GB1536160A - Method for the polymerization of vinyl chloride - Google Patents
Method for the polymerization of vinyl chlorideInfo
- Publication number
- GB1536160A GB1536160A GB52622/75A GB5262275A GB1536160A GB 1536160 A GB1536160 A GB 1536160A GB 52622/75 A GB52622/75 A GB 52622/75A GB 5262275 A GB5262275 A GB 5262275A GB 1536160 A GB1536160 A GB 1536160A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymerisation
- vinyl chloride
- polar organic
- monomers
- oxygen acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/004—Scale prevention in a polymerisation reactor or its auxiliary parts by a prior coating on the reactor walls
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
In the polymerisation of monomeric vinyl chloride, alone or mixed with one or more olefinically unsaturated, copolymerisable monomers, in the presence of a polymerisation initiator, the deposition of polymer crusts is prevented, and the quality and the productivity increased, if, before the polymerisation, the surfaces of the inside wall and other parts of the polymerisation vessel which come into contact with the monomer or the monomers are each treated with at least one compound selected from a) polar organic compounds, including polar organic dyes, and b) halides, hydroxides, oxides, and carboxylates of metals, oxygen acids of elements from the second to the sixth period of groups IIB and III to VII of the Periodic Table, and inorganic salts of these oxygen acids. The compounds a) and b) are applied separately or simultaneously, using conventional techniques.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP75157A JPS5224953B2 (en) | 1974-12-27 | 1974-12-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1536160A true GB1536160A (en) | 1978-12-20 |
Family
ID=11466193
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB52622/75A Expired GB1536160A (en) | 1974-12-27 | 1975-12-23 | Method for the polymerization of vinyl chloride |
Country Status (30)
Country | Link |
---|---|
JP (1) | JPS5224953B2 (en) |
AR (1) | AR216895A1 (en) |
AT (1) | AT345555B (en) |
AU (1) | AU502319B2 (en) |
BE (1) | BE837056A (en) |
BR (1) | BR7508670A (en) |
CA (1) | CA1118943A (en) |
CH (1) | CH631187A5 (en) |
CS (1) | CS195302B2 (en) |
DD (1) | DD125352A5 (en) |
DE (1) | DE2557788A1 (en) |
DK (1) | DK150524C (en) |
ES (1) | ES443892A1 (en) |
FI (1) | FI58782C (en) |
FR (1) | FR2295971A1 (en) |
GB (1) | GB1536160A (en) |
HU (1) | HU174511B (en) |
IE (1) | IE42459B1 (en) |
IL (1) | IL48717A (en) |
IN (1) | IN143739B (en) |
IT (1) | IT1051915B (en) |
NL (1) | NL174357C (en) |
NO (1) | NO754343L (en) |
NZ (1) | NZ179652A (en) |
PH (1) | PH11096A (en) |
RO (1) | RO71577A (en) |
SE (1) | SE7514509L (en) |
TR (1) | TR19219A (en) |
YU (1) | YU39120B (en) |
ZA (1) | ZA757968B (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1980002388A1 (en) * | 1979-04-30 | 1980-11-13 | Goodrich Co B F | Coating polymerization reactors with the reaction products of thiodiphenols and a bleach |
FR2457169A1 (en) * | 1979-05-22 | 1980-12-19 | Shinetsu Chemical Co | PROCESS FOR PREVENTING THE FORMATION OF POLYMER DEPOSITS DURING THE POLYMERIZATION OF AN ETHYLENICALLY UNSATURATED MONOMER IN AQUEOUS MEDIA |
US4359560A (en) | 1978-06-13 | 1982-11-16 | Air Products And Chemicals, Inc. | Method for reducing wall fouling in vinyl chloride polymerization |
EP0096319A1 (en) * | 1982-05-31 | 1983-12-21 | Shin-Etsu Chemical Co., Ltd. | Method for preventing scale deposition in the polymerization of ethylenically unsaturated monomers |
EP0177775A1 (en) * | 1984-09-11 | 1986-04-16 | The B.F. GOODRICH Company | Internally coated reaction vessel for use in olefinic polymerization |
EP0210104A1 (en) * | 1985-07-18 | 1987-01-28 | Shin-Etsu Chemical Co., Ltd. | A method for preventing polymer scale deposition on the reactor walls in the polymerization of ethylenically unsaturated monomers |
EP0320227A2 (en) * | 1987-12-08 | 1989-06-14 | Shin-Etsu Chemical Co., Ltd. | Method of preventing polymer-scale formation |
EP0805168A1 (en) * | 1996-04-30 | 1997-11-05 | Shin-Etsu Chemical Co., Ltd. | Vinyl chloride polymer |
CN115197351A (en) * | 2022-07-06 | 2022-10-18 | 新疆中泰化学托克逊能化有限公司 | Vinyl chloride resin material and preparation method thereof |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5213592A (en) * | 1975-07-23 | 1977-02-01 | Shin Etsu Chem Co Ltd | Polymerization of vinyl chloride |
US4068052A (en) * | 1976-06-23 | 1978-01-10 | Continental Oil Company | Reducing PVC polymer buildup in polymerization reactors with dithioxamides and alumina |
GR64894B (en) * | 1977-01-25 | 1980-06-07 | Shinetsu Chemical Co | Method for the polymerization of a vinyl menomer |
JPS548690A (en) * | 1977-06-20 | 1979-01-23 | Goodrich Co B F | Method of preventing polymer from adhering on inner surface of polymerization reactor |
JPS59170102A (en) * | 1983-03-17 | 1984-09-26 | Shin Etsu Chem Co Ltd | Polymerization of vinyl monomer |
JPS60233103A (en) * | 1984-05-07 | 1985-11-19 | Shin Etsu Chem Co Ltd | Polymerization of vinyl monomers |
JPS63180849U (en) * | 1987-05-13 | 1988-11-22 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2044259C2 (en) * | 1970-09-07 | 1985-08-22 | Shinetsu Chemical Co., Tokio/Tokyo | Process for the suspension polymerization of vinyl chloride |
US3962202A (en) * | 1973-08-27 | 1976-06-08 | The B. F. Goodrich Company | Process for polymerizing olefinic monomers which substantially eliminates polymer buildup |
US3849179A (en) * | 1973-08-27 | 1974-11-19 | Goodrich Co B F | Internally coated reaction vessel and process for coating the same |
-
1974
- 1974-12-27 JP JP75157A patent/JPS5224953B2/ja not_active Expired
-
1975
- 1975-12-19 NL NLAANVRAGE7514844,A patent/NL174357C/en active Search and Examination
- 1975-12-19 CA CA000242161A patent/CA1118943A/en not_active Expired
- 1975-12-22 SE SE7514509A patent/SE7514509L/en unknown
- 1975-12-22 DE DE19752557788 patent/DE2557788A1/en not_active Withdrawn
- 1975-12-22 NO NO75754343A patent/NO754343L/no unknown
- 1975-12-22 FI FI753618A patent/FI58782C/en not_active IP Right Cessation
- 1975-12-22 DK DK585075A patent/DK150524C/en not_active IP Right Cessation
- 1975-12-23 IE IE2819/75A patent/IE42459B1/en unknown
- 1975-12-23 NZ NZ179652A patent/NZ179652A/en unknown
- 1975-12-23 ZA ZA757968A patent/ZA757968B/en unknown
- 1975-12-23 PH PH17914A patent/PH11096A/en unknown
- 1975-12-23 AT AT978675A patent/AT345555B/en not_active IP Right Cessation
- 1975-12-23 IT IT7530709A patent/IT1051915B/en active
- 1975-12-23 HU HU75SI1504A patent/HU174511B/en unknown
- 1975-12-23 GB GB52622/75A patent/GB1536160A/en not_active Expired
- 1975-12-24 IL IL7548717A patent/IL48717A/en unknown
- 1975-12-24 YU YU03289/75A patent/YU39120B/en unknown
- 1975-12-24 FR FR7539658A patent/FR2295971A1/en active Granted
- 1975-12-24 CH CH1680075A patent/CH631187A5/en not_active IP Right Cessation
- 1975-12-24 BE BE163092A patent/BE837056A/en not_active IP Right Cessation
- 1975-12-25 TR TR19219A patent/TR19219A/en unknown
- 1975-12-26 BR BR7508670*A patent/BR7508670A/en unknown
- 1975-12-26 ES ES75443892A patent/ES443892A1/en not_active Expired
- 1975-12-27 RO RO197584335A patent/RO71577A/en unknown
- 1975-12-27 CS CS758885A patent/CS195302B2/en unknown
- 1975-12-29 DD DD190610A patent/DD125352A5/xx unknown
- 1975-12-29 AR AR261781A patent/AR216895A1/en active
- 1975-12-30 AU AU87939/75A patent/AU502319B2/en not_active Expired
-
1976
- 1976-01-05 IN IN36/CAL/76A patent/IN143739B/en unknown
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4359560A (en) | 1978-06-13 | 1982-11-16 | Air Products And Chemicals, Inc. | Method for reducing wall fouling in vinyl chloride polymerization |
WO1980002388A1 (en) * | 1979-04-30 | 1980-11-13 | Goodrich Co B F | Coating polymerization reactors with the reaction products of thiodiphenols and a bleach |
EP0027466A1 (en) * | 1979-04-30 | 1981-04-29 | Goodrich Co B F | Coating polymerization reactors with the reaction products of thiodiphenols and a bleach. |
EP0027466A4 (en) * | 1979-04-30 | 1981-08-27 | Goodrich Co B F | Coating polymerization reactors with the reaction products of thiodiphenols and a bleach. |
FR2457169A1 (en) * | 1979-05-22 | 1980-12-19 | Shinetsu Chemical Co | PROCESS FOR PREVENTING THE FORMATION OF POLYMER DEPOSITS DURING THE POLYMERIZATION OF AN ETHYLENICALLY UNSATURATED MONOMER IN AQUEOUS MEDIA |
EP0096319A1 (en) * | 1982-05-31 | 1983-12-21 | Shin-Etsu Chemical Co., Ltd. | Method for preventing scale deposition in the polymerization of ethylenically unsaturated monomers |
EP0177775A1 (en) * | 1984-09-11 | 1986-04-16 | The B.F. GOODRICH Company | Internally coated reaction vessel for use in olefinic polymerization |
EP0210104A1 (en) * | 1985-07-18 | 1987-01-28 | Shin-Etsu Chemical Co., Ltd. | A method for preventing polymer scale deposition on the reactor walls in the polymerization of ethylenically unsaturated monomers |
EP0320227A2 (en) * | 1987-12-08 | 1989-06-14 | Shin-Etsu Chemical Co., Ltd. | Method of preventing polymer-scale formation |
EP0320227A3 (en) * | 1987-12-08 | 1990-10-10 | Shin-Etsu Chemical Co., Ltd. | Method of preventing polymer-scale formation |
EP0805168A1 (en) * | 1996-04-30 | 1997-11-05 | Shin-Etsu Chemical Co., Ltd. | Vinyl chloride polymer |
US6022932A (en) * | 1996-04-30 | 2000-02-08 | Shin-Etsu Chemical Co., Ltd. | Process for producing vinyl chloride polymer, with iron chelates in coated vessel |
US6355743B1 (en) | 1996-04-30 | 2002-03-12 | Shin-Etsu Chemical Co., Ltd. | Process for producing vinyl chloride polymer in the presence of a chelating agent |
CN115197351A (en) * | 2022-07-06 | 2022-10-18 | 新疆中泰化学托克逊能化有限公司 | Vinyl chloride resin material and preparation method thereof |
Also Published As
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |