GB2101592B - Production of carboxylic esters from acyl halides formed by carbonylation - Google Patents

Production of carboxylic esters from acyl halides formed by carbonylation

Info

Publication number
GB2101592B
GB2101592B GB08216303A GB8216303A GB2101592B GB 2101592 B GB2101592 B GB 2101592B GB 08216303 A GB08216303 A GB 08216303A GB 8216303 A GB8216303 A GB 8216303A GB 2101592 B GB2101592 B GB 2101592B
Authority
GB
United Kingdom
Prior art keywords
carbonylation
production
carboxylic esters
acyl halides
halides formed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB08216303A
Other languages
English (en)
Other versions
GB2101592A (en
Inventor
Richard V Norton
Ralph F Pascoe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ashland LLC
Original Assignee
Ashland Oil Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ashland Oil Inc filed Critical Ashland Oil Inc
Publication of GB2101592A publication Critical patent/GB2101592A/en
Application granted granted Critical
Publication of GB2101592B publication Critical patent/GB2101592B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/363—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/58—Preparation of carboxylic acid halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/38—Acyl halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/10—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
GB08216303A 1981-07-10 1982-06-04 Production of carboxylic esters from acyl halides formed by carbonylation Expired GB2101592B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US28212281A 1981-07-10 1981-07-10

Publications (2)

Publication Number Publication Date
GB2101592A GB2101592A (en) 1983-01-19
GB2101592B true GB2101592B (en) 1985-10-30

Family

ID=23080195

Family Applications (1)

Application Number Title Priority Date Filing Date
GB08216303A Expired GB2101592B (en) 1981-07-10 1982-06-04 Production of carboxylic esters from acyl halides formed by carbonylation

Country Status (12)

Country Link
JP (1) JPS5810538A (ko)
KR (1) KR850001915B1 (ko)
AT (1) AT390056B (ko)
AU (1) AU535364B2 (ko)
BE (1) BE893416A (ko)
CA (1) CA1156256A (ko)
CH (2) CH657845A5 (ko)
DE (2) DE3249675C2 (ko)
FR (1) FR2509293B1 (ko)
GB (1) GB2101592B (ko)
IT (1) IT1195929B (ko)
NL (1) NL187015C (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6135980U (ja) * 1984-07-31 1986-03-05 東陶機器株式会社 便器洗浄用排水弁

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE972291C (de) * 1954-05-16 1959-07-02 Studiengesellschaft Kohle Mbh Verfahren zur Herstellung von Monocarbonsaeuren aus Olefinen, Kohlenoxyd und Wasser
DE973077C (de) * 1954-07-30 1959-11-26 Studiengesellschaft Kohle Mbh Verfahren zur Herstellung von Carbonsaeuren aus Olefinen und Kohlenoxyd
DE1064941B (de) * 1957-04-24 1959-09-10 Studiengesellschaft Kohle Mbh Verfahren zur Herstellung von Gemischen aus gesaettigten aliphatischen oder cycloaliphatischen Monocarbonsaeurealkylestern
US3167585A (en) * 1960-08-25 1965-01-26 Gulf Research Development Co Process for carboxylation of iso-olefins
GB942367A (en) * 1961-04-29 1963-11-20 Basf Ag Continuous production of carboxylic acids from olefines, carbon monoxide and water
NL6816940A (ko) * 1967-11-28 1969-05-30
BE755997A (fr) * 1969-09-11 1971-03-10 Bp Chem Int Ltd Production d'acides dicarboxyliques
IT995328B (it) * 1973-08-13 1975-11-10 Montedison Spa Procedimento per la preparazione di acidi alfa beta insaturi per ossidazione catalitica in fase gassosa di corrispondenti acidi saturi
US4224232A (en) * 1978-12-21 1980-09-23 Gulf Research & Development Company Production of carboxylic acids from olefins and mixtures of olefins
DE3067475D1 (en) * 1979-12-20 1984-05-17 Roehm Gmbh Process for the production of isobutyric acid or its lower alkyl esters

Also Published As

Publication number Publication date
AU535364B2 (en) 1984-03-15
CA1156256A (en) 1983-11-01
DE3249675A1 (ko) 1985-04-18
FR2509293B1 (fr) 1987-02-27
NL187015C (nl) 1991-05-01
FR2509293A1 (fr) 1983-01-14
DE3221175A1 (de) 1983-01-27
ATA220382A (de) 1989-08-15
NL8202271A (nl) 1983-02-01
DE3221175C2 (de) 1985-08-29
AU8460782A (en) 1983-03-24
GB2101592A (en) 1983-01-19
DE3249675C2 (ko) 1987-01-08
IT1195929B (it) 1988-11-03
CH656872A5 (de) 1986-07-31
KR850001915B1 (ko) 1985-12-31
AT390056B (de) 1990-03-12
BE893416A (fr) 1982-10-01
CH657845A5 (de) 1986-09-30
JPS5810538A (ja) 1983-01-21
JPS6227055B2 (ko) 1987-06-12
KR840000469A (ko) 1984-02-22
IT8221705A0 (it) 1982-06-04

Similar Documents

Publication Publication Date Title
DE3264875D1 (en) Process for producing carboxylic acids
GB2146637B (en) Producing carboxylic acids by carbonylation
GB2092134B (en) Process for the production of carboxylic acid esters
DE3479214D1 (en) Process for the production of l-aspartyl-l-phenylalanine methyl ester or l-aspartyl-l-phenylalanine
DE3464361D1 (en) Production of carboxylic acids from alcohols
DE3572195D1 (en) Process for the production of cyclopropane carboxylic acids
DE3263388D1 (en) Process for the co-production of carboxylic acids and carboxylic acid esters
DE3464238D1 (en) Production of carboxylic acids from alcohols
DE3264945D1 (en) Process for the co-production of carboxylic acids and carboxylic acid esters
JPS57200330A (en) Manufacture of carboxylic acid ester
DE3263021D1 (en) Process for the production of isobutyric acid or its alkyl esters
GB2101592B (en) Production of carboxylic esters from acyl halides formed by carbonylation
GB2099821B (en) Production of carboxylic acids from acyl fluorides formed by carbonylation
JPS57193469A (en) Manufacture of carboxylic acid ester of anhydrohexit
GB2100729B (en) Production of acyl fluorides by carbonylation
JPS56166163A (en) Manufacture of cyclopropane carboxylic acid ester derivative
JPS5714558A (en) Synthesis process of gamma-unsaturated carboxylic acid ester
DE3267033D1 (en) Process for the co-production of carboxylic acids and carboxylic acid esters
GB2101591B (en) Production of acyl halides and carboxylic acids and esters therefrom
ZA822718B (en) Process for hydrogenolysis of carboxylic acid esters
DE3267030D1 (en) Process for the co-production of carboxylic acids and carboxylic acid esters
JPS56166164A (en) Manufacture of cyclopropane carboxylic acid ester derivative
DE3468016D1 (en) Production of carboxylic acids
HU182380B (en) Process for producing esters of vincaminic acid
DE3462786D1 (en) Production of carboxylic acids from organic formate esters

Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19940604