GB2008112A - Alkoxy-hydride derivatives of aluminium and alkaline earth metals and complexes thereof, and their use as reducing agents. - Google Patents

Alkoxy-hydride derivatives of aluminium and alkaline earth metals and complexes thereof, and their use as reducing agents.

Info

Publication number
GB2008112A
GB2008112A GB7843919A GB7843919A GB2008112A GB 2008112 A GB2008112 A GB 2008112A GB 7843919 A GB7843919 A GB 7843919A GB 7843919 A GB7843919 A GB 7843919A GB 2008112 A GB2008112 A GB 2008112A
Authority
GB
United Kingdom
Prior art keywords
complexes
alkoxy
alkaline earth
aluminium
earth metals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7843919A
Other versions
GB2008112B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anic SpA
Original Assignee
Anic SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anic SpA filed Critical Anic SpA
Publication of GB2008112A publication Critical patent/GB2008112A/en
Application granted granted Critical
Publication of GB2008112B publication Critical patent/GB2008112B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/069—Aluminium compounds without C-aluminium linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Alkoxy-hydride derivatives having the formula M [A1H4-n(OR)n]2, wherein M is an alkaline earth metal and 0.5 </= n </= 3.5, and complexes thereof with a Lewis base, are obtained by reacting a hydride having the formula M (A1H4)2, or a complex thereof with a Lewis base, with an alcohol containing up to 20 carbon atoms. The derivates and complexes are useful as catalysts for the reduction of organic compounds.
GB7843919A 1977-11-17 1978-11-09 Alkoxy-hydride derivatives of aluminimum and alkaline earth metals and complexes thereof and their use as reducing agents Expired GB2008112B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT29752/77A IT1088553B (en) 1977-11-17 1977-11-17 SYNTHESIS PROCESS OF MIXED INDUSTRIAL ALKYROXIDE AND ALKALINE-EARTH METALS AND PRODUCTS SO OBTAINED

Publications (2)

Publication Number Publication Date
GB2008112A true GB2008112A (en) 1979-05-31
GB2008112B GB2008112B (en) 1982-04-15

Family

ID=11228374

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7843919A Expired GB2008112B (en) 1977-11-17 1978-11-09 Alkoxy-hydride derivatives of aluminimum and alkaline earth metals and complexes thereof and their use as reducing agents

Country Status (12)

Country Link
JP (1) JPS5481189A (en)
AT (1) AT366053B (en)
BE (1) BE872088A (en)
DE (1) DE2849767C2 (en)
DK (1) DK509878A (en)
EG (1) EG13564A (en)
FR (1) FR2409272A1 (en)
GB (1) GB2008112B (en)
IT (1) IT1088553B (en)
NL (1) NL179823C (en)
NO (1) NO153139C (en)
SE (2) SE436750B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006079819A2 (en) * 2005-01-27 2006-08-03 University Of Nottingham Improved method for the preparation of enantiomerically enriched secondary alcohols by the addition of organoaluminium reagents to carbonyl compounds

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1110389B (en) * 1979-01-08 1985-12-23 Anic Spa PROCESS FOR THE SYNTHESIS OF ALCALINE TERROSE METAL ALCOSSIALANATES

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3060216A (en) * 1959-12-08 1962-10-23 Basf Ag Complex metal aluminum hydrides and their production
US3394158A (en) * 1963-10-02 1968-07-23 Snam Spa Complex aluminium hydrides partly substituted with alcoxylic groups
DE2125855A1 (en) * 1970-05-26 1971-12-09 Owens Illinois Inc Metal alkoxides prodn - products used as starting - materials for highly pure spinels and refractories

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006079819A2 (en) * 2005-01-27 2006-08-03 University Of Nottingham Improved method for the preparation of enantiomerically enriched secondary alcohols by the addition of organoaluminium reagents to carbonyl compounds
WO2006079819A3 (en) * 2005-01-27 2007-05-10 Univ Nottingham Improved method for the preparation of enantiomerically enriched secondary alcohols by the addition of organoaluminium reagents to carbonyl compounds

Also Published As

Publication number Publication date
NO783863L (en) 1979-05-21
FR2409272A1 (en) 1979-06-15
NL7811335A (en) 1979-05-21
SE7811815L (en) 1979-05-18
NO153139C (en) 1986-01-22
SE8400124L (en) 1984-01-11
NL179823C (en) 1986-11-17
NO153139B (en) 1985-10-14
FR2409272B1 (en) 1984-04-27
JPS5481189A (en) 1979-06-28
DE2849767A1 (en) 1979-05-23
NL179823B (en) 1986-06-16
AT366053B (en) 1982-03-10
EG13564A (en) 1981-12-31
IT1088553B (en) 1985-06-10
BE872088A (en) 1979-05-17
GB2008112B (en) 1982-04-15
DK509878A (en) 1979-05-18
SE436750B (en) 1985-01-21
SE8400124D0 (en) 1984-01-11
DE2849767C2 (en) 1982-09-02
ATA818778A (en) 1981-07-15

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee