negatively-charged exciton seen at larger gate biases. It is apparent from Fig. 8 that there is a shift of the peaks due to the neutral and negatively-charged exciton to lower energy with increasing electron density. This shift is beneficial as it will tend to enhance the contrast between the absorption in the opaque and transparent states.
In the light of this disclosure, modifications of the described embodiments, as well as other embodiments, all within the scope of the present invention as defined by the appended claims, will now be apparent to persons skilled in this art.
Claims (4)
1. A method of operating an optical modulator which comprises a quantum well layer in a field effect transistor arrangement for altering the density of free carriers within the quantum well layer, which field effect transistor includes a gate electrode and source and drain contacts, the method comprising applying a variable bias potential between the gate and drain electrode, and varying the bias potential applied to the gate electrode such that the modulator is substantially transparent to incident light when the carrier density in the quantum well layer is zero or negligible and substantially opaque to incident light when there is a finite carrier density in the quantum well layer.
2. A method according to claim 1, wherein the source and drain contacts are held at the same fixed potential.
3. A method according to claim 1, wherein a fixed potential difference is applied across the source and drain contacts.
4. A method of operating an optical modulator which comprises a quantum well layer in a field effect transistor arrangement for altering the density of free carriers within the quantum well layer, the method being substantially as hereinbefore described with reference to any of Figures 1 to 6 or 8 of the accompanying drawings.
Priority Applications (4)
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GB9508466A GB2300299B (en) | 1995-04-26 | 1995-04-26 | Operation of a semiconductor device |
GB9521401A GB2300300B (en) | 1995-04-26 | 1995-10-20 | Semiconductor device and method for its operation |
US08/637,495 US5963358A (en) | 1995-04-26 | 1996-04-25 | Semiconductor device and method for its operation |
JP10801596A JP3825498B2 (en) | 1995-04-26 | 1996-04-26 | Optical modulator |
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GB9508466A GB2300299B (en) | 1995-04-26 | 1995-04-26 | Operation of a semiconductor device |
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GB9521401A Expired - Lifetime GB2300300B (en) | 1995-04-26 | 1995-10-20 | Semiconductor device and method for its operation |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2321340A (en) * | 1995-10-20 | 1998-07-22 | Toshiba Cambridge Res Center | Optical modulator |
GB2306773B (en) * | 1995-10-20 | 1999-01-27 | Toshiba Cambridge Res Center | Optical modulator |
WO2002093204A2 (en) | 2001-05-17 | 2002-11-21 | Optronx, Inc. | Electronic semiconductor control of light in optical waveguide |
GB2380059A (en) * | 2001-09-25 | 2003-03-26 | Toshiba Res Europ Ltd | Semiconductor optical source and modulator |
Families Citing this family (1)
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GB2323450A (en) * | 1997-03-20 | 1998-09-23 | Secr Defence | Optical modulator |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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US4872744A (en) * | 1988-01-15 | 1989-10-10 | Bell Communications Research, Inc. | Single quantum well optical modulator |
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FR2675949B1 (en) * | 1991-04-25 | 1993-07-09 | Thomson Csf | WAVE MODULATOR AND OPTICAL DETECTOR WITH QUANTUM WELLS. |
US5165105A (en) * | 1991-08-02 | 1992-11-17 | Minnesota Minning And Manufacturing Company | Separate confinement electroabsorption modulator utilizing the Franz-Keldysh effect |
JP2739666B2 (en) * | 1992-06-11 | 1998-04-15 | 国際電信電話株式会社 | Light modulation element |
JP2786063B2 (en) * | 1992-08-11 | 1998-08-13 | 日本電気株式会社 | Semiconductor light control device |
US5329147A (en) * | 1993-01-04 | 1994-07-12 | Xerox Corporation | High voltage integrated flyback circuit in 2 μm CMOS |
FR2709566B1 (en) * | 1993-09-02 | 1995-09-29 | Alcatel Nv | Ribbon semiconductor active optical component. |
-
1995
- 1995-04-26 GB GB9508466A patent/GB2300299B/en not_active Expired - Fee Related
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US4872744A (en) * | 1988-01-15 | 1989-10-10 | Bell Communications Research, Inc. | Single quantum well optical modulator |
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ELECTRONICS LETTERS vol 23 no24 19/11/87 J H ABELES ETAL pages 1302-1305 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2321340A (en) * | 1995-10-20 | 1998-07-22 | Toshiba Cambridge Res Center | Optical modulator |
GB2321340B (en) * | 1995-10-20 | 1999-01-27 | Toshiba Cambridge Res Center | Optical modulator |
GB2306773B (en) * | 1995-10-20 | 1999-01-27 | Toshiba Cambridge Res Center | Optical modulator |
WO2002093204A2 (en) | 2001-05-17 | 2002-11-21 | Optronx, Inc. | Electronic semiconductor control of light in optical waveguide |
EP1402298A2 (en) * | 2001-05-17 | 2004-03-31 | Optronix, Inc. | Electronic semiconductor control of light in optical waveguide |
EP1402298A4 (en) * | 2001-05-17 | 2006-05-17 | Optronix Inc | Electronic semiconductor control of light in optical waveguide |
GB2380059A (en) * | 2001-09-25 | 2003-03-26 | Toshiba Res Europ Ltd | Semiconductor optical source and modulator |
GB2380059B (en) * | 2001-09-25 | 2003-11-05 | Toshiba Res Europ Ltd | An optical device and a optically actuated device |
Also Published As
Publication number | Publication date |
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GB2300299B (en) | 1999-07-07 |
GB2300300B (en) | 1998-04-29 |
GB9508466D0 (en) | 1995-06-14 |
GB2300300A (en) | 1996-10-30 |
GB9521401D0 (en) | 1995-12-20 |
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