GB1500607A - Photopolymerizable resin composition - Google Patents
Photopolymerizable resin compositionInfo
- Publication number
- GB1500607A GB1500607A GB2286075A GB2286075A GB1500607A GB 1500607 A GB1500607 A GB 1500607A GB 2286075 A GB2286075 A GB 2286075A GB 2286075 A GB2286075 A GB 2286075A GB 1500607 A GB1500607 A GB 1500607A
- Authority
- GB
- United Kingdom
- Prior art keywords
- component
- acid component
- weight
- parts
- initiator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011342 resin composition Substances 0.000 title 1
- 239000002253 acid Substances 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical group C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 abstract 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 abstract 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 abstract 1
- 244000028419 Styrax benzoin Species 0.000 abstract 1
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 1
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 1
- 239000012670 alkaline solution Substances 0.000 abstract 1
- 229960002130 benzoin Drugs 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 1
- 235000019382 gum benzoic Nutrition 0.000 abstract 1
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229920006305 unsaturated polyester Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
- C08F299/0407—Processes of polymerisation
- C08F299/0421—Polymerisation initiated by wave energy or particle radiation
- C08F299/0428—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F299/0435—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1500607 Printing plates SUMITOMO CHEMICAL CO Ltd 23 May 1975 [6 June 1974] 22860/75 Heading G2C [Also in Division C3] Photosensitive plates suitable for the production of printing plates comprise a support bearing a layer of a photopolymerisable composition comprising (a) 80-40 parts by weight of an unsaturated polyester which contains an acid component -OC-CH==CH-C-, at least one glycol component # O# ## -(OCH2CH2)nwhere n is 2-4 and optionally a further acid component -OC-C6H4 -C- in a molar O #O # ## proportion not exceeding that of the first acid component, the polyester having an acid value of 15-30; (b) 20-60 parts by weight of a crosslinking monomer or monomers containing #-hydroxyethyl methacrylate as an essential component; (c) a photopolymerisation initiator; and (d) a heat polymerization inhibitor. Component (b) may include up to 50 wt. per cent of a diethylenically unsaturated monomer such as di-or tri-ethylene glycol dimethacrylate. In Examples the initiator is benzoin or benzoin methyl ether and the inhibitor is hydroquinone. The exposed plate is developed using an alkaline solution e.g. sodium hydroxide, and can then be used in a heat press operating at temperatures up to 200‹C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6469874A JPS5242084B2 (en) | 1974-06-06 | 1974-06-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1500607A true GB1500607A (en) | 1978-02-08 |
Family
ID=13265618
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2286075A Expired GB1500607A (en) | 1974-06-06 | 1975-05-23 | Photopolymerizable resin composition |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5242084B2 (en) |
CA (1) | CA1059683A (en) |
DE (1) | DE2525297A1 (en) |
FR (1) | FR2273827A1 (en) |
GB (1) | GB1500607A (en) |
IT (1) | IT1036182B (en) |
NL (1) | NL7506773A (en) |
SU (1) | SU917712A3 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0896259A2 (en) * | 1997-08-04 | 1999-02-10 | HSM Holographic Systems München GmbH | Method and device for producing a surface structure, in particular a holographic surface structure, on a substrate |
AU741157B2 (en) * | 1997-09-04 | 2001-11-22 | Signet Armorlite, Inc. | Production of photopolymerized polyester high index ophthalmic lenses |
US10272492B2 (en) | 2016-04-14 | 2019-04-30 | Desktop Metal, Inc. | Multi-part removable support structures |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5176381A (en) * | 1974-12-27 | 1976-07-01 | Toyo Boseki | TAISHOKUSEIFUHOWAHORIESUTERUJUSHI |
CA1069638A (en) * | 1976-05-14 | 1980-01-08 | Earl E. Parker | Low smoke density fire-retardant unsaturated aliphatic polyester resins containing alumina hydrate |
JPS58182631A (en) * | 1982-04-20 | 1983-10-25 | Nippon Synthetic Chem Ind Co Ltd:The | Image forming composition |
-
1974
- 1974-06-06 JP JP6469874A patent/JPS5242084B2/ja not_active Expired
-
1975
- 1975-05-23 GB GB2286075A patent/GB1500607A/en not_active Expired
- 1975-05-27 CA CA227,841A patent/CA1059683A/en not_active Expired
- 1975-06-05 IT IT6845175A patent/IT1036182B/en active
- 1975-06-05 FR FR7517596A patent/FR2273827A1/en active Granted
- 1975-06-06 SU SU752143210A patent/SU917712A3/en active
- 1975-06-06 DE DE19752525297 patent/DE2525297A1/en not_active Withdrawn
- 1975-06-06 NL NL7506773A patent/NL7506773A/en not_active Application Discontinuation
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0896259A2 (en) * | 1997-08-04 | 1999-02-10 | HSM Holographic Systems München GmbH | Method and device for producing a surface structure, in particular a holographic surface structure, on a substrate |
EP0896259A3 (en) * | 1997-08-04 | 1999-07-28 | HSM Holographic Systems München GmbH | Method and device for producing a surface structure, in particular a holographic surface structure, on a substrate |
AU741157B2 (en) * | 1997-09-04 | 2001-11-22 | Signet Armorlite, Inc. | Production of photopolymerized polyester high index ophthalmic lenses |
US10272492B2 (en) | 2016-04-14 | 2019-04-30 | Desktop Metal, Inc. | Multi-part removable support structures |
Also Published As
Publication number | Publication date |
---|---|
JPS50155303A (en) | 1975-12-15 |
CA1059683A (en) | 1979-07-31 |
FR2273827A1 (en) | 1976-01-02 |
SU917712A3 (en) | 1982-03-30 |
FR2273827B1 (en) | 1979-01-05 |
NL7506773A (en) | 1975-12-09 |
JPS5242084B2 (en) | 1977-10-22 |
IT1036182B (en) | 1979-10-30 |
DE2525297A1 (en) | 1975-12-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |