GB1589097A - Process for producing copolymers of ethylene and polyethylenically unsaturated polycyclic hydrocarbons - Google Patents
Process for producing copolymers of ethylene and polyethylenically unsaturated polycyclic hydrocarbons Download PDFInfo
- Publication number
- GB1589097A GB1589097A GB35803/79A GB3580379A GB1589097A GB 1589097 A GB1589097 A GB 1589097A GB 35803/79 A GB35803/79 A GB 35803/79A GB 3580379 A GB3580379 A GB 3580379A GB 1589097 A GB1589097 A GB 1589097A
- Authority
- GB
- United Kingdom
- Prior art keywords
- process according
- vanadium
- copolymer
- ethylene
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 34
- 229920001577 copolymer Polymers 0.000 title claims description 26
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 17
- 239000005977 Ethylene Substances 0.000 title claims description 17
- 229930195733 hydrocarbon Natural products 0.000 title claims description 10
- -1 unsaturated polycyclic hydrocarbons Chemical class 0.000 title claims description 7
- 230000003197 catalytic effect Effects 0.000 claims description 16
- 229910052720 vanadium Inorganic materials 0.000 claims description 10
- 150000003682 vanadium compounds Chemical class 0.000 claims description 10
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 9
- 238000007334 copolymerization reaction Methods 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 150000001399 aluminium compounds Chemical class 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 5
- 125000003367 polycyclic group Chemical group 0.000 claims description 4
- 125000005287 vanadyl group Chemical group 0.000 claims description 4
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229940077746 antacid containing aluminium compound Drugs 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 150000005840 aryl radicals Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 239000012429 reaction media Substances 0.000 claims description 2
- 239000012066 reaction slurry Substances 0.000 claims description 2
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 5
- SQAKRHGQZJZSRW-UHFFFAOYSA-N C12(C=CC(CC1)C2)C2=C(CCC=C2)C(C)(C)C.C Chemical compound C12(C=CC(CC1)C2)C2=C(CCC=C2)C(C)(C)C.C SQAKRHGQZJZSRW-UHFFFAOYSA-N 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000004132 cross linking Methods 0.000 claims 1
- 150000003681 vanadium Chemical class 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000009826 distribution Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- VUNCWTMEJYMOOR-UHFFFAOYSA-N hexachlorocyclopentadiene Chemical compound ClC1=C(Cl)C(Cl)(Cl)C(Cl)=C1Cl VUNCWTMEJYMOOR-UHFFFAOYSA-N 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- NSWUXAUIAZVROT-UHFFFAOYSA-N 1-(2-cyclopenta-1,3-dien-1-ylpropan-2-yl)cyclopenta-1,3-diene Chemical compound C=1C=CCC=1C(C)(C)C1=CC=CC1 NSWUXAUIAZVROT-UHFFFAOYSA-N 0.000 description 1
- JESYUGLAAYESAZ-UHFFFAOYSA-N 2,3-dimethyl-1-penta-1,3-dienylbicyclo[2.2.1]hept-2-ene Chemical compound CC1=C(C2(CCC1C2)C=CC=CC)C JESYUGLAAYESAZ-UHFFFAOYSA-N 0.000 description 1
- OTTZHAVKAVGASB-HYXAFXHYSA-N 2-Heptene Chemical compound CCCC\C=C/C OTTZHAVKAVGASB-HYXAFXHYSA-N 0.000 description 1
- OTTZHAVKAVGASB-UHFFFAOYSA-N 2-heptene Natural products CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/14—Organic medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT25379/76A IT1064663B (it) | 1976-07-16 | 1976-07-16 | Procedimento per la preparazione in alta resa di copolimeri dell etilene con polieni |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1589097A true GB1589097A (en) | 1981-05-07 |
Family
ID=11216523
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB35803/79A Expired GB1589097A (en) | 1976-07-16 | 1977-07-07 | Process for producing copolymers of ethylene and polyethylenically unsaturated polycyclic hydrocarbons |
| GB28622/77A Expired GB1589095A (en) | 1976-07-16 | 1977-07-07 | Process for producing cross-linked copolymers of ethylene and polyethylenically unsaturated polycyclic hydrocarbons |
| GB35802/79A Expired GB1589096A (en) | 1976-07-16 | 1977-07-07 | Process for producing copolymers of ethylene and polyethylenically unsaturated polycyclic hydrocarbons |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28622/77A Expired GB1589095A (en) | 1976-07-16 | 1977-07-07 | Process for producing cross-linked copolymers of ethylene and polyethylenically unsaturated polycyclic hydrocarbons |
| GB35802/79A Expired GB1589096A (en) | 1976-07-16 | 1977-07-07 | Process for producing copolymers of ethylene and polyethylenically unsaturated polycyclic hydrocarbons |
Country Status (20)
-
1976
- 1976-07-16 IT IT25379/76A patent/IT1064663B/it active
-
1977
- 1977-07-06 IL IL52475A patent/IL52475A/xx unknown
- 1977-07-07 GB GB35803/79A patent/GB1589097A/en not_active Expired
- 1977-07-07 GB GB28622/77A patent/GB1589095A/en not_active Expired
- 1977-07-07 GB GB35802/79A patent/GB1589096A/en not_active Expired
- 1977-07-07 AU AU26852/77A patent/AU512515B2/en not_active Expired
- 1977-07-07 CA CA282,224A patent/CA1112799A/en not_active Expired
- 1977-07-13 DD DD7700200041A patent/DD130483A5/xx unknown
- 1977-07-13 NL NL7707832A patent/NL7707832A/xx not_active Application Discontinuation
- 1977-07-13 CS CS774674A patent/CS199508B2/cs unknown
- 1977-07-13 FR FR7721715A patent/FR2358429A1/fr active Granted
- 1977-07-14 YU YU01749/77A patent/YU174977A/xx unknown
- 1977-07-14 CH CH873977A patent/CH628909A5/it not_active IP Right Cessation
- 1977-07-14 JP JP8363777A patent/JPS5311983A/ja active Pending
- 1977-07-14 NO NO772510A patent/NO147214C/no unknown
- 1977-07-14 LU LU77761A patent/LU77761A1/xx unknown
- 1977-07-15 SE SE7708247A patent/SE7708247L/xx not_active Application Discontinuation
- 1977-07-15 ZA ZA00774264A patent/ZA774264B/xx unknown
- 1977-07-15 DK DK323377A patent/DK323377A/da not_active Application Discontinuation
- 1977-07-15 DE DE19772732110 patent/DE2732110A1/de not_active Withdrawn
- 1977-07-15 HU HU77SA3047A patent/HU178728B/hu unknown
- 1977-07-15 BE BE179391A patent/BE856867A/xx not_active IP Right Cessation
-
1982
- 1982-07-05 YU YU01458/82A patent/YU145882A/xx unknown
- 1982-07-05 YU YU01457/82A patent/YU145782A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| LU77761A1 (enrdf_load_stackoverflow) | 1977-10-17 |
| FR2358429A1 (fr) | 1978-02-10 |
| AU2685277A (en) | 1979-01-11 |
| NO772510L (no) | 1978-01-17 |
| JPS5311983A (en) | 1978-02-02 |
| GB1589095A (en) | 1981-05-07 |
| HU178728B (en) | 1982-06-28 |
| CA1112799A (en) | 1981-11-17 |
| IT1064663B (it) | 1985-02-25 |
| YU145882A (en) | 1983-10-31 |
| CH628909A5 (en) | 1982-03-31 |
| CS199508B2 (en) | 1980-07-31 |
| NL7707832A (nl) | 1978-01-18 |
| NO147214B (no) | 1982-11-15 |
| YU145782A (en) | 1983-10-31 |
| BE856867A (fr) | 1978-01-16 |
| YU174977A (en) | 1982-10-31 |
| ZA774264B (en) | 1978-06-28 |
| NO147214C (no) | 1983-02-23 |
| FR2358429B1 (enrdf_load_stackoverflow) | 1981-05-22 |
| DE2732110A1 (de) | 1978-01-19 |
| DK323377A (da) | 1978-01-17 |
| DD130483A5 (de) | 1978-04-05 |
| IL52475A0 (en) | 1977-10-31 |
| AU512515B2 (en) | 1980-10-16 |
| GB1589096A (en) | 1981-05-07 |
| IL52475A (en) | 1981-10-30 |
| SE7708247L (sv) | 1978-01-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3378606A (en) | Semicrystalline stereoblock copolymers | |
| CA2018666C (en) | Polypropylene resin compositions of high syndiotacticity and preparation process thereof | |
| EP0381495B1 (en) | Method of production of polyethylene | |
| US4491652A (en) | Sequentially prepared thermoplastic elastomer and method of preparing same | |
| JPH05202152A (ja) | ポリプロピレン成形材料の製造方法 | |
| JPS62148503A (ja) | オレフイン系ベンゾシクロブテンポリマ−及びその製法 | |
| CA1049197A (en) | Polymers of olefins and polar monomers | |
| US2879261A (en) | Chlorosulfonated hydrocarbon copolymers | |
| JP2854886B2 (ja) | プロピレンとブテンの共重合体 | |
| US3097194A (en) | Process for preparing phosphorylated elastomeric copolymers of ethylene and propylene | |
| US4550145A (en) | Process for the production of propylene block copolymers by a three step method | |
| JPS62121711A (ja) | 低結晶性エチレン系ランダム共重合体 | |
| NO160786B (no) | Katalysator til polymerisering av alkener og anvendelse av katalysatoren til polymerisering av propen. | |
| US2852497A (en) | Unsaturated sulfonamides of chlorosulfonated olefin polymers | |
| JPS5817205B2 (ja) | ポリオレフインの製法 | |
| EP0658571B1 (en) | Olefin polymerization process, catalyst system, and polymer | |
| CA1114098A (en) | Process for producing ethylene copolymers | |
| GB2087409A (en) | Propylene polymerization process | |
| US4355144A (en) | Process for producing a propylene-ethylene copolymer having improved stretchability | |
| US3431245A (en) | Production of novel polymers and polymerization process therefor | |
| US3480599A (en) | Unsaturated interpolymers of linear aliphatic heptadienes and/or heptatrienes and alpha-olefins | |
| GB1589097A (en) | Process for producing copolymers of ethylene and polyethylenically unsaturated polycyclic hydrocarbons | |
| US3093624A (en) | Copolymers of olefines containing at least three carbon atoms | |
| US3457246A (en) | Copolymers of 4-methyl-1-pentene with lower 1-olefins | |
| US3187067A (en) | Method of making polystyrene-ethylene graft copolymer and product therefrom |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |