GB191021199A - Manufacture and Production of New Azodyestuffs. - Google Patents

Manufacture and Production of New Azodyestuffs.

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Publication number
GB191021199A
GB191021199A GB191021199DA GB191021199A GB 191021199 A GB191021199 A GB 191021199A GB 191021199D A GB191021199D A GB 191021199DA GB 191021199 A GB191021199 A GB 191021199A
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GB
United Kingdom
Prior art keywords
acid
sulphonic
alkyl
naphthylamine
molecular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Inventor
Philip Arthur Newton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of GB191021199A publication Critical patent/GB191021199A/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B35/00Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
    • C09B35/02Disazo dyes
    • C09B35/039Disazo dyes characterised by the tetrazo component
    • C09B35/26Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of a diaryl urea

Abstract

21,199. Newton, P. A., [Farbenfabriken vorm. F. Bayer & Co.]. Sept. 12. Disazo dyes are obtained by combining the tetrazo compound of p-p<1>-diaminodiphenyluream-m<1>-disulphonic acid in acid or neutral solution with one molecular proportion of 2-amino-8- naphthol-6-sulphonic acid or its alkyl, aralkyl, or aryl derivatives, and in the usual way with one molecular proportion of a 2-naphthylamine sulphonic acid or an alkyl or aralkyl derivative thereof, or in alkaline solution with one molecular proportion of an alkyl, aralkyl, or aryl derivative of 2-amino-5-naphthol-7-sulphonic acid; or by combining the above tetrazo compound with two molecular proportions of the same or different 2-naphthylamine sulphonic acids or their alkyl derivatives; the combinations can be effected in any order. The same dyes are obtained by treating with phosgene two molecular proportions of the alkali salts of the monoazo dyes obtained by combining the diazo compounds of p-nitraniline-o-sulphonic acid or p-acetylaminoaniline-o-sulphonic acid with a 2-naphthylamine sulphonic acid or an alkyl derivative thereof and reducing or saponifying the products, or by treating with phosgene two molecular properties of different monoazo dyes obtained as above from 2-amino-8-naphthol- 6-snlphonic acid or its alkyl, aralkyl, or aryl derivatives, 2-naphthylamine sulphonic acids or their alkyl derivatives, or alkyl, aralkyl, or aryl derivatives of 2-amino-5-naphthol-7-sulphonic acid. According to examples, dyes are obtained from the above tetrazo body and (1) two molecular proportions of 2-methylaminonaphthalene- 7-sulphonic acid, (2) one molecular proportion of 2:8:6-acid and one molecular proportion of 2-methylaminonaphthalene-7-sulphonic acid, (3) one molecular proportion of 2:8:6-acid and one molecular proportion of 2-phenylamino-5-naphthol-7-sulphonic acid. Ethyl and benzyl derivatives of 2-naphthylamine sulphonic acids, or of 2:8:6- or 2:5:7-acid are also specified as components. The production of the dye described under (1) above by treating the corresponding monoazo dye with phosgene is also given in an example. The products dye cotton red to violet-red shades. Specification 11,766/01 is referred to. The Provisional Specification refers also to the production of disazo dyes from the above tetrazo compound and two molecular proportions of 2-naphthylamine or its derivatives or one molecular proportion of one of these and one molecular proportion of any other component. Trisazo dyes.-The Provisional Specification also refers to trisazo dyes obtained from the above tetrazo compound with one molecule of 2-naphthylamine or its derivatives and one molecule of an azo dye capable of combining with diazo compounds ; according to examples the following components are used: (1) 2- methylnaphthylamine and the chrysoidine from o-sulphanilic acid and m-phenylenediamine; (2) 2:8:6-acid and the monoazo dye obtained in acid solution from aniline and 2:5:7-acid. These products also dye cotton. 2-Methylaminonaphthalene-7-sulphonic acid is obtained by treating 2-naphthol-7-sulphonic acid with methylamine in presence of bisulphite. 2-Ethylaminonaphthalene sulphonic acids are obtained similarly from 2-naphthol sulphonic acids and ethylamine. 2-Benzylaminonaphthalene sulphonic acids are obtained from 2-naphthylamine sulphonic acids and benzyl chloride.
GB191021199D 1910-09-12 1910-09-12 Manufacture and Production of New Azodyestuffs. Expired GB191021199A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB191021199T 1910-09-12

Publications (1)

Publication Number Publication Date
GB191021199A true GB191021199A (en) 1911-09-12

Family

ID=32492938

Family Applications (1)

Application Number Title Priority Date Filing Date
GB191021199D Expired GB191021199A (en) 1910-09-12 1910-09-12 Manufacture and Production of New Azodyestuffs.

Country Status (1)

Country Link
GB (1) GB191021199A (en)

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