GB191413149A - Improvements in the Manufacture of Aromatic Amines, and Materials to be used in such Manufacture. - Google Patents
Improvements in the Manufacture of Aromatic Amines, and Materials to be used in such Manufacture.Info
- Publication number
- GB191413149A GB191413149A GB191413149DA GB191413149A GB 191413149 A GB191413149 A GB 191413149A GB 191413149D A GB191413149D A GB 191413149DA GB 191413149 A GB191413149 A GB 191413149A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copper
- hydrogen
- vapour
- reduction
- catalytic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
13,149. Johnson, J. Y., [Badische Anilin & Soda Fabrik]. May 28. [Cognate Application, 15,334/14.] Catalytic agents, preparation and treatment of.-Aromatic amines are prepared by passing the corresponding nitro-compound, together with hydrogen, over a catalytic agent containing copper prepared pyrogenetically from a salt thereof and also containing a body promoting the action of the copper. Suitable promoters are alkali compounds, in particular alkali silicate, magnesia, aluminium and other metal oxides and other heavy metals or compounds thereof, such as an oxide or salt of zinc, silver, or iron. The body promoting the action may be added to the copper salt before its conversion, or to the copper oxide intermediately obtained, or to the finely divided copper itself. Water gas or other gas containing hydrogen and carbon monoxide may be used as the source of hydrogen. In examples: a paste of copper oxalate and magnesia is dried, and reduced in hydrogen, and the catalytic agent used to effect the reduction by hydrogen of o-nitrotoluene vapour; a paste of pumice, sodium silicate, copper carbonate, and zinc carbonate is reduced in hydrogen, and the catalytic agent obtained used for the reduction of nitrobenzene vapour; a paste of pumice, sodium silicate, copper carbonate, and zinc carbonate is reduced in hydrogen, and the catalytic agent obtained used for the reduction of nitrobenzene vapour; a paste of pumice, sodium silicate, copper carbonate, and iron carbonate is reduced in hydrogen, and the catalytic agent used in the reduction of nitrobenzene vapour; a mixture of pumice, copper and zinc carbonates, and water-glass is dried, and reduced in hydrogen and the catalytic agent used to effect the reduction by purified water gas of nitrobenzene vapour. Specification 2306/14 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB191413149T | 1914-05-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB191413149A true GB191413149A (en) | 1915-05-28 |
Family
ID=32584745
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB191413149D Expired GB191413149A (en) | 1914-05-28 | 1914-05-28 | Improvements in the Manufacture of Aromatic Amines, and Materials to be used in such Manufacture. |
GB191505692D Expired GB191505692A (en) | 1914-05-28 | 1915-04-15 | Improvements in the Manufacture of Aromatic Amines. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB191505692D Expired GB191505692A (en) | 1914-05-28 | 1915-04-15 | Improvements in the Manufacture of Aromatic Amines. |
Country Status (1)
Country | Link |
---|---|
GB (2) | GB191413149A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2525591A1 (en) * | 1982-04-27 | 1983-10-28 | Inst Chemii Przemyslowej | Aromatic mono:amine prepn. catalyst - comprises copper, magnesium and zinc oxide on silica or alumina support |
-
1914
- 1914-05-28 GB GB191413149D patent/GB191413149A/en not_active Expired
-
1915
- 1915-04-15 GB GB191505692D patent/GB191505692A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2525591A1 (en) * | 1982-04-27 | 1983-10-28 | Inst Chemii Przemyslowej | Aromatic mono:amine prepn. catalyst - comprises copper, magnesium and zinc oxide on silica or alumina support |
Also Published As
Publication number | Publication date |
---|---|
GB191505692A (en) | 1916-07-17 |
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