GB164218A - Manufacture of new azodyes - Google Patents
Manufacture of new azodyesInfo
- Publication number
- GB164218A GB164218A GB1263920A GB1263920A GB164218A GB 164218 A GB164218 A GB 164218A GB 1263920 A GB1263920 A GB 1263920A GB 1263920 A GB1263920 A GB 1263920A GB 164218 A GB164218 A GB 164218A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nitraniline
- sulphonic acid
- naphthylamine
- naphthol
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/24—Monoazo dyes prepared by diazotising and coupling from coupling components containing both hydroxyl and amino directing groups
- C09B29/28—Amino naphthols
- C09B29/30—Amino naphtholsulfonic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Monoazo dyes are obtained by coupling 4 - nitraniline - 2 - sulphonamide, in which one or both hydrogen atoms of the sulphonamide group are replaced by alkyl, aryl, or aralkyl) with a 2 - naphthylamine sulphonic acid or a 2 - amino - 8 - naphthol sulphonic acid, or a derivative thereof, in acid solution. As diazo components are mentioned 4 - nitraniline - 2 - sulphoethylanilide, 4 - nitraniline - 2 - sulphanilide, 4 - nitraniline - 2 - sulphodiphenylamide, 4 - nitraniline - 2 - sulphomethylanilide, 4 - nitraniline - 2 - sulphomethylamide, 4 - nitraniline - 2 - sulphomethyl - o-toluidide, 4 - nitraniline - 2 - sulphopiperidide; as second components, 2 - amino - 8 - naphthol - 6 - sulphonic acid, 2 - methylamino - 8 - naphthol - 6 - sulphonic acid, 2 - naphthylamine - 8 - sulphonic acid, 2 - naphthylamine - 6 : 8 - disulphonic acid, o-anisyl-2-naphthylamine-8-sulphonic acid. The products may be reduced with alkaline reducing agents. According to one example, diazotized 4 - nitraniline - 2 - sulphoethylanilide is coupled with 2 - amino - 8 - naphthol - 6 - sulphonic acid in glacial acetic acid solution yielding a navy-blue wool dye; in a second example the solution obtained by effecting the same combination in weak mineral acid solution is reduced by sodium sulphide giving a bluish wool dye. 4 - Nitraniline - 2 - sulphonamides, substituted in the sulphonamide group, are obtained by treating 4 - nitro - 1 - chlorobenzene - 2 - sulphonic chloride with an amine and replacing the chlorine atom in the 1 - position by -NH2 in the usual manner. o - Anisyl - 2 - naphthylamine - 8 - sulphonic acid is obtained in the manner described in Specifications 7337A/92 and 18726/00 from 2 - naphthylamine - 8 - sulphonic acid or 2 - naphthol - 8 - sulphonic acid and o - anisidine.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1263920A GB164218A (en) | 1920-05-06 | 1920-05-06 | Manufacture of new azodyes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1263920A GB164218A (en) | 1920-05-06 | 1920-05-06 | Manufacture of new azodyes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB164218A true GB164218A (en) | 1921-06-09 |
Family
ID=10008400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1263920A Expired GB164218A (en) | 1920-05-06 | 1920-05-06 | Manufacture of new azodyes |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB164218A (en) |
-
1920
- 1920-05-06 GB GB1263920A patent/GB164218A/en not_active Expired
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