GB1533384A - Treatment of effluents - Google Patents

Treatment of effluents

Info

Publication number
GB1533384A
GB1533384A GB51562/74A GB5156274A GB1533384A GB 1533384 A GB1533384 A GB 1533384A GB 51562/74 A GB51562/74 A GB 51562/74A GB 5156274 A GB5156274 A GB 5156274A GB 1533384 A GB1533384 A GB 1533384A
Authority
GB
United Kingdom
Prior art keywords
liquor
aqueous
nov
sulphuric acid
wash
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB51562/74A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British Gas Corp
Original Assignee
British Gas Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Gas Corp filed Critical British Gas Corp
Priority to GB51562/74A priority Critical patent/GB1533384A/en
Priority to ZA00757079A priority patent/ZA757079B/en
Priority to JP50141083A priority patent/JPS5178069A/ja
Priority to DE19752552979 priority patent/DE2552979A1/en
Priority to IT69926/75A priority patent/IT1051297B/en
Priority to FR7536350A priority patent/FR2332233A1/en
Publication of GB1533384A publication Critical patent/GB1533384A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • C10K1/124Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors containing metal compounds other than alkali- or earth-alkali carbonates, hydroxides- or oxides- or salts of inorganic acids derived from sulfur
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/12Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
    • C10K1/128Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors containing organic oxygen transferring compounds, e.g. sulfoxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Biomedical Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

1533384 Removal of H 2 S BRITISH GAS CORP 10 Nov 1975 [28 Nov 1974] 51562/74 Heading C1A Thiosulphates are removed from aqueous redox wash liquors by adding an aqueous solution of sulphuric acid of concentration 10-50% w./w. at ambient to 100‹ C., wherein the amount of sulphuric acid solution added to said liquor is such that the gram-molecular weight ratio of the H 2 SO 4 to thiosulphate ranges from 1:1 to 1:3. The aqueous redox wash liquors may be obtained by treating a hydrogen-sulphide containing gas or non-polar liquid with aqueous alkaline wash liquor comprising a salt of an anthraquinone disulphonic acid or derivative thereof and a compound of a metal having at least two stable valency states. After acidifying according to the invention the resultantsulphate-containing solution may be subjected to a solubility lowering technique and the solid sulphate may be removed from the resultant mother liquor, which may be returned to the process liquor stream after suitable pH adjustment.
GB51562/74A 1974-11-28 1974-11-28 Treatment of effluents Expired GB1533384A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
GB51562/74A GB1533384A (en) 1974-11-28 1974-11-28 Treatment of effluents
ZA00757079A ZA757079B (en) 1974-11-28 1975-11-11 Improvements in or relating to treatment of effluents
JP50141083A JPS5178069A (en) 1974-11-28 1975-11-25
DE19752552979 DE2552979A1 (en) 1974-11-28 1975-11-26 METHOD FOR TREATMENT OF Aqueous DRAIN FROM WASHING LUGS USED TO PURIFY GASES AND HYDROCARBON LIQUIDS
IT69926/75A IT1051297B (en) 1974-11-28 1975-11-27 PROCEDURE FOR THE TREATMENT OF LIQUID EFFLUENTS CONTAINING TIOSOL SULPHATES
FR7536350A FR2332233A1 (en) 1974-11-28 1975-11-27 IMPROVEMENT IN THE TREATMENT OF AQUEOUS EFFLUENTS CONTAINING SULFUR COMPOUNDS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB51562/74A GB1533384A (en) 1974-11-28 1974-11-28 Treatment of effluents

Publications (1)

Publication Number Publication Date
GB1533384A true GB1533384A (en) 1978-11-22

Family

ID=10460499

Family Applications (1)

Application Number Title Priority Date Filing Date
GB51562/74A Expired GB1533384A (en) 1974-11-28 1974-11-28 Treatment of effluents

Country Status (6)

Country Link
JP (1) JPS5178069A (en)
DE (1) DE2552979A1 (en)
FR (1) FR2332233A1 (en)
GB (1) GB1533384A (en)
IT (1) IT1051297B (en)
ZA (1) ZA757079B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2155453A (en) * 1984-03-12 1985-09-25 British Gas Corp Treatment of "Stretford" redox solutions
CN102815812A (en) * 2011-06-10 2012-12-12 中国石油化工股份有限公司 Optimization process method for recovering sodium sulfate form ethylene waste alkali

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0002880B1 (en) * 1977-10-13 1982-04-21 British Gas Corporation Regeneration of an absorbent liquid
JPS5495969A (en) * 1978-01-11 1979-07-28 Kobe Steel Ltd Desulfurizing method for gas containing hydrogen sulfide
DE2906056A1 (en) * 1979-02-16 1980-08-28 Linde Ag METHOD FOR RECOVERY OF THE SALTS OF ANTHRACHINON DISULPHONIC ACIDS FROM A WASHING LIQUID FLOW
DE3016240A1 (en) * 1980-04-26 1981-10-29 Linde Ag, 6200 Wiesbaden METHOD FOR TREATING AN AQUEOUS ALKALINE SOLUTION OF ANTHRACHINONE DISULPHONIC ACID SALTS

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2155453A (en) * 1984-03-12 1985-09-25 British Gas Corp Treatment of "Stretford" redox solutions
CN102815812A (en) * 2011-06-10 2012-12-12 中国石油化工股份有限公司 Optimization process method for recovering sodium sulfate form ethylene waste alkali
CN102815812B (en) * 2011-06-10 2013-11-06 中国石油化工股份有限公司 Optimization process method for recovering sodium sulfate form ethylene waste alkali

Also Published As

Publication number Publication date
FR2332233A1 (en) 1977-06-17
JPS5178069A (en) 1976-07-07
IT1051297B (en) 1981-04-21
FR2332233B3 (en) 1978-09-01
ZA757079B (en) 1976-10-27
DE2552979A1 (en) 1976-08-12

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee