GB2014970A - Ultrahydrophobic zeolite Y - Google Patents

Ultrahydrophobic zeolite Y

Info

Publication number
GB2014970A
GB2014970A GB7906357A GB7906357A GB2014970A GB 2014970 A GB2014970 A GB 2014970A GB 7906357 A GB7906357 A GB 7906357A GB 7906357 A GB7906357 A GB 7906357A GB 2014970 A GB2014970 A GB 2014970A
Authority
GB
United Kingdom
Prior art keywords
zeolite
less
value
water
forms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7906357A
Other versions
GB2014970B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB2014970A publication Critical patent/GB2014970A/en
Application granted granted Critical
Publication of GB2014970B publication Critical patent/GB2014970B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Hydrothermally stable forms of zeolite Y which exhibit an unique degree of adsorptive preference for less polar organic molecules relative to strongly polar molecules such as water are prepared by rigourously steaming the low-sodium forms of zeolite Y. The zeolite has SiO2/Al2O3 ratio of 3.5 35, ion exchange capacity not greater than 0.070, unit cell dimension ao of less than 24.45 ANGSTROM , surface area of at least 350m<2>/g, sorptive capacity for water vapour at 25 DEG C and p/po value of 0.10 of less than 5% wt and a Residual Butanol test value of not more than 0.40% wt.
GB7906357A 1978-02-23 1979-02-22 Ultrahydrophobic zeolite gamma Expired GB2014970B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US88056178A 1978-02-23 1978-02-23

Publications (2)

Publication Number Publication Date
GB2014970A true GB2014970A (en) 1979-09-05
GB2014970B GB2014970B (en) 1982-06-09

Family

ID=25376556

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7906357A Expired GB2014970B (en) 1978-02-23 1979-02-22 Ultrahydrophobic zeolite gamma

Country Status (8)

Country Link
JP (1) JPS54122700A (en)
BE (1) BE874373A (en)
CA (1) CA1131195A (en)
DE (1) DE2906656C3 (en)
FR (1) FR2418198B1 (en)
GB (1) GB2014970B (en)
IT (1) IT1112018B (en)
NL (1) NL7901415A (en)

Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0028938A1 (en) * 1979-11-13 1981-05-20 Union Carbide Corporation Catalytic conversion of hydrocarbons
WO1984004913A1 (en) * 1983-06-09 1984-12-20 Zeol Ab Method for reducing the hydrocarbon content in air or water
US4762813A (en) * 1979-10-15 1988-08-09 Union Oil Company Of California Hydrocarbon conversion catalyst
US4767734A (en) * 1979-10-15 1988-08-30 Union Oil Company Of California Hydrocarbon conversion process and catalyst for selectively making middle distillates
US4857171A (en) * 1986-05-30 1989-08-15 Shell Oil Company Hydrocarbon conversion process and catalysts
US4857170A (en) * 1986-05-30 1989-08-15 Shell Oil Company Hydrocarbon conversion catalysts
US4869803A (en) * 1979-10-15 1989-09-26 Union Oil Company Of California Hydrocarbon conversion process for selectively making middle distillates
US4879019A (en) * 1979-10-15 1989-11-07 Union Oil Company Of California Hydrocarbon conversion process for selectively making middle distillates
US4960505A (en) * 1987-08-14 1990-10-02 Shell Oil Company Process for the hydrogenation of hydrocarbon oils
US4990476A (en) * 1979-10-15 1991-02-05 Union Oil Company Of California Hydrocarbon conversion catalyst for use in selectively making middle distillates
US5023221A (en) * 1990-05-31 1991-06-11 Union Oil Company Of California Middle distillate hydrocracking catalyst and process
US5059567A (en) * 1986-05-22 1991-10-22 Pq Zeolite B. V. Process for the preparation of a modified zeolite
US5076907A (en) * 1990-05-31 1991-12-31 Union Oil Company Of California Middle distillate hydrocracking process
US5116792A (en) * 1979-10-15 1992-05-26 Union Oil Company Of California Hydrocarbon conversion catalyst for use in selectively making middle distillates
US5288396A (en) * 1979-10-15 1994-02-22 Union Oil Company Of California Hydrocracking process using a catalyst selective for making middle distillates
US5350501A (en) * 1990-05-22 1994-09-27 Union Oil Company Of California Hydrocracking catalyst and process
US5371308A (en) * 1992-08-25 1994-12-06 Shell Oil Company Process for the preparation of lower olefins
US5374335A (en) * 1991-10-28 1994-12-20 Eka Nobel Ab Sized paper, process for producing same and use thereof
US5464527A (en) * 1992-05-22 1995-11-07 Uop Hydrocracking process for producing middle distillates
EP0703003A1 (en) 1994-08-24 1996-03-27 Shell Internationale Researchmaatschappij B.V. Hydrocarbon conversion catalysts
US5603997A (en) * 1991-10-28 1997-02-18 Nobel Ab Packaging material process for producing same and use thereof
US5676914A (en) * 1994-04-26 1997-10-14 Competitive Technologies, Inc. Method for the destruction of methylene iodide
CN1053429C (en) * 1996-10-15 2000-06-14 中国石油化工总公司 Super-hydrophobic Y zeolite and its preparing process
WO2000051940A1 (en) * 1999-03-03 2000-09-08 Pq Holding, Inc. Process for preparing a modified zeolite
WO2004044100A1 (en) 2002-11-08 2004-05-27 Chevron U.S.A. Inc. Extremely low acidity ultrastable y zeolite catalyst composition and process
US6902664B2 (en) 2002-11-08 2005-06-07 Chevron U.S.A. Inc. Extremely low acidity USY and homogeneous, amorphous silica-alumina hydrocracking catalyst and process
US7192900B2 (en) 2002-11-27 2007-03-20 Shell Oil Company Hydrocracking catalyst
EP2085360A1 (en) 2007-12-27 2009-08-05 Chevron USA, Inc. Synthesis of a crystalline silicoaluminophosphate
WO2010139997A2 (en) 2009-06-03 2010-12-09 University Of Manchester Modified zeolites and their use in the recycling of plastics waste
US8372368B2 (en) 2008-07-29 2013-02-12 Chevron U.S.A. Inc. Synthesis of a crystalline silicoaluminophosphate
RU2481268C2 (en) * 2011-08-05 2013-05-10 Открытое акционерное общество "Корпорация "Росхимзащита" (ОАО "Корпорация "Росхимзащита") Method of producing hydrophobic zeolite
CN115806299A (en) * 2022-11-09 2023-03-17 复榆(张家港)新材料科技有限公司 Multistage Kong Gaogui hydrophobic zeolite with FAU structure

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1141229A (en) * 1978-12-26 1983-02-15 Thomas P.J. Izod Removal of caffeine by selective adsorption using zeolite adsorbents
US4517074A (en) * 1979-10-15 1985-05-14 Union Oil Company Of California Hydrocarbon conversion process
US4419271A (en) * 1979-10-15 1983-12-06 Union Oil Company Of California Hydrocarbon conversion catalyst
US4743355A (en) * 1979-10-15 1988-05-10 Union Oil Company Of California Process for producing a high quality lube oil stock
US4517073A (en) * 1982-08-09 1985-05-14 Union Oil Company Of California Hydrocracking process and catalyst therefor
US4743354A (en) * 1979-10-15 1988-05-10 Union Oil Company Of California Process for producing a product hydrocarbon having a reduced content of normal paraffins
US4576711A (en) * 1979-10-15 1986-03-18 Union Oil Company Of California Hydrocracking process and catalyst therefor
US4632749A (en) * 1983-03-14 1986-12-30 Uop Inc. Fluid catalytic cracking hydrocarbon conversion process
US4652538A (en) * 1983-11-01 1987-03-24 Union Carbide Corporation Catalysts for conversion of syngas to liquid motor fuels
US4617320A (en) * 1984-06-27 1986-10-14 Union Carbide Corporation Enhanced conversion of syngas to liquid motor fuels
US4617283A (en) * 1984-06-27 1986-10-14 Union Carbide Corporation Catalyst for converting synthesis gas to liquid motor fuels
US4663355A (en) * 1984-06-27 1987-05-05 Union Carbide Corporation Catalyst and process for converting synthesis gas to liquid motor fuels
US4632941A (en) * 1984-06-27 1986-12-30 Union Carbide Corporation Enhanced catalyst and process for converting synthesis gas to liquid motor fuels
US4579830A (en) * 1984-06-27 1986-04-01 Union Carbide Corporation Enhanced catalyst for converting synthesis gas to liquid motor fuels
US4556645A (en) * 1984-06-27 1985-12-03 Union Carbide Corporation Enhanced catalyst for conversion of syngas to liquid motor fuels
US4740648A (en) * 1985-03-11 1988-04-26 Union Carbide Corporation Conversion of olefins to liquid motor fuels
WO1986005483A1 (en) * 1985-03-11 1986-09-25 Union Carbide Corporation Conversion of olefins to liquid motor fuels
EP0432132B1 (en) * 1988-03-28 1993-12-08 Tosoh Corporation A method for preparation of mono- and diisopropylnaphthalenes
JP2544317B2 (en) * 1990-06-29 1996-10-16 財団法人石油産業活性化センター Fluid catalytic cracking catalyst composition, method for producing the same, and fluid catalytic cracking method for hydrocarbon oil using the same
FR2735764B1 (en) * 1995-06-21 1997-08-22 Irma DESEALUMINATED ZEOLITE THEREOF, PROCESS FOR PRODUCING THE SAME AND APPLICATION THEREOF TO ADSORPTION OF VOLATILE ORGANIC COMPOUNDS IN THE PRESENCE OF WATER VAPOR

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6503410A (en) * 1963-02-21 1965-09-20
US3293192A (en) * 1965-08-23 1966-12-20 Grace W R & Co Zeolite z-14us and method of preparation thereof
US3354077A (en) * 1966-03-30 1967-11-21 Union Oil Co Stabilized zeolites and use thereof for hydrocarbon conversions
US3591488A (en) * 1969-06-11 1971-07-06 Exxon Research Engineering Co High silica crystalline zeolites and processes for their preparation
US3929672A (en) * 1971-10-20 1975-12-30 Union Oil Co Ammonia-stable Y zeolite compositions
GB1514522A (en) * 1974-07-25 1978-06-14 Basf Ag Manufacture of heat-resistant and acid-resistant zeolites from alkali metal faujasites
DE2510700C2 (en) * 1975-03-12 1983-01-27 Basf Ag, 6700 Ludwigshafen Process for the production of zeolites with improved resistance to high temperatures and acids
GB1506429A (en) * 1975-05-13 1978-04-05 Union Carbide Corp Catalyst for hydrocarbon processes and process for preparing same

Cited By (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4869803A (en) * 1979-10-15 1989-09-26 Union Oil Company Of California Hydrocarbon conversion process for selectively making middle distillates
US4762813A (en) * 1979-10-15 1988-08-09 Union Oil Company Of California Hydrocarbon conversion catalyst
US4767734A (en) * 1979-10-15 1988-08-30 Union Oil Company Of California Hydrocarbon conversion process and catalyst for selectively making middle distillates
US4879019A (en) * 1979-10-15 1989-11-07 Union Oil Company Of California Hydrocarbon conversion process for selectively making middle distillates
US5116792A (en) * 1979-10-15 1992-05-26 Union Oil Company Of California Hydrocarbon conversion catalyst for use in selectively making middle distillates
US5288396A (en) * 1979-10-15 1994-02-22 Union Oil Company Of California Hydrocracking process using a catalyst selective for making middle distillates
US5468700A (en) * 1979-10-15 1995-11-21 Uop Hydrocarbon conversion catalyst for use in selectively making middle distillates
US4990476A (en) * 1979-10-15 1991-02-05 Union Oil Company Of California Hydrocarbon conversion catalyst for use in selectively making middle distillates
EP0028938A1 (en) * 1979-11-13 1981-05-20 Union Carbide Corporation Catalytic conversion of hydrocarbons
WO1984004913A1 (en) * 1983-06-09 1984-12-20 Zeol Ab Method for reducing the hydrocarbon content in air or water
US5059567A (en) * 1986-05-22 1991-10-22 Pq Zeolite B. V. Process for the preparation of a modified zeolite
US4857171A (en) * 1986-05-30 1989-08-15 Shell Oil Company Hydrocarbon conversion process and catalysts
US4857170A (en) * 1986-05-30 1989-08-15 Shell Oil Company Hydrocarbon conversion catalysts
US4960505A (en) * 1987-08-14 1990-10-02 Shell Oil Company Process for the hydrogenation of hydrocarbon oils
US5447623A (en) * 1990-05-22 1995-09-05 Uop Hydrocracking catalyst and process
US5350501A (en) * 1990-05-22 1994-09-27 Union Oil Company Of California Hydrocracking catalyst and process
US5536687A (en) * 1990-05-22 1996-07-16 Uop Catalyst containing zeolite Beta
US5076907A (en) * 1990-05-31 1991-12-31 Union Oil Company Of California Middle distillate hydrocracking process
US5023221A (en) * 1990-05-31 1991-06-11 Union Oil Company Of California Middle distillate hydrocracking catalyst and process
US5374335A (en) * 1991-10-28 1994-12-20 Eka Nobel Ab Sized paper, process for producing same and use thereof
US5603997A (en) * 1991-10-28 1997-02-18 Nobel Ab Packaging material process for producing same and use thereof
US5464527A (en) * 1992-05-22 1995-11-07 Uop Hydrocracking process for producing middle distillates
US5371308A (en) * 1992-08-25 1994-12-06 Shell Oil Company Process for the preparation of lower olefins
US5676914A (en) * 1994-04-26 1997-10-14 Competitive Technologies, Inc. Method for the destruction of methylene iodide
EP0703003A1 (en) 1994-08-24 1996-03-27 Shell Internationale Researchmaatschappij B.V. Hydrocarbon conversion catalysts
US5954946A (en) * 1994-08-24 1999-09-21 Shell Oil Company Hydrocarbon conversion catalysts
CN1053429C (en) * 1996-10-15 2000-06-14 中国石油化工总公司 Super-hydrophobic Y zeolite and its preparing process
WO2000051940A1 (en) * 1999-03-03 2000-09-08 Pq Holding, Inc. Process for preparing a modified zeolite
US6521208B1 (en) 1999-03-03 2003-02-18 Pq Corporation Process for preparing a modified zeolite
WO2004044100A1 (en) 2002-11-08 2004-05-27 Chevron U.S.A. Inc. Extremely low acidity ultrastable y zeolite catalyst composition and process
US6860986B2 (en) 2002-11-08 2005-03-01 Chevron U.S.A. Inc. Extremely low acidity ultrastable Y zeolite catalyst composition and process
US6902664B2 (en) 2002-11-08 2005-06-07 Chevron U.S.A. Inc. Extremely low acidity USY and homogeneous, amorphous silica-alumina hydrocracking catalyst and process
US7192900B2 (en) 2002-11-27 2007-03-20 Shell Oil Company Hydrocracking catalyst
EP2085360A1 (en) 2007-12-27 2009-08-05 Chevron USA, Inc. Synthesis of a crystalline silicoaluminophosphate
US8372368B2 (en) 2008-07-29 2013-02-12 Chevron U.S.A. Inc. Synthesis of a crystalline silicoaluminophosphate
WO2010139997A2 (en) 2009-06-03 2010-12-09 University Of Manchester Modified zeolites and their use in the recycling of plastics waste
EP3608019A1 (en) 2009-06-03 2020-02-12 University of Manchester Modified zeolites and their use in the recycling of plastics waste
RU2481268C2 (en) * 2011-08-05 2013-05-10 Открытое акционерное общество "Корпорация "Росхимзащита" (ОАО "Корпорация "Росхимзащита") Method of producing hydrophobic zeolite
CN115806299A (en) * 2022-11-09 2023-03-17 复榆(张家港)新材料科技有限公司 Multistage Kong Gaogui hydrophobic zeolite with FAU structure

Also Published As

Publication number Publication date
DE2906656A1 (en) 1979-08-30
IT1112018B (en) 1986-01-13
DE2906656B2 (en) 1981-02-12
NL7901415A (en) 1979-08-27
JPS54122700A (en) 1979-09-22
CA1131195A (en) 1982-09-07
IT7920444A0 (en) 1979-02-22
GB2014970B (en) 1982-06-09
DE2906656C3 (en) 1982-04-01
FR2418198A1 (en) 1979-09-21
BE874373A (en) 1979-08-22
FR2418198B1 (en) 1986-09-05

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee