GB2128931A - Embossed surface covering and process for making the same - Google Patents

Abstract

An embossed, ornamented surface covering, suitable for use as a floor or wall tile, is made by: providing a decorated resinous film on a release carrier, with the decorated surface of the film facing away from the carrier; providing a pre-formed, low-density, reinforced, porous thermoplastic base material, which may include hollow, non-thermoplastic particles; interfacing the decorated surface of the film with the top surface of the base material; perforating the film and subjecting the structure to high frequency electrical energy and pressure in a flatbed press having a cooled embossing plate and a cooled back-up plate, to emboss the structure, fuse the resins and render the film substantially impermeable. <IMAGE>

Description

SPECIFICATION Embossed surface covering and process for making the same This invention relates to an embossed surface covering, especially one in tile form, and a process for forming it. More particularly, the invention relates to such a tile surface covering having deeply embossed areas and an improved replication of the embossed surface of the embossing plate.

It is known to produce embossed resinous surface coverings wherein the embossing is achieved chemically or mechanically. It is further known to provide decorative designs on such surface covering by applying variously-colored inks either to the top surface of the base material, or to a film wear layer thereon, prior to, or subsequent to, the embossing of the structure.

However, there have been problems in the past involving distortion of the material and the design thereon, registration of designs and embossing, the inability to obtain full replication of embossing surface detail, development of stresses in the product created during the formation thereof, and dimensional stability of the product, in the use of mechanical embossing where different depths of embossing combined with full replication of the embossing surface was desired.

U.S. Patent No. 3,562,059 relates to a method of decorating a plastic foam form by placing the printed face of the polymer film, blanked to the shape of the foam form, against the foam, covering the film with a woven ptfe cloth, applying heat and pressure to the face of the cloth, and then stripping the cloth from the film.

U.S. Patent No. 3,1 80,776 relates to the ornamentation of plastic articles by forming a color support blank of incompletely cured, filled, resinous material, printing decorations thereon with appropriate inks and subjecting the blank to a high frequency heat treatment to harden the inks.

A transparent incompletely cured, filled, plastic sheet of similar resinous material may then be placed on the previously formed blank, with the printed surface on the color support blank in contact with the transparent sheet. The product is formed by molding and fusing the material using heat and pressure.

U.S. Patent No. 3,024,154 relates to the art of embossing thermoplastic film which comprises heating a relatively thick sheet of thermoplastic material to a temperature above its softening temperature and that of the film, bringing one surface of the film in a relatively cool condition into contact with the surface of the thicker sheet, moving the film and sheet together between a cooled, indented embossing element and a backing element, to press the film and sheet into the identations in the embossing element, and then cooling the composite structure.

U.S. Patent No. 3,325,332 relates to a method of laminating a relatively thick plastic film to a compatible plastic foam by heat-softening the foam and pre-heating only the contacting surface of the film and then pressing the film and foam together.

The problems previously indicated herein have not been satisfactory solved by the foregoing prior art.

The present invention provides a process for making a stress-free embossed, ornamented surface covering comprising: (a) providing a resinous thermoplastic film on a release carrier, said resinous film being capable of being permeated and having design portions on the surface thereof facing away from the release carrier; (b) providing a low density, porous, thermoplastic resinous base material having top and bottom surfaces; (c) interfacing the design-bearing film surface with the top surface of the base material; (d) separating the release carrier from said film; and (e) embossing the film and base material while applying heat and pressure thereto to fuse the resinous material and render the film substantially impermeable.

The invention also provides an ornamented, multilevel embossed curl-resistant surface covering comprising: (a) a main body portion layer having a top surface and a bottom surface, said layer being comprised of a fused matrix of resinous dryblend containing homogeneously distributed therein originally hollow non-thermoplastic particles; (b) first depressed portions on said resinous layer; (c) second depressed portions on said resinous layer comprising fused resin in a substantially continuous phase and substantially completely crushed non-thermoplastic particles, said second depressed portions being depressed to a greater depth than said first depressed portions;; (d) raised portions on said resinous layer elevated with respect to said first and second depressed portions, said first depressed portions and said raised portions comprising fused resin in a relatively non-continuous phase with non-crushed and substantially only partially crushed non-thermoplastic particles therein; (e) a reinforcing material layer positioned between the top and bottom surfaces of said resinous layer; (f) a substantially impermeable transparent fused resinous wear layer bonded to the top surface of the main body layer; and (g) ornamentation located between the wear layer and the top layer of the main body layer.

As will be described in more detail below, there may be provided, between the ornamented wear layer and the main body layer a further layer, having a lower softening or fusion temperature than the wear layer.

The surface covering according to the invention is advantageously in the form of a floor or wall tile, and the following describes a preferred process for making it.

A transparent, thermoplastic film, capable of being permeated and having decorative design portions on one surface thereof, is placed on the top surface of a porous, low-density thermoplastic base material, with the decorated surface of the film being interfaced with the top surface of the base material.

The porous base material may be a lightly sintered resinous dryblend structure having hollow non-thermoplastic particles therein and may be reinforced with a material such as glass scrim.

The term "capable of being permeated" as used herein in describing the thermoplastic film indicates either that the film is initially permeable or that it may be rendered permeable at a later stage in the process prior to the embossing of the surface covering and fusion of the resins therein. The film may be cut to the desired tile dimensions in register with the design portions thereon while it is on the release carrier without cutting the carrier, interfaced with the top surface of a piece of the base material of similar size, and the release carrier removed, or the film may be interfaced with the top surface of a sheet of the base material, and the film and the base material cut in register with the design on the film simultaneously, after removal of the release carrier.Adhesive may be applied to the base materialcontacting surface of the film or the adhesive may be included in the ink used for the decoration on the film.

When laminating the film to the base material, heat at a temperature sufficient only to activate the adhesive is used, together with light pressure, to assure bonding of the film to the base material. In both cases, the base material with the decorated film thereon is then subjected to high frequency electrical energy and pressure in a flatbed press having a cooled embossing plate and a cooled back-up plate, to emboss the structure, fuse the resins and render the film impermeable. The film may be vinyl, and may be perforated to allow air trapped in the deeper recesses of the embossing plate to escape therethrough. The perforations are sealed during the embossing and fusing of the resins in the composite structure.

The prior art problems previously indicated herein are solved by the present invention. Since the base material is a porous low density material with hollow, non-thermoplastic particles therein, it can be compressed vertically in a flatbed press with a minimum of lateral flow. This permits deeper, more clearly defined embossing and less distortion in the product. The process further substantially eliminates the distortion of the decoration on the film and of the base material which is normally encountered when using a flatbed embossing press, especially with low density compositions that are difficult to heat and cool.In a preferred embodiment, the invention further controls distortion through the use of high frequency heating and compositions which are receptive thereto, coupled with cooling of the embossing and back-up plates of the press, so that the materials can be heated quickly to a temperature sufficient for embossing while avoiding distortion of the film ornamentation under pressure. Lack of distortion of the ornamentation of the film in the process of this invention, of course, makes it possible to easily emboss in register with the decoration on the film. As is commonly known, thermoplastic films are not dimensionally stable when heated sufficiently so that they must be embossed. They tend to expand or contract differently in different parts of the sheet.

The avoidance of heating the materials to high temperatures prior to the final embossing and fusion step substantially eliminates the build-up of stress in the materials. This, together with the flat, cooled bottom surface of the embossing press, the inclusion of the reinforcing glass scrim, and the use of high frequency heating, produces a product that is dimensionally stable, stays flat, and does not curl when subjected to conditions of heat and moisture.

Figure 1 is a flow diagram depicting the steps followed in carrying out various embodiments of the process of this invention; Figure 2 is an enlarged cross-sectional view of a portion of a first surface covering constructed according to the invention.

Figure 3 is a similar view of a portion of a further form of surface covering constructed according to the invention.

The flow diagram of Fig. 1 illustrates various embodiments of the invention.

In the first embodiment of the invention, the manufacturing process begins with the formation of a porous low density base material. As indicated in the flow chart of Fig. 1, a first dryblend layer is formed on a release carrier. In the formation of the base material a mixture of resinous dryblend particles and expanded perlite is prepared. The dryblend is in the form of a freeflowing homogeneous mixture of unfused thermoplastic resin particles, including liquid plasti cizer, filler, pigment, and vinyl stabilizer.

Poly(vinyl chloride) is the preferred resin for use in forming the surface covering of the present invention, although copolymers of vinyl chloride with minor proportions of other materials such as vinyl acetate, vinylidene chloride, other vinyl esters such as vinyl propionate, vinyl butyrate as well as alkyl substituted vinyl esters may be used.

Other thermoplastic resins which are receptive to high frequency heating or which can be combined with materials receptive to high frequency heating may also be used. These may include, for example, polyethylene, polyurethanes, polyesters, polyamides, polyacrylates (e.g., polymethyl methacrylates) as well as polymers derived from acetates and cellulose esters.

The free-flowing mix of resin, plasticizer, stabilizer, pigment, and filler may be readily formed by adding the resin, for example a homopolymer of vinyl chloride in the form of discrete particles, along with the vinyl resin plasticizer such as di-2-ethylhexyl phthalate, butylbenxyl phthalate, epoxidized soybean oil, or tricresyl phosphate, filler, pigment, and suitable vinyl resin stabilizers to a mixer, or blender, such as Henschel blender, where they are mixed under moderate heat, for instance, at a temperature of about 1 60"F (about 70 to 105"C), for a period of time to insure that the liquid plasticizer and the stabilizer become absorbed and thus diffused throughout the resin particles and the remaining ingredients adsorbed thereon.Care is taken that no fusion of the resin particles occurs during the mixing, and the temperature is kept below that at which such would occur. Generally speaking, the addition of fillers and pigments to the mix may be made either initially, at the end of the mixing cycle when the resin particles remain relatively warm, or after the dryblend particles have been mixed and cooled.

The dryblend composition useable in the present invention may include the following ingredients in the indicated ranges, based on 100 parts of resin: Ingredients Parts by Weight Poly(vinyl chloride) dispersion grade resin-Average Mw 70,000-80,000 50-100 Poly(vinyl chloride) blending grade resin-Average Mw 33,000-46,000 50-0 Dioctyl phthalate, plasticizer 25-75 Organotin stabilizer 1-3 Titanium dioxide paste (50% in DOP) 0-5 Limestone (50 mesh) filler 0-200 The dryblend/perlite mix used in the present invention is formed by a simple mixing or tumbling together of the two dry materials until a uniform blend is obtained. About 90 parts by weight of the dryblend and about 10.5 parts by weight of the perlite are used.

The quantity of perlite used in the composition, however, can be varied considerably, but the upper limit is determined by the ability of the composition to hold together in a useful manner after heating and consolidation. This upper level is affected by the particle size of the perlite used, and, since proportions by weight are under consideration, the density of the perlite particles. The perlite particles preferred for use in the present invention are available as Spherepack MM-100, sold by Patentech Corporation, Shepherd Grove, illinois. The particle size of the perlite useable in the present invention generally ranges from about 35 to 850 microns.

The average particle size for the Spherepack MM-100 perlite is about 60 microns. The effective range of the quantity of perlite useable would be between 2 and 20 percent by weight when combined with a quantity of dryblend in the range of from about 98 to 80 percent by weight.

The preferred range of the perlite used would be about 5 to 1 5 percent by weight, and the most preferred range would be about 8 to 1 2 percent by weight. The levels of other types of perlite, for example, the 3.5 and 10 pound/cubic foot (56 and 160 kg/m2) bulk density materials, may differ due to their larger particle size and/or density. Although it is preferred that the base material should be formed using expanded perlite as the hollow particles, it is contemplated that other hollow particles of, for example, glass, ceramic, or organic materials could be used within the scope of the invention.

A layer of the perlite-containing dryblend mixture about 100 mils (2.5 mm) thick is then formed on a release-surfaced carrier and heated to a temperature sufficient to cause surface portions of the resinous particles to melt slightly and stick together at their points of contact with each other. A reinforcing layer of non-woven glass scrim is then placed on the perlitecontaining dryblend layer so formed and light consolidating pressure is applied thereto. The glass scrim may have a basis weight of about 10g-50g/m2. Alternatively, the reinforcing layer may comprise woven or non-woven fibers of glass, polyester, polyamide, and the like.Another layer of similar thickness of the dryblend and perlite mixture is formed on top of the scrim and this second layer is then heated to a temperature similar to that used in forming the first layer and slight consolidating pressure is again applied. The resulting base material is now in a friable but suitable condition to be handled for further processing. It is also porous, allowing it to be subsequently compressed in a vertical direction with minimum lateral flow. It is also receptive to high frequency energy.

The preferred reinforced, sintered dryblend and expanded perlite composite is a unique porous structure in which each individual pore is reinforced by the rigid cellular structure of the individual expanded perlite particle. The collective effect of the many reinforced pores contributes to a great extent to the necessary dimensional stability and light weight of the product, while at the same time still allowing crushability during the embossing step with limited lateral flow.

Although it is preferred that the base material should be as described, other porous structures, such as open-celled thermoplastic resin foams (e.g., vinyl foam), thermoplastic matting, and the like may be used; however, results generally are not as good since print distortion, material extrusion, and structural collapse may occur during subsequent processing operations.

A dimensionally stable release carrier is then provided with a resinous thermoplastic film preferably about 4 mils (0.1 mm) thick and having ornamented design portions on the surface thereof facing away from the carrier. The film may, however, range from about 0.1-15.0 mils (0.0025 to 0.38 mm) in thickness and, at this point, may be permeable or impermeable, but must be capable of being permeated when the composite structure is subsequently embossed.

The film may be cast, extruded, or laminated onto the release carrier and the design or decoration may be applied either prior to, or subsequent to, application of the film to the release carrier. Also, it is recognized that the decoration may be applied to the top surfacce of the base material and a non-decorated film or a coating applied thereover. The film preferably comprises a poly(vinyl chloride) resin and/or copolymers thereof (e.g., vinyl chloride and acrylic monomers and copolymers such as ethylene-acrylic acid). However, other thermoplastic materials such as polyesters, polyurethanes, polyamides, polyolefins (e.g., polyethylenes), polyacrylates, and the like could be used in the invention. Adhesive may be applied to the decorative surface of the film or the adhesive may be in the ink or may be combined with the ink.

The film is then die-cut to the desired dimensions in register with the design while the film is on the release carrier, but without cutting the carrier. The base material is cut into shapes corresponding to those of the cut portions of the film.

The decorated surface of the cut portions of the film is then interfaced with the top surface of the shaped portions of the base material, the release carrier is removed and the film is perforated. The diecut film pieces may be preheated to only warm the adhesive so that lamination can be carried out at a relatively low temperature. The pieces of base material may also be pre-heated, but not all the way through. The composite structures so formed are then put into a flatbed press comprising a cooled deep embossing plate and a cooled flat back plate.

High frequency energy is applied after the press is closed. The temperature of the material goes from ambient temperature to about 350"F (177"C). The high frequency power is then turned off and the pieces are allowed to sit under pressure for about 4 to 20 seconds. The press is then opened, the pieces removed and die-cut in register. Adhesive is applied to the back of the pieces and release paper is applied.

In a second embodiment of the invention the same material and procedures are used except that the film and base material are die-cut simultaneously in register with the design portions on the film, after the design-bearing surface of the film has been interfaced with the top surface of the base material, and after separation of the release carrier from the film.

As shown in Fig. 2 of the drawings the surface covering produced by the foregoing processes comprises a main body portion layer 1 having a top surface 2 and a bottom surface 3 and comprises a fused matrix of resinous dryblend 4 with hollow non-thermoplastic particles 5 therein. The top surface 2 of the layer 1 has depressed portions 6 and 7 therein, depressed portions 7 being substantially deeper than depressed portions 6 and containing fused resin 8 in a substantially continuous phase with substantially completely crushed non-thermoplastic particles 9 therein. Raised portions 10 are provided on the top surface 2 of the main body layer 1 and are elevated with respect to both the depressed portions 6 and 7. The raised portions and the shallow depressed portions 6 comprise fused resin in a substantially non-continuous phase with non-crushed and substantially only partially crushed non-thermoplastic particles therein. A reinforcing non-woven glass scrim 11 is provided intermediate top and bottom surfaces 2 and 3 of the main body portion layer 1. A substantially impermeable transparent fused resinous wear layer 1 2 is bonded to the top surface 2 of the layer 1, and ornamentation 1 3 is provided between the wear layer and the top surface of the main body layer 1.A releasable covering 1 4 is secured by adhesive coating 1 5 to the bottom surface 3 of the surface covering to, upon removal of the covering 14, facilitate installation of the surface covering to a substrate such as a wall or floor. The surface covering is substantially stress free and has non-curling tendencies; is relatively easy and more economical to produce; and provides an improved, more aesthetically appealing product having improved stability.

It has been found that the perforations which aid in air release during embossing do not completely seal in some cases, for example, where the embossing plate is very deep and does not have enough raised areas to help seal the perforations, e.g., a deep, smooth, and recessed plate. Unsealed holes allow penetration of stains to the interior of the finished product which is undesirable. By incorporating a second resinous thermoplastic layer beneath the decorated top layer or film, which second layer has a lower softening, fusing or curing temperature, or which will flow at a temperature which is lower than that of the top decorated film, the healing of the perforations or holes of the top film is assisted. This is because the greatest heat is generated within the structure of the base which is next to the softer, more flowable second layer.

The second resinous thermoplastic layer may be a poly(vinyl chloride) layer, advantageously in the form of a plastisol or in the form of a sintered powder layer, such as that designated VYFS by Union Carbide. It could also be any of the other thermoplastic materials mentioned above for the base material, provided that it softens and starts to flow at a lower temperature than does the first, or top, perforated film or layer, thereby ensuring a complete closure of the perforations in the final product.

In the preferrd method of manufacture, in which the base material is heated by radio frequency energy, and the embossing plate is cooled, e.g., to about 180"F (82"C), the second layer will soften and flow before the top layer because the second layer is closer to the high temperature material. The resulting flow in the second layer contributes to the sealing of the perforations.

This embodiment, which may be employed in combination with either of the first and second embodiments (cutting the film in register on the release carrier, and cutting in register after applying the film to the base) is illustrated in Fig. 3 of the drawings, in which the same reference numerals as used in Fig. 2 indicate like feaures. A second thermoplastic layer 16 having a lower fusing temperature than that of the wear layer 1 2 is positioned between the wear layer carrying ornamentation 1 3 and the top surface of the main body portion layer 1.

The following examples illustrate the invention. All parts and percentages are by weight unless otherwise specified.

Example 1 In forming the base material for the surface covering of the present invention, dryblend granules were prepared by mixing the following components together in a conventional Herschel dryblending apparatus through a heat history from ambient conditions to 220"F (about 105"C) to ambient conditions, using the following ingredients in the indicated ranges: Ingredients Parts by Weight Poly(vinyl chloride) Dispersion Grade Resin 66.6 Poly(vinyl chloride) Blending Grade Resin 33.4 Dioctyl phthalate 25-75 Organotin Stabilizer 2 Titanium Dioxide Paste (50% in DOP) 2 Limestone (50 mesh) Filler 100 The dryblend granules formed as above were then mixed with perlite particles in the following proportions:: Parts by Weight Dryblend particles 90.0 *Perlite (Spherepack MM-100) 10.5 100.5 * A low density, hollow silica glass particle available from Patentech Corporation, Shepherd Grove, Illinois.

The above dry materials were mixed together by a simple tumbling operation until a uniform blend was obtained.

The dryblend mixture was deposited on a release-surfaced carrier to form a uniform layer of about 100 mils (2.5 mm) thick. Heat was then applied via infra-red irradiation of the top surface and electric heating of the lower platen for a period of about 2 minutes to bring the mixture to a temperature of about 375"F (1 90 C) to cause partial melting of surface portions of the dryblend granules and cause them to stick together at their points of contact. A sheet of non-woven glass scrim having a basis weight of about 35g/m2 and having linear dimensions similar to those of the dryblend layer was then placed thereon and slight consolidating pressure applied by passing the structure through a roll laminator.

Another layer of the same dryblend mixture similar in thickness to that of the first layer was deposited onto the glass scrim covering thereon and similarly heated and slightly consolidated.

After cooling, the composite sheet, which was approximately 100 mils (2.5 mm) thick, was cut into about 7 by 7 inch (18 x 18 cm) tile size portions which were low density, porous, reinforced and in a suitable condition for handling and further processing procedures.

A 4 mil (0.1 mm) poly(vinyl chloride) coating was applied to a 1.42 mil (0.036 mm) thick polyester release carrier and heated to an interface temperature of about 290"F (1 43 C). The resulting film was then printed with vinyl inks in a decorative pattern. An acrylic lacquer having the following composition was then applied to the decorated surface of the film to assure good bonding of the film to the base material.

Parts by Weight *A2lLV Resin 13 Ethyl Acetate 43 Methyl Ethyl Ketone 1 3 69 * A methyl methacrylate resin available from Rohm 8 Haas, Philadelphia, Pennsylvania.

The decorated film was then cut into shapes and sizes corresponding to those of the base material without cutting the release carrier. The decorated surface of the film was then interfaced with the top surface of the pieces of the base material which were pre-heated to warm the top surface portion only. Heat was applied from a silicone roller heated to about 440"F (205 C) to soften the adhesive on the decorated surface of the film, and light pressure was applied by a roll laminator to bond the film to the base material. After cooling, the release carrier was removed. The decorated film was then perforated using a pin roll to provide a plurality of openings spaced about 5/16" (8 mm) apart.

The composite structures were then placed in a flatbed press having water-cooled embossing and back-up plates. High frequency electrical energy was applied to fuse the resins in the structures which were then embossed by the downward pressure exerted by the embossing plate. The products were then allowed to cool under pressure, removed from the press, and diecut in register to remove excess trim. A water-based acrylic adhesive having the following formulation was then applied to the back of the finished pieces to facilitate their subsequent attachment to a surface such as a wall or floor: Parts by Weight *Polyacrylic Emulsion (UCAR174) 98.62 **Sodium Polyacrylic Solution (Alcogum 6940) 1.31 ***1 ,2-Benzisothiazolin-3-one (Proxel CRL) 0.7 * available from Union Carbide, Danbury, Connecticut ** available from Alco Chemical Col., Philadelphia, Pennsylvania available from ICI America, Inc., Wilmington, Delaware A release-coated paper was then applied onto the adhesive. The paper is easily removable at the time of installation of the product on a substrate. The product is a stress-fress, decorated, embossed surface covering having non-curling tendencies.

Example II A stress-free, embossed, ornamented surface covering was formed by using the same base material dryblend-perlite mixture and procedures as in Example I. The decorated film was also provided using the same materials and procedures as in Example I. In the formation of this surface covering, however, neither the ornamented film nor the base material was cut prior to lamination of the film and base material. In this procedure, the decorated surface of the film was interfaced with the top surface of the base material, and heat and pressure were applied to activate the adhesive. After cooling, the release carrier was removed, the film perforated and the film and base material cut simultaneously in register with the design on the film.

The embossing of the structure, fusing of the resins, die-cutting to remove excess trim, and application of adhesive and release paper to the back of the product were done in the same manner and using the same materials as in Example I.

Example 111 This example illustrates the use of a second layer of lower fusion temperature. A 3-4 mil poly(vinyl chloride) first coating time or layer is applied to a 1.42 mil (0.036 mm) thick polyester release carrier and heated at an interface temperature of about 290do (143"C). This is provided with a decorative pattern as described in Example I. A second layer consisting of a 1 mil (0.025 mm) poly(vinyl chloride) coating, and in this case containing white pigment, is applied to the decorated surface of the poly(vinyl chloride) film and heated to an interface temperature of 270"F (132"C). Thereafter the structure is applied to the base material formed as in Example I, so that the second layer is between the decorated upper film layer and the top surface of the base material. If an adhesive is used in the process it is applied to the decorated surface of the first coating or film layer to assure good bonding of the first and 5 second layers.

Claims (38)

1. A process for making a stress-free embossed, ornamented surface covering comprising: (a) providing a first resinous thermoplastic film on a release carrier, said resinous film being capable of being permeated and having design portions on the surface thereof facing away from the release carrier; (b) providing a low density, porous, thermoplastic resinous base material having top and bottom surfaces: (c) positioning the film on the top surface of the base material with the design-bearing film surface toward the base material: (d) separating the release carrier from said film; and (e) embossing the film and base material while applying heat and pressure thereto to fuse the resinous material and render the film substantially impermeable.

2. The process according to claim 1, wherein the first resinous film is a vinyl film.

3. The process according to claim 1, wherein the first resinous film is a polyamide, polyacrylate, polyurethane, polyester, or polyethylene.

4. The process according to any one of claims 1 to 3, wherein the first resinous film is made permeable by forming perforations therein.

5. The process according to any one of claims 1 to 4, wherein a shaped portion of the first resinous film is cut in register with the design portions thereon while it is on the release carrier without cutting the carrier, and prior to positioning the film on the top surface of the base material, and wherein the base material is provided in a size and shape corresponding to that of the cut portion of the film.

6. The process according to any one of claims 1 to 4 including the step of cutting the first film and base material in register with the design portions on the film after the film has been positioned on the top surface of the base material and after separation of the release carrier from the film.

7. The process according to any one of claims 1 to 6, wherein the base material is a vinyl resin dryblend composition.

8. The process according to any one of claims 1 to 7, wherein the base material comprises a pre-consolidated resinous dryblend including pre-formed, hollow particles.

9. The process according to any one of claims 1 to 6, wherein the base material is a porous low density, thermoplastic resinous foam.

10. The process according to claim 9, wherein the porous foam is a vinyl foam composition.

11. The process according to any one of claims 1 to 6, wherein the base material is provided by: (1) preparing a mixture comprising from 98 to 80 percent by weight of vinyl resin dryblend composition, and from 2 to 20 percent by weight of expanded perlite particles composed essentially of particles having a diameter of from 35 to 850 microns; (2) forming a first layer of said mixture to a desired thickness on a release surface; (3) heating said first layer of said mixture at a temperature sufficient to cause partial melting of the dryblend granules at their points of contact, thereby forming bonds which result in the formation of a cohesive porous layer; (4) applying a reinforcing material onto the surface of the cohesive porous dryblend layer; (5) applying slight consolidating pressure to the composite structure so formed:: (6) forming a second layer of the mixture prepared in step (1) to a desired thickness on the reinforcing material-dryblend structure formed by steps (4) and (5); (7) heating said second layer of said mixture as in step (3) to obtain similar results; and (8) applying slight consolidating pressure to said second cohesive porous layer, thereby obtaining a low-density, porous, reinforced, thermoplastic resinous structure which is receptive to high frequency electrical energy and capable of being further consolidated by vertically applied pressure, with a minimum of lateral extrusion.

1 2. The process according to any one of claims 1 to 11, wherein the heat and pressure applied to the film and the base material to fuse and emboss the composite structure and render the film impermeable are accomplished by placing the structure in a flatbed press having a cooled embossing plate and a cooled backing plate and applying high frequency electrical energy to the structure after the press is closed.

1 3. The process according to any one of claims 1 to 12, wherein an adhesive layer is provided on the design-bearing film surface to assist its bonding to an adjacent layer.

1 4. A process according to any one of claims 1 to 13, which also comprises the step, carried out between steps (a) and (c), of (a') providing a second resinous thermoplastic layer on the surface of the first resinous thermoplastic layer remote from the release carrier, said second layer having a lower fusion temperature than that of the first layer, the second resinous layer then being contacted in step (c) with the top surface of the base material provided by step (b).

1 5. The process according to claim 1 4, wherein the second resinous layer is a vinyl film.

16. The process according to claim 14, wherein the second resinous thermoplastic layer is a lightly sintered resinous powder.

1 7. The process according to claim 16, wherein the resinous thermoplastic powder is a vinyl or vinyl dryblend.

1 8. The process according to claim 1 4 or claim 16, wherein the second thermoplastic layer is a polyamide, polyacrylate, polyurethane, polyester, or polyethylene.

1 9. The process according to any one of claims 14 to 18, wherein the first and second layers are made permeable by forming perforations therein.

20. The process according to claim 1 carried out substantially as described with reference to any one or more of the accompanying drawings.

21. The process according to claim 1 carried out substantially as described in any one of the Examples.

22. An ornamented, multilevel embossed curl-resistant surface covering comprising: (a) a main body portion layer having a top surface and a bottom surface, said layer being comprised of a fused matrix of resinous dryblend having uniformly distributed therein originally hollow non-thermoplastic particles; (b) first depressed portions on said resinous layer; (c) second depressed portions on said resinous layer comprising fused resin in a substantially continuous phase and substantially completely crushed non-thermoplastic particles, said second depressed portions being depressed to a greater depth than said first depressed portions;; (d) raised portions on said resinous layer elevated with respect to said first and second depressed portions, said first depressed portions and said raised portions comprising fused resin in a relatively non-continuous phase with non-crushed and substantially only partially crushed non-thermoplastic particles therein; (e) a reinforcing material layer positioned between the top and bottom surface of said resinous layer; (f) a substantially impermeable transparent fused resinous wear layer overlying the top surface of the main body layer; and (g) ornamentation located between the wear layer and the top layer of the main body layer.

23. A surface covering product according to claim 22, which also comprises a substantially impermeable fused second resinous layer bonded to the top surface of the main body layer and bonded to the ornamented surface of the wear layer.

24. A surface covering product according to claim 23, wherein the fusion temperature of the second layer is lower than that of the wear layer.

25. A surface covering product according to claim 23 or claim 24, wherein the second resinous layer is a plasticized vinyl resin.

26. A surface covering product according to claim 23 or claim 24, wherein the second resinous layer is a polyamide, polyacrylate, polyurethane, polyester, or polyethylene.

27. A surface covering product according to claim 22, wherein the ornamented surface of the wear layer is bonded to the top surface of the main body layer.

28. A surface covering product according to any one of claims 22 to 27, wherein the ornamented surface of the wear layer is provided with a layer of adhesive to assist bonding to the surface adjacent thereto.

29. A surface covering product according to any one of claims 22 to 28, wherein the fused resinous dryblend layer is a plasticized, vinyl resin composition.

30. A surface covering product according to claim 29, wherein the vinyl resin is poly(vinyl chloride).

31. A surface covering product according to any one of claims 22 to 30, wherein the crushed and partially crushed, originally hollow, non-thermoplastic particles are perlite.

32. A surface covering product according to any one of claims 22 to 31, wherein the reinforcing material layer is glass scrim.

33. A surface covering product according to any one of claims 22 to 32, wherein the resinous wear layer is a plasticized vinyl resin.

34. A surface covering product according to any one of claims 22 to 32, wherein the resinous wear layer is a polyamide, polyacrylate, polyurethane, polyester, polyethylene.

35. A surface covering product according to any one of claims 22 to 34 including an adhesive coating on the bottom surface of the main body portion layer and a releasable material covering said coating and held in place by the adhesive.

36. A surface covering product substantially as described with reference to and as illustrated by Fig. 2 or Fig. 3 of the accompanying drawings.

37. A surface covering product substantially as described in any one of the examples herein.

38. Any new and novel feature or combination of features herein described.