GB2116552B - Process for hydrogenolysis of carboxylic acid esters - Google Patents

Process for hydrogenolysis of carboxylic acid esters

Info

Publication number
GB2116552B
GB2116552B GB08306413A GB8306413A GB2116552B GB 2116552 B GB2116552 B GB 2116552B GB 08306413 A GB08306413 A GB 08306413A GB 8306413 A GB8306413 A GB 8306413A GB 2116552 B GB2116552 B GB 2116552B
Authority
GB
United Kingdom
Prior art keywords
carboxylic acid
hydrogenolysis
acid esters
kpa
absolute
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB08306413A
Other versions
GB2116552A (en
GB8306413D0 (en
Inventor
Michael William Bradley
Norman Harris
Keith Turner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey Davy Technologies Ltd
Davy Mckee Ltd
Original Assignee
Davy Mckee Ltd
Davy Mckee London Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Davy Mckee Ltd, Davy Mckee London Ltd filed Critical Davy Mckee Ltd
Publication of GB8306413D0 publication Critical patent/GB8306413D0/en
Publication of GB2116552A publication Critical patent/GB2116552A/en
Application granted granted Critical
Publication of GB2116552B publication Critical patent/GB2116552B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B31/00—Reduction in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for effecting hydrogenolysis of a carboxylic acid ester comprising contacting a vaporous mixture containing the ester and hydrogen with a catalyst comprising a reduced mixture of copper oxide and zinc oxide at a temperature in the range of from about 75<o>C up to about 300<o>C and at a pressure in the range of from about 0.1 kg/cm<2> absolute (about 9.8 kPa) up to about 100 kg/cm<2> absolute (9813 kPa).
GB08306413A 1981-04-29 1982-04-21 Process for hydrogenolysis of carboxylic acid esters Expired GB2116552B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US25873381A 1981-04-29 1981-04-29
GB8203701 1982-02-09
PCT/GB1982/000118 WO1982003854A1 (en) 1981-04-29 1982-04-21 Process fo enolysis of carboxylic acid esters

Publications (3)

Publication Number Publication Date
GB8306413D0 GB8306413D0 (en) 1983-04-13
GB2116552A GB2116552A (en) 1983-09-28
GB2116552B true GB2116552B (en) 1985-09-25

Family

ID=26281940

Family Applications (1)

Application Number Title Priority Date Filing Date
GB08306413A Expired GB2116552B (en) 1981-04-29 1982-04-21 Process for hydrogenolysis of carboxylic acid esters

Country Status (13)

Country Link
JP (1) JPS58500993A (en)
AU (1) AU560590B2 (en)
BR (1) BR8207962A (en)
CA (1) CA1229096A (en)
FI (1) FI831848L (en)
GB (1) GB2116552B (en)
IT (1) IT1190783B (en)
MX (1) MX156577A (en)
NL (1) NL191438C (en)
NO (1) NO824396L (en)
NZ (1) NZ200442A (en)
SE (1) SE452154B (en)
WO (1) WO1982003854A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9212114B2 (en) 2012-10-09 2015-12-15 Johnson Matthey Davy Technologies Limited Process for the production of a fatty alcohol from a fatty acid
EP3010876B1 (en) 2013-06-19 2018-08-08 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for producing fatty alcohols from fatty acid methyl ester

Families Citing this family (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0104197B1 (en) * 1982-03-26 1986-05-28 DAVY McKEE (LONDON) LIMITED Process for the production of ethanol
US4588848A (en) * 1984-11-01 1986-05-13 Air Products And Chemicals, Inc. Synthesis of neoalkanols
US4593147A (en) * 1984-11-01 1986-06-03 Air Products And Chemicals, Inc. Synthesis of neoalkanes
DE3510883A1 (en) * 1985-03-26 1986-10-09 Kali-Chemie Ag, 3000 Hannover METHOD FOR PRODUCING 2.2.2.-TRIFLUORAETHANOL
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
US4837367A (en) * 1987-08-03 1989-06-06 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds
US4837368A (en) * 1988-02-01 1989-06-06 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
US4810807A (en) * 1987-10-13 1989-03-07 The Standard Oil Company Hydrogenation of maleic anhydride to tetrahydrofuran
JP2772524B2 (en) * 1988-07-15 1998-07-02 東燃株式会社 Method for producing 1,4-butanediol
DK0454704T3 (en) * 1989-01-17 1995-09-11 Davy Mckee London Process for the production of fatty alcohols
GB8917862D0 (en) * 1989-08-04 1989-09-20 Davy Mckee London Process
DE3930288A1 (en) * 1989-09-11 1991-03-21 Henkel Kgaa COPPER SILICATE CATALYST, ITS MANUFACTURING METHOD AND ITS USE
CA2026275C (en) * 1989-10-17 2000-12-05 Deepak S. Thakur Hydrogenation catalyst, process for preparing and process of using said catalyst
JP2595358B2 (en) * 1989-12-07 1997-04-02 東燃株式会社 Method for producing 1,4-butanediol and tetrahydrofuran
GB9025708D0 (en) * 1990-11-27 1991-01-09 Unilever Plc Fatty ester hydrogenation
DE4141220A1 (en) * 1991-12-13 1993-06-17 Basf Ag PROCESS FOR THE PREPARATION OF PRIMARY ALCOHOLS
DE4142899A1 (en) * 1991-12-23 1993-06-24 Sued Chemie Ag METHOD FOR PRODUCING ALCOHOLS BY CATALYTIC HYDRATION OF CARBONIC ACID ALKYL ESTERS
DE4206750A1 (en) * 1992-03-04 1993-09-09 Hoechst Ag METHOD FOR PRODUCING ALCOHOLS OR AMINES
DE4233431A1 (en) * 1992-10-05 1994-04-07 Basf Ag Process for the hydrogenation of citric acid
US5334779A (en) * 1993-06-01 1994-08-02 Eastman Kodak Company Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters
DE69417720T2 (en) * 1993-10-08 1999-07-29 Ube Industries METHOD FOR PRODUCING DIOLES
GB9324783D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
GB9324752D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
GB9324786D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
GB9324823D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
GB9324782D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
GB9324753D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
GB9324784D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
GB9324785D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
DE4431220A1 (en) 1994-09-02 1996-03-07 Bayer Ag Process for the preparation of 1,4-butanediol from maleic anhydride
DE19500783A1 (en) * 1995-01-13 1996-07-18 Bayer Ag Process for the preparation of aliphatic alpha, omega diols
EP0833808B1 (en) * 1995-06-20 2000-05-03 Kao Corporation Method for producing alcohol
DE19711404A1 (en) * 1997-03-19 1998-09-24 Hoechst Ag Process for the preparation of aromatic alcohols
DE19754788A1 (en) * 1997-12-10 1999-06-17 Bayer Ag Process for the preparation of aliphatic alpha, omega diols
US7074603B2 (en) 1999-03-11 2006-07-11 Zeachem, Inc. Process for producing ethanol from corn dry milling
PL203207B1 (en) 1999-03-11 2009-09-30 Zeachem Inc Process for producing ethanol
DE10207443A1 (en) 2002-02-22 2003-09-04 Bayer Ag Process and catalyst for the production of alcohols
DE10225927A1 (en) 2002-06-11 2003-12-24 Basf Ag Process for the production of butanediol by combined gas phase and liquid phase synthesis
DE10225926A1 (en) 2002-06-11 2003-12-24 Basf Ag Process for the production of butanediol
JP5013879B2 (en) 2004-01-29 2012-08-29 ズィーケム インコーポレイテッド Organic acid recovery
EP2821494B1 (en) 2007-03-16 2017-03-08 Genomatica, Inc. Compositions and methods for the biosynthesis of 1,4-butanediol and its precursors
US7947483B2 (en) 2007-08-10 2011-05-24 Genomatica, Inc. Methods and organisms for the growth-coupled production of 1,4-butanediol
GB0719251D0 (en) 2007-10-03 2007-11-14 Davy Process Techn Ltd Process
US7803589B2 (en) 2008-01-22 2010-09-28 Genomatica, Inc. Methods and organisms for utilizing synthesis gas or other gaseous carbon sources and methanol
MX2010008587A (en) 2008-02-07 2010-09-28 Zeachem Inc Indirect production of butanol and hexanol.
CA3081506A1 (en) 2008-03-05 2009-09-11 Genomatica, Inc. Long chain alcohol-producing organisms
JP2011519561A (en) 2008-05-01 2011-07-14 ジェノマティカ， インコーポレイテッド Microorganisms for the production of methacrylic acid
BRPI0908303A2 (en) 2008-05-07 2015-08-18 Zeachem Inc Organic Acid Recovery
WO2010030711A2 (en) 2008-09-10 2010-03-18 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol
CA2745633A1 (en) 2008-12-02 2010-06-10 The Texas A&M University System Alternative paths to alcohols and hydrocarbons from biomass
GB0906031D0 (en) 2009-04-07 2009-05-20 Davy Process Techn Ltd Process
US8993285B2 (en) 2009-04-30 2015-03-31 Genomatica, Inc. Organisms for the production of isopropanol, n-butanol, and isobutanol
EP3686272A1 (en) 2009-04-30 2020-07-29 Genomatica, Inc. Organisms for the production of 1,3-butanediol
EP3392340B1 (en) 2009-06-04 2022-01-05 Genomatica, Inc. Microorganisms for the production of 1,4-butanediol and related methods
DK2462221T3 (en) 2009-08-05 2017-05-22 Genomatica Inc SEMISYNTHETIC TEREPHTHALIC ACID BY MICRO-ORGANISMS PRODUCING MUCONIC ACID
EE200900073A (en) 2009-09-22 2011-06-15 Nordbiochem O� Catalyst and Method for the Catalytic Hydrogenation of Carboxylic Acid Esters to Gl Schools
EP2491125A4 (en) 2009-10-23 2014-04-23 Genomatica Inc Microorganisms for the production of aniline
US8530210B2 (en) 2009-11-25 2013-09-10 Genomatica, Inc. Microorganisms and methods for the coproduction 1,4-butanediol and gamma-butyrolactone
KR20120123742A (en) 2010-01-29 2012-11-09 게노마티카 인코포레이티드 Microorganisms and methods for the biosynthesis of p-toluate and terephthalate
EP2357037A1 (en) 2010-02-17 2011-08-17 LANXESS Deutschland GmbH Method for producing mechanically stable shaped catalysts
US9023636B2 (en) 2010-04-30 2015-05-05 Genomatica, Inc. Microorganisms and methods for the biosynthesis of propylene
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8859827B2 (en) 2011-11-18 2014-10-14 Celanese International Corporation Esterifying acetic acid to produce ester feed for hydrogenolysis
US8846988B2 (en) 2010-07-09 2014-09-30 Celanese International Corporation Liquid esterification for the production of alcohols
US8901358B2 (en) 2010-07-09 2014-12-02 Celanese International Corporation Esterification of vapor crude product in the production of alcohols
US9150474B2 (en) 2010-07-09 2015-10-06 Celanese International Corporation Reduction of acid within column through esterification during the production of alcohols
US8846986B2 (en) 2011-04-26 2014-09-30 Celanese International Corporation Water separation from crude alcohol product
EP3312284A3 (en) 2010-07-26 2018-05-30 Genomatica, Inc. Microorganisms and methods for the biosynthesis of aromatics, 2,4-pentadienoate and 1,3-butadiene
US9000233B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Process to recover alcohol with secondary reactors for hydrolysis of acetal
US8907141B2 (en) 2011-04-26 2014-12-09 Celanese International Corporation Process to recover alcohol with secondary reactors for esterification of acid
TW201302684A (en) 2011-04-26 2013-01-16 Celanese Int Corp Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
GB201119871D0 (en) 2011-11-17 2011-12-28 Davy Process Techn Ltd Process
US8853468B2 (en) 2011-11-18 2014-10-07 Celanese International Corporation Vapor esterification method to produce ester feed for hydrogenolysis
US9024089B2 (en) 2011-11-18 2015-05-05 Celanese International Corporation Esterification process using extractive separation to produce feed for hydrogenolysis
EP2782890A1 (en) 2011-11-22 2014-10-01 Celanese International Corporation Esterifying an ethanol and acetic acid mixture to produce an ester feed for hydrogenolysis
WO2013076747A1 (en) 2011-11-25 2013-05-30 Conser Spa Process for producing 1,4- butanediol by hydrogenating dialkyl maleate in mixed liquid/vapor phase
US8697802B2 (en) 2011-11-28 2014-04-15 Celanese International Corporation Process for producing polyvinyl alcohol or a copolymer thereof
US9029614B2 (en) 2011-12-14 2015-05-12 Celanese International Corporation Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol
US9051235B2 (en) 2012-02-07 2015-06-09 Celanese International Corporation Process for producing ethanol using a molar excess of hydrogen
US8975452B2 (en) 2012-03-28 2015-03-10 Celanese International Corporation Process for producing ethanol by hydrocarbon oxidation and hydrogenation or hydration
US11932845B2 (en) 2012-06-04 2024-03-19 Genomatica, Inc. Microorganisms and methods for production of 4-hydroxybutyrate, 1,4-butanediol and related compounds
CN102766021B (en) * 2012-07-24 2014-04-09 唐山市冀东溶剂有限公司 Production system and production method for continuously producing ethanol by ethyl acetate through using hydrogenation
CN104755449B (en) 2012-08-31 2016-09-21 罗门哈斯公司 The method being prepared alcohol by organic acid
US8853469B2 (en) 2012-11-20 2014-10-07 Celanese International Corporation Combined column for separating products of different hydrogenation reactors
CN104822643B (en) 2012-12-20 2018-06-15 阿彻丹尼尔斯米德兰德公司 Hydrogenated products from biologically-derived carboxylate
CN104854222B (en) * 2012-12-20 2018-04-10 阿彻丹尼尔斯米德兰德公司 Bio-fuel is produced from biologically-derived carboxylate
US8975451B2 (en) 2013-03-15 2015-03-10 Celanese International Corporation Single phase ester feed for hydrogenolysis
WO2014176514A2 (en) 2013-04-26 2014-10-30 Genomatica, Inc. Microorganisms and methods for production of 4-hydroxybutyrate, 1,4-butanediol and related compounds
US20180222831A1 (en) * 2015-08-05 2018-08-09 White Dog Labs, Inc. Method for the production of at least one derivate of a carboxylic acid
GB201617698D0 (en) 2016-10-19 2016-11-30 Johnson Matthey Davy Technologies Limited Process
US10544077B2 (en) 2017-08-02 2020-01-28 Eastman Chemical Company Process for making formic acid utilizing higher-boiling formate esters
US10266466B2 (en) 2017-08-02 2019-04-23 Eastman Chemical Company Iron-catalyzed transfer hydrogenation of esters to alcohols
US10435349B2 (en) 2017-08-02 2019-10-08 Eastman Chemical Company Iron-catalyzed cross-coupling of methanol with secondary or tertiary alcohols to produce formate esters
US10570081B2 (en) 2017-08-02 2020-02-25 Eastman Chemical Company Process for making formic acid utilizing lower-boiling formate esters
US10266467B2 (en) 2017-08-02 2019-04-23 Eastman Chemical Company Synthesis of glycols via transfer hydrogenation of alpha-functional esters with alcohols
WO2022190141A1 (en) 2021-03-12 2022-09-15 Conser S.P.A. Process for the co-production of dialkyl succinate and 1,4-butanediol by hydrogenating dialkyl maleate in two stages.
CN113713829A (en) * 2021-10-09 2021-11-30 凯瑞环保科技股份有限公司 Preparation method of sec-butyl acetate hydrogenation catalyst

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2248465A (en) * 1936-12-19 1941-07-08 American Hyalsol Corp Process for the reduction of fatty acids to alcohols
US2285448A (en) * 1937-10-30 1942-06-09 Du Pont Preparation of polyhydric alcohols
DE1005497B (en) * 1954-03-19 1957-04-04 Dehydag Gmbh Process for the production of alcohols
BE548808A (en) * 1955-07-08 1900-01-01
GB932991A (en) * 1959-02-02 1963-07-31 Asahi Denka Kogyo Kk Method for producing a copper containing catalyst
FR1303231A (en) * 1961-09-01 1962-09-07 Hydrierwerk Rodleben Veb Process for preparing alcohols
NL282632A (en) * 1961-09-02 1900-01-01
NL292315A (en) * 1962-05-05
AT257556B (en) * 1962-11-16 1967-10-10 Celanese Corp Process for the production of alcohols
DE1768313B2 (en) * 1968-04-27 1977-05-18 Henkel & Cie GmbH, 4000 Düsseldorf PROCESS FOR MANUFACTURING HIGHERMOLECULAR VALUE-VALUE ALCOHOLS
DE2455617C3 (en) * 1974-11-23 1982-03-18 Basf Ag, 6700 Ludwigshafen Process for the production of butanediol and / or tetrahydrofuran via the intermediate stage of γ-butyrolactone
DE2613226B2 (en) * 1976-03-27 1978-12-14 Henkel Kgaa, 4000 Duesseldorf Process for the continuous production of fatty alcohols
US4112245A (en) * 1976-08-18 1978-09-05 Atlantic Richfield Company Process for the preparation of ethylene glycol
BE864567A (en) * 1977-04-25 1978-07-03 Chevron Res PROCESS FOR HYDROGENATION OF ESTERS INTO ACOOLS
US4199479A (en) * 1978-02-24 1980-04-22 Chevron Research Company Hydrogenation catalyst

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9212114B2 (en) 2012-10-09 2015-12-15 Johnson Matthey Davy Technologies Limited Process for the production of a fatty alcohol from a fatty acid
EP3010876B1 (en) 2013-06-19 2018-08-08 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for producing fatty alcohols from fatty acid methyl ester

Also Published As

Publication number Publication date
SE452154B (en) 1987-11-16
SE8303027L (en) 1983-05-30
MX156577A (en) 1988-09-13
JPH0457655B2 (en) 1992-09-14
AU560590B2 (en) 1987-04-09
GB2116552A (en) 1983-09-28
NO824396L (en) 1982-12-28
NZ200442A (en) 1985-10-11
JPS58500993A (en) 1983-06-23
BR8207962A (en) 1983-10-04
GB8306413D0 (en) 1983-04-13
FI831848A0 (en) 1983-05-24
AU8336582A (en) 1982-12-07
WO1982003854A1 (en) 1982-11-11
IT8220820A0 (en) 1982-04-20
NL8220121A (en) 1983-07-01
SE8303027D0 (en) 1983-05-30
FI831848L (en) 1983-05-24
CA1229096A (en) 1987-11-10
NL191438B (en) 1995-03-01
NL191438C (en) 1995-07-04
IT1190783B (en) 1988-02-24

Similar Documents

Publication Publication Date Title
GB2116552B (en) Process for hydrogenolysis of carboxylic acid esters
GB2016461B (en) Method for production of an ester and its recovery from the reaction mixture
JPS57123143A (en) Production of glycolic ester
GB2015514A (en) Process for recovery of ethylene oxide containing low levels of aldehydic impurities
JPS5615220A (en) Production of high-purity isobutylene
ZA829007B (en) Process for the removal of acid gases from gas mixtures
DE3271576D1 (en) Process for esterifying fluorinated carboxylic acid polymer
DE3365327D1 (en) Method for the preparation of alcohols and aldehydes by reacting olefins with carbon monoxide and hydrogen
CA2024713A1 (en) Continuous synthesis of mercaptocarboxylic acid esters
YU159282A (en) Process for the cryogenic fractional elimination of acid gases from a gaseous mixture
ES8300671A1 (en) Vapor state formation of diesters of oxalic acid
ZA822718B (en) Process for hydrogenolysis of carboxylic acid esters
ES8306696A1 (en) Sorbic acid process.
JPS5626861A (en) Manufacture of methyleneebissphenylcarbamic ester and polymethyleneepolyphenylcarbamic ester
JPS5770836A (en) Preparation of cinnamic acid ester
EP0150106A3 (en) Process for the production of 1-alkoxyalkyl esters
JPS5488230A (en) 4-alkoxy-3,5-diamino-alpha,alpha,alpha-trifluoromethylbenzene,its preparation, and hardeners for polyurethane elastomers consisting of it
JPS51125252A (en) Process for preparing substituted cyclopropanecarboxylic acid esters
JPS52111508A (en) Preparation of magnesium alkoxides
JPS527915A (en) Process for preparation of higher fatty acid
JPS5371010A (en) Purification of adipic acid ester
JPS53103437A (en) Continuous feed of slurry
JPS5721339A (en) Esterification of organic carboxylic acid
JPS5334729A (en) Preparation of alpha-siloxy-alpha-cyanocarboxylic acid esters
JPS5227089A (en) Catalyst for production of carboxylic acid ester

Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19960421