GB2169274A - Silicate complexes and materials containing them - Google Patents
Silicate complexes and materials containing them Download PDFInfo
- Publication number
- GB2169274A GB2169274A GB08531865A GB8531865A GB2169274A GB 2169274 A GB2169274 A GB 2169274A GB 08531865 A GB08531865 A GB 08531865A GB 8531865 A GB8531865 A GB 8531865A GB 2169274 A GB2169274 A GB 2169274A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silicate
- cations
- silicon atoms
- alkoxysilane cluster
- crystals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000463 material Substances 0.000 title claims abstract description 32
- 150000004760 silicates Chemical class 0.000 title description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 150000001768 cations Chemical class 0.000 claims abstract description 18
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- 125000002091 cationic group Chemical group 0.000 claims description 10
- -1 hydroxyl hectorite Chemical compound 0.000 claims description 10
- 239000013078 crystal Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 230000008961 swelling Effects 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 238000005342 ion exchange Methods 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 229910052628 phlogopite Inorganic materials 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- 239000010455 vermiculite Substances 0.000 claims description 5
- 229910052902 vermiculite Inorganic materials 0.000 claims description 5
- 235000019354 vermiculite Nutrition 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 229910000271 hectorite Inorganic materials 0.000 claims description 3
- WNDZGSZAABWBMU-UHFFFAOYSA-N hydroxyboron Chemical compound O[B] WNDZGSZAABWBMU-UHFFFAOYSA-N 0.000 claims description 3
- 239000006104 solid solution Substances 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 150000001413 amino acids Chemical class 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 241000894007 species Species 0.000 claims 2
- 241000237519 Bivalvia Species 0.000 claims 1
- 235000020639 clam Nutrition 0.000 claims 1
- 239000002808 molecular sieve Substances 0.000 abstract description 9
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052615 phyllosilicate Inorganic materials 0.000 abstract description 2
- 239000004927 clay Substances 0.000 description 13
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 9
- 125000003342 alkenyl group Chemical group 0.000 description 8
- 239000011229 interlayer Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 238000009830 intercalation Methods 0.000 description 3
- 230000002687 intercalation Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004337 3-ethylpentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- ZZTJYSAFGSQPHE-UHFFFAOYSA-M benzyl-dimethyl-propylazanium;chloride Chemical compound [Cl-].CCC[N+](C)(C)CC1=CC=CC=C1 ZZTJYSAFGSQPHE-UHFFFAOYSA-M 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000020335 dealkylation Effects 0.000 description 1
- 238000006900 dealkylation reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/06—Boron halogen compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/20—Mica; Vermiculite
- C04B14/206—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68785284A | 1984-12-31 | 1984-12-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB8531865D0 GB8531865D0 (en) | 1986-02-05 |
| GB2169274A true GB2169274A (en) | 1986-07-09 |
Family
ID=24762135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB08531865A Withdrawn GB2169274A (en) | 1984-12-31 | 1985-12-30 | Silicate complexes and materials containing them |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS61163113A (nl) |
| CN (1) | CN85109768A (nl) |
| AU (1) | AU4931085A (nl) |
| BE (1) | BE903974A (nl) |
| DE (1) | DE3540102A1 (nl) |
| ES (1) | ES8700962A1 (nl) |
| FR (1) | FR2575484A1 (nl) |
| GB (1) | GB2169274A (nl) |
| IT (1) | IT1201509B (nl) |
| LU (1) | LU86236A1 (nl) |
| NL (1) | NL8503565A (nl) |
| SE (1) | SE8506154L (nl) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5462905A (en) * | 1992-08-21 | 1995-10-31 | Toyota Jidosha Kabushiki Kaisha | Exhaust gas purifying catalyst |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4367163A (en) * | 1981-04-15 | 1983-01-04 | Research Corporation | Silica-clay complexes |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1571983A (en) * | 1977-05-16 | 1980-07-23 | Imai M | Sol of ultra-fine particles of layered structure material |
| US4239519A (en) * | 1979-03-26 | 1980-12-16 | Corning Glass Works | Inorganic gels and ceramic papers, films, fibers, boards, and coatings made therefrom |
| US4510257A (en) * | 1983-12-08 | 1985-04-09 | Shell Oil Company | Silica-clay complexes |
-
1985
- 1985-10-30 ES ES548368A patent/ES8700962A1/es not_active Expired
- 1985-11-04 AU AU49310/85A patent/AU4931085A/en not_active Abandoned
- 1985-11-12 DE DE19853540102 patent/DE3540102A1/de not_active Withdrawn
- 1985-12-12 JP JP60278122A patent/JPS61163113A/ja active Pending
- 1985-12-20 IT IT23350/85A patent/IT1201509B/it active
- 1985-12-24 NL NL8503565A patent/NL8503565A/nl not_active Application Discontinuation
- 1985-12-24 FR FR8519134A patent/FR2575484A1/fr not_active Withdrawn
- 1985-12-30 GB GB08531865A patent/GB2169274A/en not_active Withdrawn
- 1985-12-30 CN CN198585109768A patent/CN85109768A/zh not_active Withdrawn
- 1985-12-30 SE SE8506154A patent/SE8506154L/ not_active Application Discontinuation
- 1985-12-30 LU LU86236A patent/LU86236A1/de unknown
- 1985-12-31 BE BE0/216090A patent/BE903974A/fr unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4367163A (en) * | 1981-04-15 | 1983-01-04 | Research Corporation | Silica-clay complexes |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5462905A (en) * | 1992-08-21 | 1995-10-31 | Toyota Jidosha Kabushiki Kaisha | Exhaust gas purifying catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| ES8700962A1 (es) | 1986-11-16 |
| NL8503565A (nl) | 1986-07-16 |
| SE8506154L (sv) | 1986-07-01 |
| CN85109768A (zh) | 1986-09-24 |
| BE903974A (fr) | 1986-06-30 |
| LU86236A1 (de) | 1986-06-11 |
| SE8506154D0 (sv) | 1985-12-30 |
| IT8523350A0 (it) | 1985-12-20 |
| ES548368A0 (es) | 1986-11-16 |
| FR2575484A1 (fr) | 1986-07-04 |
| JPS61163113A (ja) | 1986-07-23 |
| DE3540102A1 (de) | 1986-07-10 |
| GB8531865D0 (en) | 1986-02-05 |
| AU4931085A (en) | 1986-07-10 |
| IT1201509B (it) | 1989-02-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |