GB1469896A - Process for the manufacture of a hydroxytetramethyl-butylbenzene - Google Patents
Process for the manufacture of a hydroxytetramethyl-butylbenzeneInfo
- Publication number
- GB1469896A GB1469896A GB3955975A GB3955975A GB1469896A GB 1469896 A GB1469896 A GB 1469896A GB 3955975 A GB3955975 A GB 3955975A GB 3955975 A GB3955975 A GB 3955975A GB 1469896 A GB1469896 A GB 1469896A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphuric acid
- manufacture
- trimethylpentene
- diisobutylene
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1469896 Preparation of hydroxytetramethylbutylbenzene CIBA GEIGY AG 26 Sept 1975 [9 Oct 1974] 39559/75 Heading C2C The invention comprises a process for the manufacture of a hydroxy-(1,1,3,3-tetramethylbutyl)-benzene by reacting the corresponding hydroxybenzene with 2,4,4-trimethylpentene in the presence of a hydroxyalkyl compound and using highly concentrated sulphuric acid (as hereinafter defined) as the catalyst, characterized in that the reaction is carried out in the presence of ethylene glycol. By highly concentrated sulphuric acid is meant a sulphuric acid which contains 90 to 98% by weight of H 2 SO 4 , the remainder consisting essentially of water. It is possible to use as the 2,4,4-trimethylpentene either of the two isomers, that is to say α-diisobutylene of the formula or #-diisobutylene of the formula or, usually particularly advantageously, a mixture of the two. The ratio of ethylene glycol to sulphuric acid, in parts by volume, which is used for the reaction is advantageously 1 : 2 to 2 : 1.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1356874A CH594582A5 (en) | 1974-10-09 | 1974-10-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1469896A true GB1469896A (en) | 1977-04-06 |
Family
ID=4393523
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3955975A Expired GB1469896A (en) | 1974-10-09 | 1975-09-26 | Process for the manufacture of a hydroxytetramethyl-butylbenzene |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS5163135A (en) |
CH (1) | CH594582A5 (en) |
DE (1) | DE2544904A1 (en) |
GB (1) | GB1469896A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2740449A1 (en) * | 1995-10-31 | 1997-04-30 | Rhone Poulenc Chimie | PROCESS FOR C-ALKYLATION OF HYDROXYLIC AROMATIC COMPOUNDS |
US6255538B1 (en) | 2000-01-05 | 2001-07-03 | Eastman Chemical Company | Process for the C-alkylation of aromatic hydroxyl compounds |
-
1974
- 1974-10-09 CH CH1356874A patent/CH594582A5/xx not_active IP Right Cessation
-
1975
- 1975-09-26 GB GB3955975A patent/GB1469896A/en not_active Expired
- 1975-10-07 DE DE19752544904 patent/DE2544904A1/en not_active Withdrawn
- 1975-10-09 JP JP12141675A patent/JPS5163135A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2740449A1 (en) * | 1995-10-31 | 1997-04-30 | Rhone Poulenc Chimie | PROCESS FOR C-ALKYLATION OF HYDROXYLIC AROMATIC COMPOUNDS |
WO1997016402A1 (en) * | 1995-10-31 | 1997-05-09 | Rhodia Chimie | Method for c-alkylating hydroxylated aromatic compounds |
US6049015A (en) * | 1995-10-31 | 2000-04-11 | Rhodia Chimie | Method for C-alkylating hydroxylated aromatic compounds |
US6255538B1 (en) | 2000-01-05 | 2001-07-03 | Eastman Chemical Company | Process for the C-alkylation of aromatic hydroxyl compounds |
Also Published As
Publication number | Publication date |
---|---|
CH594582A5 (en) | 1978-01-13 |
DE2544904A1 (en) | 1976-04-22 |
JPS5163135A (en) | 1976-06-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1510043A (en) | Selective nitration of aromatic and substituted aromatic compounds | |
GB1469896A (en) | Process for the manufacture of a hydroxytetramethyl-butylbenzene | |
GB1468647A (en) | Process for the preparation of 2-nitro-4,6-dichloro-5-methyl phenol | |
GB1392337A (en) | Process for the production of hydroxylamino-and aminoanthra- quinones | |
GB1381730A (en) | Process for the industrial manufacture of dinitrostilbene disulphonic acid | |
GB1496277A (en) | Chlorinated polycyclic amines and their use as insecticides | |
GB1184576A (en) | Process for the Production of 1,2-Dichloroethane. | |
GB1505922A (en) | Manufacture of beta-bromoalkylsulphones and beta-bromoalkenylsulphones | |
ES423366A1 (en) | Production of N,N-dichloro-terephthalamide and N,N-dichloro-isophthalamide | |
ES287874A1 (en) | Process for making cyclohexanoneoxime | |
GB1345645A (en) | Diamido amino sulphonates and preparation thereof | |
GB1202447A (en) | Process for the manufacture of nitrosyl chloride | |
GB1329382A (en) | Aromatic diamines and a process for the production thereof | |
FR2397832A1 (en) | DEODORIZER CONTAINING VINYL ETHER | |
GB1198575A (en) | Aminoaphthalene Sulphonic Acids. | |
GB1351453A (en) | Preparation of 4,4-dichlorodiphenyl sulphone | |
GB1323657A (en) | Process for the preparation of dinitrodiphenyl ethers | |
GB1384840A (en) | Process for preparing bisphenol-a | |
GB998686A (en) | Production of acyclic acetone peroxides | |
GB971591A (en) | Process for the manufacture of pseudocumene-5-carboxylic acid | |
GB1210780A (en) | A method of preparing a bis(2 hydroxyethyl) ester of an alkali metal salt of 3,5-dicarboxy-benzene sulphuric acid | |
GB1475556A (en) | Flame-retardant polyurethane resin compositions | |
ES8406428A1 (en) | Process for the preparation of aryloxybenzoic acids containing a sulfonamide group | |
GB1294153A (en) | Process for the preparation of 4-bromo-2,5-dichlorophenol | |
GB1420191A (en) | Purification of anthraquinone suophonic acids |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |