GB1473024A - Process for the continuous preparation of trimethylol-alkane allyl ethers - Google Patents
Process for the continuous preparation of trimethylol-alkane allyl ethersInfo
- Publication number
- GB1473024A GB1473024A GB3269075A GB3269075A GB1473024A GB 1473024 A GB1473024 A GB 1473024A GB 3269075 A GB3269075 A GB 3269075A GB 3269075 A GB3269075 A GB 3269075A GB 1473024 A GB1473024 A GB 1473024A
- Authority
- GB
- United Kingdom
- Prior art keywords
- trimethylolalkane
- sodium hydroxide
- allyl chloride
- ethers
- aug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1473024 Trimethylolalkane ethers BAYER AG 5 Aug 1975 [6 Aug 1974] 32690/75 Heading C2C Allyl ethers of the formula where X is 0 or 1 and n is 1, 2, or 3, are produced by the continuous etherification of a trimethylolalkane with allyl chloride under an inert atmosphere in the presence of an aqueous sodium hydroxide solution; the method comprises initially introducing the ether to be produced into at least two reaction chambers arranged in series, and introducing continuously, whilst stirring, the trimethylolalkane, 1À05-1À3 moles sodium hydroxide in a 40-50% aqueous solution and 1À0-1À2 moles of allyl chloride per mole of hydroxyl group to be etherified, to produce such concentrations that sodium salts of the trimethylolalkane do not precipitate, keeping the system at 80-130‹ C., and introducing continuously 0À5-1À7 parts by weight toluene relative to 1 part by weight of the sodium hydroxide, whilst azeotropically distilling off the water, to give a conversion of trimethylolalkane exceeding 99%. The process may be carried out in a stirred kettle cascade, the starting materials being fed to the first reaction chamber; part of the allyl chloride may be fed to the second chamber. The products may be used for the preparation of air-drying synthetic resins.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742437789 DE2437789C3 (en) | 1974-08-06 | 1974-08-06 | Process for the continuous production of trimethylolalkane allyl ethers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1473024A true GB1473024A (en) | 1977-05-11 |
Family
ID=5922553
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3269075A Expired GB1473024A (en) | 1974-08-06 | 1975-08-05 | Process for the continuous preparation of trimethylol-alkane allyl ethers |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS5141313A (en) |
| AT (1) | ATA602575A (en) |
| BE (1) | BE832086A (en) |
| CA (1) | CA1059153A (en) |
| DE (1) | DE2437789C3 (en) |
| FR (1) | FR2281348A1 (en) |
| GB (1) | GB1473024A (en) |
| IT (1) | IT1041128B (en) |
| NL (1) | NL7509370A (en) |
| SE (1) | SE7508823L (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4374282A (en) | 1979-10-15 | 1983-02-15 | Elf France | Ethers of polyols, their preparation and use |
| WO2000018713A1 (en) * | 1998-09-30 | 2000-04-06 | Perstorp Ab | Method in recovery of trimethylolpropane triallyl or diallyl ether |
| CN102040486A (en) * | 2010-11-24 | 2011-05-04 | 山东省化工研究院 | Preparation method of trimethylolpropane diallyl ether |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60231625A (en) * | 1984-05-02 | 1985-11-18 | Nippon Shokubai Kagaku Kogyo Co Ltd | Production of allyl ether of trimethylolpropane |
| JPS60233026A (en) * | 1984-05-02 | 1985-11-19 | Nippon Shokubai Kagaku Kogyo Co Ltd | Preparation of trimethylolpropane allyl ether |
| JPS60252440A (en) * | 1984-05-29 | 1985-12-13 | Nippon Shokubai Kagaku Kogyo Co Ltd | Production of trimethylolpropane diallyl ether |
| CN1052970C (en) * | 1996-06-04 | 2000-05-31 | 中国石化齐鲁石油化工公司 | Preparation method of polyol allyl ether |
| WO2003104177A1 (en) * | 2002-06-07 | 2003-12-18 | ダイソー株式会社 | Process for producing allyl ether |
-
1974
- 1974-08-06 DE DE19742437789 patent/DE2437789C3/en not_active Expired
-
1975
- 1975-08-01 CA CA232,724A patent/CA1059153A/en not_active Expired
- 1975-08-04 JP JP9428575A patent/JPS5141313A/en active Pending
- 1975-08-04 AT AT602575A patent/ATA602575A/en not_active Application Discontinuation
- 1975-08-04 IT IT5080075A patent/IT1041128B/en active
- 1975-08-04 BE BE158911A patent/BE832086A/en unknown
- 1975-08-05 GB GB3269075A patent/GB1473024A/en not_active Expired
- 1975-08-05 SE SE7508823A patent/SE7508823L/en not_active Application Discontinuation
- 1975-08-06 NL NL7509370A patent/NL7509370A/en not_active Application Discontinuation
- 1975-08-06 FR FR7524557A patent/FR2281348A1/en active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4374282A (en) | 1979-10-15 | 1983-02-15 | Elf France | Ethers of polyols, their preparation and use |
| WO2000018713A1 (en) * | 1998-09-30 | 2000-04-06 | Perstorp Ab | Method in recovery of trimethylolpropane triallyl or diallyl ether |
| CN102040486A (en) * | 2010-11-24 | 2011-05-04 | 山东省化工研究院 | Preparation method of trimethylolpropane diallyl ether |
| CN102040486B (en) * | 2010-11-24 | 2013-03-13 | 山东省化工研究院 | Preparation method of trimethylolpropane diallyl ether |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7509370A (en) | 1976-02-10 |
| JPS5141313A (en) | 1976-04-07 |
| CA1059153A (en) | 1979-07-24 |
| IT1041128B (en) | 1980-01-10 |
| BE832086A (en) | 1976-02-04 |
| DE2437789B2 (en) | 1979-06-21 |
| DE2437789A1 (en) | 1976-02-19 |
| FR2281348B1 (en) | 1979-01-05 |
| ATA602575A (en) | 1977-04-15 |
| SE7508823L (en) | 1976-02-09 |
| DE2437789C3 (en) | 1980-03-20 |
| FR2281348A1 (en) | 1976-03-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |