GB1493522A - Production of tertiary(hydroxymethyl)-methylphosphine oxides - Google Patents
Production of tertiary(hydroxymethyl)-methylphosphine oxidesInfo
- Publication number
- GB1493522A GB1493522A GB11927/75A GB1192775A GB1493522A GB 1493522 A GB1493522 A GB 1493522A GB 11927/75 A GB11927/75 A GB 11927/75A GB 1192775 A GB1192775 A GB 1192775A GB 1493522 A GB1493522 A GB 1493522A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxymethyl
- solvent
- tertiary
- rearrangement
- carried out
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 title abstract 2
- 238000006462 rearrangement reaction Methods 0.000 abstract 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003701 inert diluent Substances 0.000 abstract 2
- 239000012442 inert solvent Substances 0.000 abstract 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 230000008707 rearrangement Effects 0.000 abstract 2
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 229930040373 Paraformaldehyde Natural products 0.000 abstract 1
- 239000006004 Quartz sand Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- WFFKVKZKYNJGCV-UHFFFAOYSA-N [hydroxymethyl(methyl)phosphanyl]methanol Chemical compound OCP(C)CO WFFKVKZKYNJGCV-UHFFFAOYSA-N 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- RQOKIVVUNQCMJS-UHFFFAOYSA-N dimethylphosphorylmethanol Chemical compound CP(C)(=O)CO RQOKIVVUNQCMJS-UHFFFAOYSA-N 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 239000011968 lewis acid catalyst Substances 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- SAWKFRBJGLMMES-UHFFFAOYSA-N methylphosphine Chemical compound PC SAWKFRBJGLMMES-UHFFFAOYSA-N 0.000 abstract 1
- XVRBEHPXGQXDEH-UHFFFAOYSA-N methylphosphonoylmethanol Chemical group CP(=O)CO XVRBEHPXGQXDEH-UHFFFAOYSA-N 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000012454 non-polar solvent Substances 0.000 abstract 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical group P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 abstract 1
- 229920002866 paraformaldehyde Polymers 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- 239000003495 polar organic solvent Substances 0.000 abstract 1
- 239000002798 polar solvent Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5004—Acyclic saturated phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
- C07F9/5304—Acyclic saturated phosphine oxides or thioxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2413824A DE2413824C2 (de) | 1974-03-22 | 1974-03-22 | Verfahren zur Herstellung von tertiären (Hydroxymehtyl)-methylphosphinoxiden |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1493522A true GB1493522A (en) | 1977-11-30 |
Family
ID=5910836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB11927/75A Expired GB1493522A (en) | 1974-03-22 | 1975-03-21 | Production of tertiary(hydroxymethyl)-methylphosphine oxides |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4028421A (enExample) |
| JP (1) | JPS5327247B2 (enExample) |
| BE (1) | BE826973A (enExample) |
| CA (1) | CA1055962A (enExample) |
| CH (1) | CH610905A5 (enExample) |
| DE (1) | DE2413824C2 (enExample) |
| FR (1) | FR2329672A1 (enExample) |
| GB (1) | GB1493522A (enExample) |
| IT (1) | IT1032366B (enExample) |
| NL (1) | NL7503277A (enExample) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE564200A (enExample) * | 1957-01-23 | |||
| US3660495A (en) * | 1969-12-10 | 1972-05-02 | Hooker Chemical Corp | Process for preparing hydroxymethylated phosphines |
| US3732316A (en) * | 1970-11-12 | 1973-05-08 | Hooker Chemical Corp | Process for producing methyl phosphine oxides |
| US3928463A (en) * | 1973-11-16 | 1975-12-23 | Hoechst Ag | Process for the preparation of tertiary methyl-phosphine oxides |
-
1974
- 1974-03-22 DE DE2413824A patent/DE2413824C2/de not_active Expired
-
1975
- 1975-03-19 NL NL7503277A patent/NL7503277A/xx not_active Application Discontinuation
- 1975-03-20 IT IT48680/75A patent/IT1032366B/it active
- 1975-03-20 JP JP3422175A patent/JPS5327247B2/ja not_active Expired
- 1975-03-21 CA CA222,780A patent/CA1055962A/en not_active Expired
- 1975-03-21 BE BE154576A patent/BE826973A/xx not_active IP Right Cessation
- 1975-03-21 GB GB11927/75A patent/GB1493522A/en not_active Expired
- 1975-03-21 US US05/560,890 patent/US4028421A/en not_active Expired - Lifetime
- 1975-03-21 FR FR7508980A patent/FR2329672A1/fr active Granted
- 1975-03-21 CH CH367175A patent/CH610905A5/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FR2329672A1 (fr) | 1977-05-27 |
| NL7503277A (nl) | 1975-09-24 |
| CA1055962A (en) | 1979-06-05 |
| JPS5327247B2 (enExample) | 1978-08-07 |
| DE2413824C2 (de) | 1983-03-03 |
| IT1032366B (it) | 1979-05-30 |
| BE826973A (fr) | 1975-09-22 |
| CH610905A5 (enExample) | 1979-05-15 |
| JPS50131931A (enExample) | 1975-10-18 |
| US4028421A (en) | 1977-06-07 |
| FR2329672B1 (enExample) | 1980-02-22 |
| DE2413824A1 (de) | 1975-10-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES468325A1 (es) | Procedimiento para la obtencion de una mezcla de alcoholes polivalentes de bajo peso molecular | |
| Shimizu et al. | Highly selective ring opening of epoxides with silicon tetrafluoride: preparation of fluorohydrins | |
| Wang et al. | Regioselective synthesis of trimethylsilyl-substituted. alpha.-allenic alcohols via propargylic organoboranes | |
| GB1493522A (en) | Production of tertiary(hydroxymethyl)-methylphosphine oxides | |
| ATE193295T1 (de) | Verfahren zur herstellung von alkylpolyglykosiden | |
| US3953518A (en) | Process for preparing γ, δ-unsaturated carbonyl compounds | |
| US3145234A (en) | Organic phosphine derivatives and methods of preparating same | |
| Saigo et al. | THE TITANIUM TETRACHLORIDE-PROMOTED REACTION OF KETENE ALKYL TRIALKYLSILYL ACETALS WITH ACETALS OR AN ORTHOFORMATE | |
| GB1490122A (en) | Production of tertiary methylphosphine oxides | |
| GB1378446A (en) | Process for the manufacture of dicyanovinyl compounds | |
| Hart et al. | 1, 3-Bisdiazopropane. Preparation and cyclization to pyrazole | |
| US3116299A (en) | Preparation of substituted dioxepins | |
| US2882315A (en) | Production of organic phosphonyl halide | |
| Hoffman et al. | Furfuryl cationic capture processes. 5-Substituted. DELTA. 3, 4-2, 5-dihydro-2-methylenefurans and their rearrangement to furfuryl derivatives | |
| JPS5826838A (ja) | ３−ブロモ−４−フルオロベンズアルデヒドの製造方法 | |
| GB941495A (en) | Novel organophosphine oxides and process for their preparation | |
| ES8202536A1 (es) | Un procedimiento para preparar 2-halogeno-acetanilidas | |
| EP0104666B1 (en) | Production of formaldehyde | |
| US3131234A (en) | Preparation of tetraalkylallenes | |
| US3135786A (en) | Organoboron esters | |
| Fukuoka et al. | Formation of. alpha.,. beta.-diphenyl-. gamma.-butyrolactone from styrene oxide by the action of organo transition metal complexes | |
| US3968160A (en) | Preparation of 1,2,3-tris[1,2-bis(difluoramino)ethoxy]propane | |
| US4065511A (en) | Alcohol production | |
| GB1497623A (en) | Ar-octahalogen diphenyl ether-4,4'-dimethanols and a process for producing the same | |
| ES434650A2 (es) | Procedimiento para la preparacion de una sintesis quimica del oxa-1, oxo-2, diaza-3, 8, fenetil-8, spiro (4, 5) deca- no. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] |