JPH0216254A - Chip pattern decoration member and its manufacture - Google Patents
Chip pattern decoration member and its manufactureInfo
- Publication number
- JPH0216254A JPH0216254A JP16748188A JP16748188A JPH0216254A JP H0216254 A JPH0216254 A JP H0216254A JP 16748188 A JP16748188 A JP 16748188A JP 16748188 A JP16748188 A JP 16748188A JP H0216254 A JPH0216254 A JP H0216254A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- chips
- pattern
- pvc
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000005034 decoration Methods 0.000 title abstract 5
- 239000011347 resin Substances 0.000 claims abstract description 28
- 229920005989 resin Polymers 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 26
- 239000006260 foam Substances 0.000 claims abstract description 14
- 238000005187 foaming Methods 0.000 claims abstract description 8
- 239000010410 layer Substances 0.000 claims description 58
- 239000004800 polyvinyl chloride Substances 0.000 claims description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 9
- 239000011247 coating layer Substances 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- 235000013405 beer Nutrition 0.000 claims 1
- 229920001944 Plastisol Polymers 0.000 abstract description 5
- 239000004999 plastisol Substances 0.000 abstract description 5
- 239000000843 powder Substances 0.000 abstract description 5
- 239000004745 nonwoven fabric Substances 0.000 abstract description 4
- 239000003365 glass fiber Substances 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000004156 Azodicarbonamide Substances 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 2
- 235000019399 azodicarbonamide Nutrition 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 238000009408 flooring Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000000059 patterning Methods 0.000 description 2
- WZRRRFSJFQTGGB-UHFFFAOYSA-N 1,3,5-triazinane-2,4,6-trithione Chemical compound S=C1NC(=S)NC(=S)N1 WZRRRFSJFQTGGB-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は床材、壁材等の内装材に適したチップ模様装飾
材に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a chip pattern decorative material suitable for interior materials such as flooring and wall materials.
（従来技術）
床材として特公昭５４−９４３号公報に記載されたケミ
カルエンボス発泡体上に模様チップが被覆された状態で
透明樹脂耐摩耗層を形成するのは公知である。(Prior Art) It is known to form a transparent resin wear-resistant layer on a chemically embossed foam covered with pattern chips as described in Japanese Patent Publication No. 54-943 as a flooring material.
しかしながら、上記装飾材では模様チップは同調エンボ
ス模様上に付与され、上から透視するという補助的な役
割で、立体感に乏しく意匠性も満足されなかった。However, in the above-described decorative material, the pattern chip is provided on the matching embossed pattern and has an auxiliary role of being seen through from above, resulting in a lack of three-dimensional effect and an unsatisfactory design.
（本発明の１ｔｌｊｌｉ） 本発明は上記問題点を解消し、立体感もあり。(1tljli of the present invention) The present invention solves the above problems and also provides a three-dimensional effect.
意匠性の優れた装飾材を提供することを目的とする。The purpose is to provide decorative materials with excellent design.
（発明の構成）
本発明製造方法は発泡性樹脂層上に発泡抑制剤含有イン
キで模様層が形成される工程と、該模様層上にポリ塩化
ビニルドライブレンドを塗工して均一層を形成する工程
と、ドライブレンド層上に前記模様層が透視可能に分散
載置される工程と、該ドライブレンド層が溶融しない程
度に焼結される工程と、ポリ塩化ビニルペーストを塗工
する工程と、得られた積層体を加熱して樹脂を発泡及び
ゲル化する工程からなることを特徴とするチップ模様装
飾材の製造方法、をその要旨とする。(Structure of the Invention) The manufacturing method of the present invention includes a step in which a pattern layer is formed on a foamable resin layer using an ink containing a foaming inhibitor, and a polyvinyl chloride dry blend is coated on the pattern layer to form a uniform layer. A step of dispersing the pattern layer on the dry blend layer so that it can be seen through, a step of sintering the dry blend layer to an extent that it does not melt, and a step of applying a polyvinyl chloride paste. The gist of the present invention is a method for producing a chip pattern decorative material, which comprises a step of heating the obtained laminate to foam and gel the resin.
ガラス不織布、セルロースフェルト、または剥離性材な
どの基材１上に発泡性ｐｖｃペースト２をドクターブレ
ード３で０．１〜０．５閾に塗工する。A foamable PVC paste 2 is applied with a doctor blade 3 to a thickness of 0.1 to 0.5 on a base material 1 such as a glass nonwoven fabric, cellulose felt, or a removable material.
本発明において発泡体を形成するには、ＰＶＣ１００重
量部に対して可塑剤２０〜１００部、アゾジカルボンア
ミド等の発泡剤が０．２〜１０重量部、その他酸化亜鉛
等の発泡助剤、安定剤等を適宜添加すればよい。In order to form a foam in the present invention, for 100 parts by weight of PVC, 20 to 100 parts of a plasticizer, 0.2 to 10 parts by weight of a foaming agent such as azodicarbonamide, and other foaming aids such as zinc oxide, stabilizers, etc. What is necessary is just to add an agent etc. suitably.
得られたペースト層はヒーター４でプリゲル化後、グラ
ビヤロールスクリーンまたは転写装置または他のランダ
ム模様付は装置等の模様付与手段５でインキによる模様
層を付与し。The obtained paste layer is pre-gelled with a heater 4, and then a patterned layer of ink is applied with a patterning means 5 such as a gravure roll screen, a transfer device, or other random patterning device.
模様６上にＰｖＣドライブレンドパウダー７をドクター
８で０．１〜２■に塗工し、ホッパー９から望ましくは
１〜２０ｍｍ角、厚さ０．１〜２ｍの装飾チップ１０を
５〜１００ｇ／ｒｒ？の割合で散布する。この時、ビニ
ル・ドライブレンドとして一般に引用される樹脂混合体
は自由流動性粉末状で、それは不溶熱可塑性ビニル樹脂
粒、流体ビニル可塑剤およびビニル安定剤からなる均一
混合体である。Apply 0.1 to 2 cm of PvC dry blend powder 7 on the pattern 6 using a doctor 8, and then add 5 to 100 g of decorative chips 10, preferably 1 to 20 mm square and 0.1 to 2 m thick, from the hopper 9. rr? Spray at the rate of At this time, the resin mixture, commonly referred to as a vinyl dry blend, is in the form of a free-flowing powder, which is a homogeneous mixture of insoluble thermoplastic vinyl resin particles, a fluid vinyl plasticizer, and a vinyl stabilizer.
樹脂、可塑剤、安定剤からなる自由流動混合体は例えば
、粒状の塩化ビニル・ホモポリマーなる樹脂をフタル酸
ジー（２−エチルヘキシル）、フタル酸ブチル・ベンジ
ル、エポキシ化大豆油、またはリン酸トリクレジル、充
填剤、顔料および適当なビニル樹脂安定剤を混合するこ
とにより容易に作製できる。混合は、ヘンシェル（）ｌ
ｅｎｓｅｈｅｌ）混合機のような標準混合機で行い、流
体可塑剤および安定剤が樹脂粒全体に拡散するように適
当な温度で適当な時間配合材を混合する。Free-flowing mixtures of resin, plasticizer, and stabilizer can be prepared, for example, by combining particulate vinyl chloride homopolymer resin with di(2-ethylhexyl) phthalate, butyl benzyl phthalate, epoxidized soybean oil, or tricresyl phosphate. , a filler, a pigment and a suitable vinyl resin stabilizer. The mixture is Henschel ()l
The formulations are mixed in a standard mixer, such as a resin blender, at a suitable temperature and for a suitable time to allow the fluid plasticizer and stabilizer to diffuse throughout the resin granules.
混合中に樹脂粒が溶けないように注意し、温度は融点以
下に保持する必要がある。Care must be taken not to melt the resin particles during mixing, and the temperature must be kept below the melting point.
また、層を形成されたビニル・ドライブレンドは透明層
が得られる。粉末自由流動混合体の調製には、樹脂１０
０重量部当たり可塑剤１．５〜６０重量部、安定剤２〜
５重量部を用いる。この後、上記ドライブレンド層をヒ
ーター１１で溶融しない程度に１５０〜１８０℃で加熱
焼結する。この加熱焼結した状態ではドライブレンド層
は多孔質である。In addition, a layered vinyl dry blend provides a transparent layer. For the preparation of powder free-flowing mixtures, resin 10
1.5 to 60 parts by weight of plasticizer, 2 to 60 parts by weight of stabilizer per 0 parts by weight
5 parts by weight is used. Thereafter, the dry blend layer is heated and sintered with a heater 11 at 150 to 180°C to an extent that it does not melt. In this heated and sintered state, the dry blend layer is porous.
この後、所望によりロール１２．１２′で装飾チップ１
０を軽く押圧してもよい。After this, if desired, the decorative chips 1 are
You may also press 0 lightly.
その後、ＰｖＣペースト１３をドクターブレード１４で
装飾チップ上に０．１〜１ｍｍ形成されるように塗工す
ると、装飾チップはそのままペーストで被覆された状態
１５で残り、チップのない多孔質ドライブレンド層上の
ＰｖＣペーストはドライブレンド層中に吸収される。Thereafter, when the PvC paste 13 is applied to the decorative chip to a thickness of 0.1 to 1 mm using a doctor blade 14, the decorative chip remains coated with the paste 15, and a porous dry blend layer with no chips is formed. The top PvC paste is absorbed into the dry blend layer.
この後、シートはオーブン１６で１８０〜２５０℃で加
熱され、ゲル化と同時に発泡性樹脂層は発泡され、かつ
前記模様層のインキ中に含有される発泡抑制剤でケミカ
ルエンボスされる。基材が剥離性材である場合は基材を
剥して本発明装飾シート１７を得る。Thereafter, the sheet is heated in an oven 16 at 180 to 250° C., and at the same time as it gels, the foamable resin layer is foamed and chemically embossed with a foam suppressor contained in the ink of the pattern layer. When the base material is a removable material, the base material is peeled off to obtain the decorative sheet 17 of the present invention.
第２図は本発明装飾材の断面図である６本発明装飾材は
発泡層全面に模様層とこの模様層に同調したエンボスを
有し、この模様層表面に透明被覆層が形成され、この被
覆層表面に模様層が透視可能に装飾チップが散在し、該
チップ表面が透明樹脂で被覆されたチップ模様装飾材、
をその要旨とする。Figure 2 is a cross-sectional view of the decorative material of the present invention.6 The decorative material of the present invention has a pattern layer on the entire surface of the foam layer and embossments in phase with this pattern layer, and a transparent coating layer is formed on the surface of this pattern layer. A chip pattern decorative material in which decorative chips are scattered on the surface of the coating layer so that the pattern layer can be seen through, and the chip surface is coated with a transparent resin;
The gist is:
発泡層１８はｐｖｃペーストの０．３〜３．０ｍの発泡
層であり、アゾジカルボンアミド等の発泡剤を含有して
最終工程で加熱発泡する。このｐｖｃ発泡層裏面には所
望により織布、不織布、合成樹脂の発泡または非発泡シ
ートの裏打ち材１を積層してもよい６ＰｖＣ発泡層上に
は望ましくは印刷による模様層６が形成されている。模
様層を形成するインキの一部に発泡抑制剤を含有させて
おくことにより模様層と同調したケミカルエンボスが得
られる。The foam layer 18 is a 0.3 to 3.0 m foam layer of PVC paste, contains a foaming agent such as azodicarbonamide, and is heated and foamed in the final step. On the back side of this PVC foam layer, a backing material 1 of woven fabric, non-woven fabric, foamed or non-foamed sheet of synthetic resin may be laminated as desired.6 A pattern layer 6 is preferably formed by printing on the PvC foam layer. . By containing a foaming inhibitor in a part of the ink forming the pattern layer, chemical embossing that is in sync with the pattern layer can be obtained.
このエンボス面に均一厚さで透明樹脂層１９が得られる
。透明樹脂層１９はドライブレンド焼結多孔質層中にＰ
ｖＣペーストが含浸された状態でドライブレンド層を溶
融して透明樹脂層を形成する。A transparent resin layer 19 having a uniform thickness is obtained on this embossed surface. The transparent resin layer 19 contains P in the dry blend sintered porous layer.
The dry blend layer impregnated with vC paste is melted to form a transparent resin layer.
透明樹脂層上に１〜２０ｎｎ角、厚さ０．１〜２膿の装
飾チップ１０が散布されており、装飾チップ間を通して
下の模様が透視できる。Decorative chips 10 of 1 to 20 nn square and 0.1 to 2 mm thick are scattered on the transparent resin layer, and the pattern underneath can be seen through between the decorative chips.
さらにこの装飾チップは透明樹脂２０により被覆される
。この透明樹脂被覆部２０は０．１〜ＩＩＩＩｌの厚さ
で、装飾チップ上に厚盛すされるのが望ましい。Further, this decorative chip is covered with a transparent resin 20. This transparent resin coating part 20 has a thickness of 0.1 to IIIl and is desirably applied thickly onto the decorative chip.
本発明により得られた装飾材１７は意匠性と立体感を兼
備したものであった。Decorative material 17 obtained according to the present invention had both design and three-dimensional appearance.
（発明の効果）
発泡体上に印刷模様と同調したエンボスが形成され、透
明樹脂中に装飾チップが散在しており、装飾チップ上に
は盛上り状に透明樹脂で被覆され、かつ装飾チップ間か
らは印刷模様が透視され１歩行感、立体感、意匠性をす
べて具備した装飾材が得られた。(Effects of the invention) Embosses are formed on the foam in synchronization with the printed pattern, decorative chips are scattered in the transparent resin, the decorative chips are coated with the transparent resin in a raised shape, and there are gaps between the decorative chips. The printed pattern could be seen through, and a decorative material with a sense of walking, three-dimensionality, and design was obtained.
実施例
ｐｖｃ樹脂含浸ガラス繊維不織布に配合Ａの発泡性Ｐｖ
Ｃプラスチゾルを０．４請塗工し、１８０℃・３０秒加
熱してプリゲル化した。Example: PVC resin-impregnated glass fiber nonwoven fabric with foaming Pv of formulation A
C plastisol was applied for 0.4 coats and heated at 180°C for 30 seconds to form a pregel.
ブリゲル化されたプラスチゾル層上にインキの一部に発
泡抑制剤（チオシアヌール酸）を添加した印刷インキを
転写して模様層を形成し、さらにその模様層の上に市販
のＰＶＣドライブレンド粉を均一に０．７ｎｙ＋＋の厚
さに塗工した。ドライブレンド層上に厚さ０．３ｍのｌ
Ｏ〜１６メツシユのＰｖＣチップを前記模様層が透視し
うるように散布し、１８０℃で１分間ロールで加熱加圧
した。 ４゜その後、配合ＢのＰｖＣプラス
チゾルを上記チップを被覆するように０．２ｎｏの厚さ
で塗工し、２００℃で２分間加熱し、ドライブレンド層
と表面透明層をゲル化させると共に発泡性層を加熱発泡
させてケミカルエンボスのある本発明装飾材を得た。A pattern layer is formed by transferring a printing ink containing a foaming inhibitor (thiocyanuric acid) to a portion of the ink onto the brigelized plastisol layer, and then a commercially available PVC dry blend powder is uniformly spread over the pattern layer. It was coated to a thickness of 0.7ny++. 0.3 m thick l on the dry blend layer
PvC chips of 0 to 16 meshes were scattered so that the pattern layer could be seen through, and heated and pressed with a roll at 180° C. for 1 minute. 4゜After that, the PvC plastisol of Formulation B was applied to a thickness of 0.2NO to cover the above chip, and heated at 200°C for 2 minutes to gel the dry blend layer and the surface transparent layer and to form a foamable layer. The layer was heated and foamed to obtain a chemically embossed decorative material of the present invention.
れており、本発明装飾材全体として優れた歩行感と立体
感のある意匠性が得られた。As a result, the overall decorative material of the present invention had an excellent walking feeling and a three-dimensional design.
第１図は本発明装飾材製造工程図、第２図は本発明装飾
材断面図である。
１０は装飾チップ、１７は装飾材、２０は透明樹脂層で
ある。
以上FIG. 1 is a manufacturing process diagram of the decorative material of the present invention, and FIG. 2 is a sectional view of the decorative material of the present invention. 10 is a decorative chip, 17 is a decorative material, and 20 is a transparent resin layer. that's all
Claims (1)
スを有し、この模様層表面に透明被覆層が形成され、こ
の被覆層表面に模様層が透視可能に装飾チップが散在し
、該チップ表面が透明樹脂で被覆されたチップ模様装飾
材。 ２、発泡性樹脂層上に発泡抑制剤含有インキで模様層が
形成される工程と、該模様層上にポリ塩化ビニルドライ
ブレンドを塗工して均一層を形成する工程と、ドライブ
レンド層上に前記模様層が透視可能に分散載置される工
程と、該ドライブレンド層が溶融しない程度に焼結され
る工程と、ポリ塩化ビールペーストを塗工する工程と、
作られた積層体を加熱して樹脂を発泡及びゲル化する工
程からなることを特徴とするチップ模様装飾材の製造方
法。[Claims] 1. The foam layer has a pattern layer and embossments in phase with the pattern layer on the entire surface, a transparent coating layer is formed on the surface of the pattern layer, and the pattern layer is decorated so that it can be seen through the surface of the coating layer. A chip pattern decorative material in which chips are scattered and the surface of the chips is coated with a transparent resin. 2. A step of forming a pattern layer with an ink containing a foaming inhibitor on the foamable resin layer, a step of coating a polyvinyl chloride dry blend on the pattern layer to form a uniform layer, and a step of forming a uniform layer on the dry blend layer. a step of dispersing the pattern layer so that it can be seen through, a step of sintering the dry blend layer to the extent that it does not melt, a step of applying a polychloride beer paste,
A method for producing a chip pattern decorative material, comprising the steps of heating the produced laminate to foam and gel the resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16748188A JPH0216254A (en) | 1988-07-04 | 1988-07-04 | Chip pattern decoration member and its manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16748188A JPH0216254A (en) | 1988-07-04 | 1988-07-04 | Chip pattern decoration member and its manufacture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0216254A true JPH0216254A (en) | 1990-01-19 |
Family
ID=15850482
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16748188A Pending JPH0216254A (en) | 1988-07-04 | 1988-07-04 | Chip pattern decoration member and its manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0216254A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0395434U (en) * | 1990-01-20 | 1991-09-30 | ||
| JPH03230945A (en) * | 1990-02-02 | 1991-10-14 | Toto Ltd | Frp molded article |
| KR100409091B1 (en) * | 2001-11-15 | 2003-12-11 | 주식회사 엘지화학 | PVC Flooring Matched Print and Embossed Pattern |
| KR100423842B1 (en) * | 2000-12-30 | 2004-03-24 | 주식회사 금강고려화학 | Floor with pastel and cubic quality, and exceellant durability |
| KR100730089B1 (en) * | 2005-03-05 | 2007-06-20 | 이상원 | Concrete exterior wall patterned composite exterior panel |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57143059A (en) * | 1981-03-02 | 1982-09-04 | Lonseal Kogyo Kk | Decorative elastic floor carpet having membossed pattern and production thereof |
-
1988
- 1988-07-04 JP JP16748188A patent/JPH0216254A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57143059A (en) * | 1981-03-02 | 1982-09-04 | Lonseal Kogyo Kk | Decorative elastic floor carpet having membossed pattern and production thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0395434U (en) * | 1990-01-20 | 1991-09-30 | ||
| JPH03230945A (en) * | 1990-02-02 | 1991-10-14 | Toto Ltd | Frp molded article |
| KR100423842B1 (en) * | 2000-12-30 | 2004-03-24 | 주식회사 금강고려화학 | Floor with pastel and cubic quality, and exceellant durability |
| KR100409091B1 (en) * | 2001-11-15 | 2003-12-11 | 주식회사 엘지화학 | PVC Flooring Matched Print and Embossed Pattern |
| KR100730089B1 (en) * | 2005-03-05 | 2007-06-20 | 이상원 | Concrete exterior wall patterned composite exterior panel |
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