GB2026019A - Utilising refuse - Google Patents

Utilising refuse Download PDF

Info

Publication number
GB2026019A
GB2026019A GB7916300A GB7916300A GB2026019A GB 2026019 A GB2026019 A GB 2026019A GB 7916300 A GB7916300 A GB 7916300A GB 7916300 A GB7916300 A GB 7916300A GB 2026019 A GB2026019 A GB 2026019A
Authority
GB
United Kingdom
Prior art keywords
refuse
fraction
paper
pyrolysis
fibrous material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7916300A
Other versions
GB2026019B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BKMI Industrieanlagen GmbH
Original Assignee
Babcock Krauss Maffei Industrieanlagen GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Babcock Krauss Maffei Industrieanlagen GmbH filed Critical Babcock Krauss Maffei Industrieanlagen GmbH
Publication of GB2026019A publication Critical patent/GB2026019A/en
Application granted granted Critical
Publication of GB2026019B publication Critical patent/GB2026019B/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • B03B9/06General arrangement of separating plant, e.g. flow sheets specially adapted for refuse
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • B03B9/06General arrangement of separating plant, e.g. flow sheets specially adapted for refuse
    • B03B9/061General arrangement of separating plant, e.g. flow sheets specially adapted for refuse the refuse being industrial
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/02Pretreatment of the raw materials by chemical or physical means
    • D21B1/026Separating fibrous materials from waste
    • D21B1/028Separating fibrous materials from waste by dry methods
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)
  • Processing Of Solid Wastes (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

A process for utilising refuse comprises first separating the refuse into at least one paper fraction (which is further processed for producing fibrous material) and a residual fraction, the slops (e.g. plastics films, textiles) accumulating during the production of fibrous material from the paper fraction being subjected to pyrolysis together with the residual fraction and the heat obtained is used in the production of the fibrous material.

Description

SPECIFICATION A process for utilising refuse This invention relates to a process for utilising refuse in which the refuse is initially separated into at least one paper fraction and a residual fraction, the paper fraction is subjected to further processing for making paper and the residual fraction is utilised for its energy content.
It is known that the paper fraction obtained in the sorting of refuse may be used as old paper in the manufacture of paper. On account of the high foreign matter content, difficulties are involved in processing the waste paper obtained by sorting refuse because the sorting installations of the conventionally equipped waste paper industry are not designed for separating the high foreign matter content. For this reason, the waste paper obtained from the sorting of refuse is only used to a certain extent together with standard commercial-grade old paper in the manufacture of paper.
In a further processing of the waste paper obtained in the sorting of refuse for paper making purposes, the undesirable foreign constituents (such as plastics films, textiles, etc.) are separated out in the form of so-called "slops" which it wouid be extremely desirable to utilise in view of their considerable energy content, but which cannot be incinerated together with domestic refuse on account of the possible formation of local heat spots and the excessive pollutant concentration formed during incineration. Accordingly, they are dumped as special refuse without their energy content being utilised. The special refuse character of the slops and the considerable quantities in which they accumulate impose an undesirable financial burden on the production of fibrous material from waste paper.
The object of the present invention is to obviate the disadvantages referred to above and to provide a process for utilising refuse which is distinguished by considerably reduced outlay on plant and energy for further processing the paper fraction obtained in the sorting of refuse for papermaking purposes.
According to the invention, this object is achieved in that the slops accumulating during the production of fibrous material from the paper fraction are subjected to pyrolysis together with the residual fraction from the sorting of refuse and the thermal energy obtained is used for producing the fibrous material.
According to the invention, therefore, the utilisation of refuse for its energy content and the further processing of the paper fraction obtained from the refuse for paper-making purposes are combined into a composite process which provides for a considerable saving of energy, for a considerable simplification of the process itself and of the installation required for carrying it out and for a particularly high-quality starting product for the manufacture of paper.
In the process according to the invention, the paper fraction obtained in the sorting of refuse is directly further processed into a fibrous starting material in a paper factory equipped for separating off the increased foreign matter content (in contrast to conventional processes, therefore, it is not processed into paper or board which would require a further fine purification stage). This simplifies further processing for papermaking purposes and enables the fibrous raw material to be used in any conventionally equipped wastepaper-processing paper factory. The direct further processing of the waste paper in the vicinity of the refuse sorting plant promotes the use of the energy obtained during utilisation of the refuse for the production of raw fibrous material, as will be explained in the following.
According to the invention, the residual fraction from the sorting of refuse and also the slops accumulating during the production of fibrous material from the paper fraction are together subjected to pyrolysis. The use of pyrolysis for utilising the energy of these waste materials affords the considerable advantage that, due to the absence of air or oxygen, no uncontrolled heat spots can be formed during pyrolysis of the slops and the pollutant gases given off during pyrolysis can be purified effectively and inexpensively by virtue of the low gas volume which only amounts to between 1 5 and 20% by comparison with the quantities of smoke gas given off during the incineration of refuse.Accordingly, it is also possible by pyrolysis to recover the considerable energy content of the slops accumulating during production of the fibrous material which, hitherto, it has been difficult to utilise. The common utilisation of the residual fraction obtained in the sorting of refuse and of the slops accumulating during production of the fibrous material for their thermal energy enables the installation required for pyrolysis to be provided with particularly economic dimensions.
By virtue of the fact that the thermal energy obtained during pyrolysis of the residual fraction from the sorting of refuse and the slops accumulating during production of the fibrous material is used for production of the fibrous material (a highly endothermic process), it is possible to obtain a largely compensated energy balance of the entire composite system.
However, it is of course also possible completely or partly to separate other useful constituents, such as plastic films and glass, in addition to the metal fraction and the paper fraction during sorting of the refuse. The extent to which use is made of this possibility will be determined by the proceeds obtained from the sale of these materials. If these proceeds do not cover the cost of the heat extracted therefrom, it is best not to separate these constituents.
In the process according to the invention, pyrolysis is best carried out in a revolving tubular furnace in which the slops and the residual fraction from the sorting of refuse are subjected to low-temperature carbonisation in the substantial absence of air. Pyrolysis with continuous circulation of the material to be subjected to low-temperature carbonisation has the advantage, particularly for the waste materials in question here (residual fraction from the sorting of refuse and the slops accumulating during production of the fibrous material), that the material undergoing low temperature carbonisation in the revolving tubular furnace is continuously loosened and gradually decomposed.Where pyrolysis is carried out in a shaft furnace, where the waste materials slide through a shaft without any internal movement, the slops above all have to be intensively size-reduced beforehand and thoroughly mixed with the remaining waste materials to ensure complete low-temperature carbonisation of the slops.
The low-temperature carbonisation gases produced during pyrolysis are best subjected to a high-temperature treatment at 1000 to 1 250 C in order to crack the long-chain organic constituents present in them. The lowtemperature carbonisation gases thus treated may either be directly used as a heat source for production of the fibrous material or may be completely or partly used for generating current (in which case the electrical energy obtained may be completely or partly used for production of the fibrous material).
According to the invention, not only the residual fraction obtained during sorting of the refuse and the slops accumulating during production of the fibrous material, but also other waste materials, for example special waste materials, such as old oils, plastics, tyres, tank residues, etc., and also refuse of low paper content which is not worth sorting, may be subjected to pyrolysis.
During sorting of the refuse, it is possible to separate several paper fractions of which the fractions having a relatively large long-fibre content, such as for example cards, boards, etc., may be used for producing the fibrous material whilst the fractions having a relatively large short-fibre content, such as for example newspapers, magazines etc., may be subjected to pyrolysis together with the residual fraction.
It has proved to be favourable to sort the refuse under dry conditions where the light components of the refuse, such as paper, cardboard, films and textiles, are separated from the heavier components by an airstream.
In the context of the invention, the expression "paper" or "paper fraction" is of course also understood to include cardboard.
The composite process according to the invention, which is distinguished by its high economy and flexibility, is described in detail in the following with reference to a material balance (Fig. 1) and an energy balance (Fig.
2). It is obvious that the figures quoted in the material and energy balance are purely exemplary.
According to Fig. 1, 27.5 t/h of refuse are delivered to a sorting installation. This sorting installation yields a metal fraction of 1.5 t/h, a paper fraction of 9 t/h and a residual fraction of 1 7 t/h. The production of fibrous material gives 5.8 t/h of fibrous raw material and 3.2 t/h of slops.
Accordingly, 20.2 t/h of slops are subjected to pyrolysis. The low-temperature carbonisation gas given off during pyrolysis is either directly used (together with any waste gas accumulating) as a heat source for the production of fibrous material or is used for generating electrical energy which in turn may be used for production of the fibrous material.
In addition, the pyrolysis plant yields 6.8 t/h of low-temperature coke from which it is possible to separate non-ferrous metals, glass and carbon for the production of active carbon.
The energy balance shown in Fig. 2 is based on 1 kg of domestic refuse having a heat content of 1 900 kcal. Of this 1 900 kcal, the purified raw fibrous material contains 896 kcal, the slops accumulating during production of the fibrous material 335 kcal and the residual fraction 669 kcal. Accordingly, 1004 kcal are delivered to the pyrolysis furnace (disregarding the possibility of separating plastics films having an energy content of 235 kcal from the slops).
From pyrolysis 442 kcal are given off for production of the fibrous material. The losses and energy content of the solids accumulating during pyrolysis amount to 562 kcal. The heat recovered in the pyrolysis process amounts to 228 kcal.

Claims (9)

1. A process for utilising refuse in which the refuse is first separated into at least one paper fraction and a residual fraction, the paper fraction is furtherprocessed for papermaking purposes and the residual fraction is utilised for its energy content, characterised in that the slops accumulating during the production of fibrous material from the paper fraction are subjected to pyrolysis together with the residual fraction from sorting of the refuse and the thermal energy obtained in this way is used for production of the fibrous material.
2. A process as claimed in Claim 1, characterised in that pyrolysis is carried out in a revolving tubular furnace in which the slops and the residual fraction from sorting of the refuse are subjected to low-temperature carbonisation in the substantial absence of air.
3. A process as claimed in Claim 1, characterised in that, after cracking of the longchain organic constituents present in them, the low-temperature carbonisation gases produced during pyrolysis are directly used for covering the heat demand for production of the fibrous material.
4. A process as claimed in Claim 1, characterised in that at least part of the lowtemperature carbonisation gases produced during pyrolysis is used for generating current after cracking of the long-chain organic constituents present in them.
5. A process as claimed in Claim 1, characterised in that the refuse is sorted into at least one paper fraction, a metal fraction and a residual fraction.
6. A process as claimed in Claim 5, characterised in that, in addition to the metal fraction and the paper fraction, other useful constituents, such as plastics films and glass, are completely or partly separated from the refuse.
7. A process as claimed in Claim 1, characterised in that, in addition to the residual fraction obtained during sorting of the refuse and the slops accumulating during production of the fibrous material, other refuse, particularly special refuse, and unsorted refuse of low paper content are subjected to pyrolysis.
8. A process as claimed in Claim 1, characterised in that several paper fractions are separated during sorting of the refuse, of which the fractions having a relatively large long-fibre content are used for production of the fibrous material whilst the fractions having a relatively large short-fibre content are subjected to pyrolysis together with the residual fraction.
9. A process as claimed in Claim 1, characterised by sorting of the refuse under dry conditions where the light components of the refuse, such as paper, cardboard, films and textiles, are separated from the heavier components by an air stream.
GB7916300A 1978-05-30 1979-05-10 Utilising refuse Expired GB2026019B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2823505A DE2823505C2 (en) 1978-05-30 1978-05-30 Process for recycling waste

Publications (2)

Publication Number Publication Date
GB2026019A true GB2026019A (en) 1980-01-30
GB2026019B GB2026019B (en) 1982-07-07

Family

ID=6040513

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7916300A Expired GB2026019B (en) 1978-05-30 1979-05-10 Utilising refuse

Country Status (7)

Country Link
JP (2) JPS54158759A (en)
DE (1) DE2823505C2 (en)
DK (1) DK220579A (en)
ES (1) ES480702A1 (en)
GB (1) GB2026019B (en)
IT (1) IT1124094B (en)
SE (1) SE7904634L (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000035588A1 (en) * 1998-12-17 2000-06-22 Metso Paper, Inc. Method and production plant for the manufacture of fibrous material
WO2001089730A2 (en) * 2000-05-22 2001-11-29 Metso Paper, Inc. Method for processing waste and waste processing plant
US6988682B2 (en) 2000-05-22 2006-01-24 Metso Paper, Inc. Method and system for utilizing waste
US8034271B2 (en) 2006-03-25 2011-10-11 Building Research Establishment Ltd. Process for making composite products from fibrous waste material

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19627528C2 (en) * 1996-07-09 1999-02-11 Radwan Dr Rer Nat Matrmawi Process for processing rejects and use of the product produced by the process

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7205607A (en) * 1971-04-26 1972-10-30
US3736111A (en) * 1971-05-17 1973-05-29 Hercules Inc Process and apparatus for the complete reclamation of valuable products from solid waste
DE2227924A1 (en) * 1972-06-08 1973-12-20 Otto Bauer Metal recovery from scrap - esp copper from insulated wire
CH545661A (en) * 1972-06-12 1974-02-15
DE2639165A1 (en) * 1976-08-31 1978-03-02 Patra Patent Treuhand Agricultural waste converted into mechanical energy - by disintegrating and fluidising waste, gasifying and supplying gas with air admixture to IC engine

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000035588A1 (en) * 1998-12-17 2000-06-22 Metso Paper, Inc. Method and production plant for the manufacture of fibrous material
AU760530B2 (en) * 1998-12-17 2003-05-15 Metso Paper Inc. Method and production plant for the manufacture of fibrous material
WO2001089730A2 (en) * 2000-05-22 2001-11-29 Metso Paper, Inc. Method for processing waste and waste processing plant
WO2001089730A3 (en) * 2000-05-22 2002-03-14 Metso Paper Inc Method for processing waste and waste processing plant
AU2001262381B2 (en) * 2000-05-22 2004-06-24 Metso Paper, Inc. Method for processing waste and waste processing plant
US6988682B2 (en) 2000-05-22 2006-01-24 Metso Paper, Inc. Method and system for utilizing waste
US8034271B2 (en) 2006-03-25 2011-10-11 Building Research Establishment Ltd. Process for making composite products from fibrous waste material

Also Published As

Publication number Publication date
SE7904634L (en) 1979-12-01
JPS54158759A (en) 1979-12-14
ES480702A1 (en) 1979-11-16
GB2026019B (en) 1982-07-07
DE2823505C2 (en) 1983-11-24
IT1124094B (en) 1986-05-07
DE2823505A1 (en) 1979-12-06
IT7912621A0 (en) 1979-05-29
JPS5755547U (en) 1982-04-01
DK220579A (en) 1979-12-01

Similar Documents

Publication Publication Date Title
AU593017B2 (en) Process for recovering gas byproducts from refuse
US4153514A (en) Pyrolysis process for solid wastes
EP0423606B1 (en) Process for the preparation of domestic, industrial or similar waste for the extraction of cellulose materials
US4260473A (en) Removal of particulates from pyrolytic oil
US5795479A (en) Apparatus and method for waste recycling and conversion
US4618735A (en) Process and apparatus for the conversion of sludges
US3714038A (en) Process and product for converting organic materials by pyrolysis or hydrogenation
EP0588814B1 (en) Treatment of automobile shredder residue by vacuum pyrolysis
JP5800313B2 (en) Pyrolysis system and method for producing pyrolysis oil
US7419514B2 (en) Process for producing a liquid fuel composition
CA1091602A (en) Solvent recovery in a coal deashing process
DE102007034139A1 (en) Method for thermal treatment of wet wastes, production residues and other residual substances having native organic or synthetic organic constituents, involves shredding coarse particle material mixtures mechanically
JP2003534123A (en) Waste treatment method and waste treatment equipment
GB2026019A (en) Utilising refuse
USRE29312E (en) Gasification of carbonaceous solids
EP0678116B1 (en) Process for recovery of tank bottom wastes
CH552523A (en) PROCESS FOR THE PRODUCTION AND RECOVERY OF CHEMICALS AND FUELS FROM WASTE CONTAINING ORGANIC SOLIDS, IN PARTICULAR WASTE.
WO2001079123A1 (en) Method for conditioning biogenic solid substances
KR970001511A (en) Oiling apparatus and its method by complex pyrolysis of waste tire / waste oil
EP0682099A1 (en) Process and apparatus for treating composite packaging material and/or plastic wastes and use of the solid carbonaceous pyrolysis residue
EP0381254B1 (en) Process for obtaining synthesis gas either from solid fuels derived from urban solid waste, or from industrial solid waste
JPH10168462A (en) Method for effective utilization of secondary waste material of waste plastic
EP0661367B1 (en) Process for treating waste
SU827533A1 (en) Method of producing smokeless solid fuel coal (preferably from brown coal)
FI98638C (en) A method of producing diesel fuel from vehicle tires or similar waste rubber material

Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee