GB1461831A - Process for the production of butanediol - Google Patents

Process for the production of butanediol

Info

Publication number
GB1461831A
GB1461831A GB1166274A GB1166274A GB1461831A GB 1461831 A GB1461831 A GB 1461831A GB 1166274 A GB1166274 A GB 1166274A GB 1166274 A GB1166274 A GB 1166274A GB 1461831 A GB1461831 A GB 1461831A
Authority
GB
United Kingdom
Prior art keywords
butanediol
alkanoyloxybutyraldehyde
diols
acid
alkanoic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1166274A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Publication of GB1461831A publication Critical patent/GB1461831A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/29—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by introduction of oxygen-containing functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1461831 1,4-Butanediol GENERAL ELECTRIC CO 15 March 1974 [30 May 1973] 11662/74 Heading C2C 1,4-Butanediol is made by reacting propylene, oxygen and a C 1-6 alkanoic acid in the presence of Pd, Ru, Rh, Pt, Os, Ir or their salts or oxides, or mixtures thereof, at an elevated temperature; hydroformylating the resulting allyl alkanoate; hydrogenating the formed mixture of 4-alkanoyloxybutyraldehyde, 3-alkanoyloxy-2-methylpropionaldehyde, and 2-alkanoyloxybutyraldehyde to the corresponding alcohols; hydrolysing the latter to give the corresponding diols and the alkanoic acid; separating the diols from the acid and recycling the latter.
GB1166274A 1973-05-30 1974-03-15 Process for the production of butanediol Expired GB1461831A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US36522873A 1973-05-30 1973-05-30

Publications (1)

Publication Number Publication Date
GB1461831A true GB1461831A (en) 1977-01-19

Family

ID=23438002

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1166274A Expired GB1461831A (en) 1973-05-30 1974-03-15 Process for the production of butanediol

Country Status (7)

Country Link
JP (1) JPS5030809A (en)
BR (1) BR7404405D0 (en)
DE (1) DE2425653A1 (en)
FR (1) FR2231645B1 (en)
GB (1) GB1461831A (en)
IT (1) IT1012955B (en)
NL (1) NL7407237A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018164B1 (en) * 1979-04-11 1984-07-11 DAVY McKEE (LONDON) LIMITED Production of tetrahydrofuran
US8124805B2 (en) 2009-11-25 2012-02-28 Lyondell Chemical Technology, L.P. Allyl acetate hydroformylation process

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5621221B2 (en) * 1975-02-19 1981-05-18
CN114522735B (en) * 2020-11-23 2023-10-20 中国科学院大连化学物理研究所 Solid catalyst for hydroformylation of vinyl ester compounds and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018164B1 (en) * 1979-04-11 1984-07-11 DAVY McKEE (LONDON) LIMITED Production of tetrahydrofuran
US8124805B2 (en) 2009-11-25 2012-02-28 Lyondell Chemical Technology, L.P. Allyl acetate hydroformylation process

Also Published As

Publication number Publication date
BR7404405D0 (en) 1975-09-30
AU6952274A (en) 1975-12-04
FR2231645A1 (en) 1974-12-27
DE2425653A1 (en) 1974-12-19
IT1012955B (en) 1977-03-10
JPS5030809A (en) 1975-03-27
NL7407237A (en) 1974-12-03
FR2231645B1 (en) 1980-08-01

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee