GB1473035A - Catalyst and process for producing unsaturated carboxylic acid - Google Patents
Catalyst and process for producing unsaturated carboxylic acidInfo
- Publication number
- GB1473035A GB1473035A GB2344875A GB2344875A GB1473035A GB 1473035 A GB1473035 A GB 1473035A GB 2344875 A GB2344875 A GB 2344875A GB 2344875 A GB2344875 A GB 2344875A GB 1473035 A GB1473035 A GB 1473035A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- composition
- carboxylic acid
- unsaturated carboxylic
- producing unsaturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 229920000297 Rayon Polymers 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000002964 rayon Substances 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8871—Rare earth metals or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8877—Vanadium, tantalum, niobium or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP49062067A JPS5827255B2 (ja) | 1974-05-31 | 1974-05-31 | 不飽和脂肪酸の製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1473035A true GB1473035A (en) | 1977-05-11 |
Family
ID=13189375
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2344875A Expired GB1473035A (en) | 1974-05-31 | 1975-05-29 | Catalyst and process for producing unsaturated carboxylic acid |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5827255B2 (enrdf_load_stackoverflow) |
| DE (1) | DE2523757C3 (enrdf_load_stackoverflow) |
| FR (1) | FR2275436A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1473035A (enrdf_load_stackoverflow) |
| NL (1) | NL7506423A (enrdf_load_stackoverflow) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0005769A1 (en) * | 1978-05-31 | 1979-12-12 | Nippon Kayaku Kabushiki Kaisha | A process for producing methacrolein and methacrylic acid |
| US4409128A (en) | 1980-08-09 | 1983-10-11 | Basf Aktiengesellschaft | Oxidation catalyst, especially for the preparation of methacrylic acid by gas phase oxidation of methacrolein |
| EP0100057A1 (en) * | 1982-07-20 | 1984-02-08 | Mitsubishi Kasei Corporation | Process for producing methacrylic acid and/or methacrylic acid ester |
| EP0088328A3 (en) * | 1982-03-10 | 1984-05-30 | Basf Aktiengesellschaft | Oxidation catalyst, in particular for the preparation of methyacrylic acid by the vapour phase oxidation of methacrolein |
| US4467113A (en) * | 1978-12-13 | 1984-08-21 | Nippon Kayaku Kabushiki Kaisha | Process for producing methacrylic acid |
| US4595778A (en) * | 1983-03-11 | 1986-06-17 | Basf Aktiengesellschaft | Preparation of methacrylic acid and catalyst therefor |
| US4925823A (en) * | 1982-03-10 | 1990-05-15 | Basf Aktiengesellschaft | Process and catalyst for the preparation of methacrylic acid |
| US6930201B2 (en) * | 2000-12-25 | 2005-08-16 | Mitsubishi Rayon Co., Ltd. | Process for producing methacrylic acid |
| EP2261196A4 (en) * | 2008-04-09 | 2012-05-30 | Nippon Catalytic Chem Ind | PROCESS FOR THE PREPARATION OF ACROLEIN AND / OR ACRYLIC ACID |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51115414A (en) * | 1975-04-03 | 1976-10-12 | Mitsubishi Rayon Co Ltd | Process for preparation of unsaturated fatty acids |
| JPS5946934B2 (ja) * | 1976-02-09 | 1984-11-15 | 東ソー株式会社 | メタクリル酸の製法 |
| US4085065A (en) | 1976-10-19 | 1978-04-18 | The Standard Oil Company (Ohio) | Process for the preparation of unsaturated acids from unsaturated aldehydes |
| JPS5924140B2 (ja) * | 1977-10-31 | 1984-06-07 | 日本化薬株式会社 | メタクリル酸の製造法及び触媒 |
| NL7909142A (nl) * | 1978-12-26 | 1980-06-30 | Halcon Res & Dev | Katalysator en werkwijze voor de bereiding van methacrylzuur. |
| US4252682A (en) * | 1978-12-26 | 1981-02-24 | Halcon Research And Development Corp. | Catalyst for producing methacrylic acid |
| JPS55124734A (en) * | 1979-03-22 | 1980-09-26 | Nippon Kayaku Co Ltd | Preparation of methacrylic acid |
| CA1199905A (en) * | 1982-06-07 | 1986-01-28 | William J. Kennelly | Catalyst compositions and their use for the preparation of unsaturated carboxylic acids |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57297B2 (enrdf_load_stackoverflow) * | 1974-01-19 | 1982-01-06 |
-
1974
- 1974-05-31 JP JP49062067A patent/JPS5827255B2/ja not_active Expired
-
1975
- 1975-05-28 DE DE19752523757 patent/DE2523757C3/de not_active Expired
- 1975-05-29 FR FR7516803A patent/FR2275436A1/fr not_active Withdrawn
- 1975-05-29 GB GB2344875A patent/GB1473035A/en not_active Expired
- 1975-05-30 NL NL7506423A patent/NL7506423A/xx unknown
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0005769A1 (en) * | 1978-05-31 | 1979-12-12 | Nippon Kayaku Kabushiki Kaisha | A process for producing methacrolein and methacrylic acid |
| US4467113A (en) * | 1978-12-13 | 1984-08-21 | Nippon Kayaku Kabushiki Kaisha | Process for producing methacrylic acid |
| US4530916A (en) * | 1978-12-13 | 1985-07-23 | Nippon Kayaku Kabushiki Kaisha | Catalyst for use in a methacrylic acid process |
| US4409128A (en) | 1980-08-09 | 1983-10-11 | Basf Aktiengesellschaft | Oxidation catalyst, especially for the preparation of methacrylic acid by gas phase oxidation of methacrolein |
| EP0088328A3 (en) * | 1982-03-10 | 1984-05-30 | Basf Aktiengesellschaft | Oxidation catalyst, in particular for the preparation of methyacrylic acid by the vapour phase oxidation of methacrolein |
| US4489170A (en) * | 1982-03-10 | 1984-12-18 | Basf Aktiengesellschaft | Oxidation catalyst, especially for the preparation of methacrylic acid by gas phase oxidation of methacrolein |
| US4925823A (en) * | 1982-03-10 | 1990-05-15 | Basf Aktiengesellschaft | Process and catalyst for the preparation of methacrylic acid |
| EP0100057A1 (en) * | 1982-07-20 | 1984-02-08 | Mitsubishi Kasei Corporation | Process for producing methacrylic acid and/or methacrylic acid ester |
| US4595778A (en) * | 1983-03-11 | 1986-06-17 | Basf Aktiengesellschaft | Preparation of methacrylic acid and catalyst therefor |
| US6930201B2 (en) * | 2000-12-25 | 2005-08-16 | Mitsubishi Rayon Co., Ltd. | Process for producing methacrylic acid |
| EP2261196A4 (en) * | 2008-04-09 | 2012-05-30 | Nippon Catalytic Chem Ind | PROCESS FOR THE PREPARATION OF ACROLEIN AND / OR ACRYLIC ACID |
| US8415498B2 (en) | 2008-04-09 | 2013-04-09 | Nippon Shokubai Co., Ltd. | Process for producing acrolein and/or acrylic acid |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7506423A (nl) | 1975-12-02 |
| JPS5827255B2 (ja) | 1983-06-08 |
| DE2523757A1 (de) | 1976-01-15 |
| FR2275436A1 (fr) | 1976-01-16 |
| DE2523757C3 (de) | 1979-01-04 |
| DE2523757B2 (de) | 1978-05-03 |
| JPS50151816A (enrdf_load_stackoverflow) | 1975-12-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19950528 |