JPS5030809A - - Google Patents
Info
- Publication number
- JPS5030809A JPS5030809A JP5984174A JP5984174A JPS5030809A JP S5030809 A JPS5030809 A JP S5030809A JP 5984174 A JP5984174 A JP 5984174A JP 5984174 A JP5984174 A JP 5984174A JP S5030809 A JPS5030809 A JP S5030809A
- Authority
- JP
- Japan
- Prior art keywords
- alkanoyloxybutyraldehyde
- butanediol
- diols
- acid
- alkanoic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 3
- 150000002009 diols Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/29—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by introduction of oxygen-containing functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1461831 1,4-Butanediol GENERAL ELECTRIC CO 15 March 1974 [30 May 1973] 11662/74 Heading C2C 1,4-Butanediol is made by reacting propylene, oxygen and a C 1-6 alkanoic acid in the presence of Pd, Ru, Rh, Pt, Os, Ir or their salts or oxides, or mixtures thereof, at an elevated temperature; hydroformylating the resulting allyl alkanoate; hydrogenating the formed mixture of 4-alkanoyloxybutyraldehyde, 3-alkanoyloxy-2-methylpropionaldehyde, and 2-alkanoyloxybutyraldehyde to the corresponding alcohols; hydrolysing the latter to give the corresponding diols and the alkanoic acid; separating the diols from the acid and recycling the latter.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36522873A | 1973-05-30 | 1973-05-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5030809A true JPS5030809A (en) | 1975-03-27 |
Family
ID=23438002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5984174A Pending JPS5030809A (en) | 1973-05-30 | 1974-05-29 |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5030809A (en) |
| BR (1) | BR7404405D0 (en) |
| DE (1) | DE2425653A1 (en) |
| FR (1) | FR2231645B1 (en) |
| GB (1) | GB1461831A (en) |
| IT (1) | IT1012955B (en) |
| NL (1) | NL7407237A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5195251A (en) * | 1975-02-19 | 1976-08-20 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0018164B1 (en) * | 1979-04-11 | 1984-07-11 | DAVY McKEE (LONDON) LIMITED | Production of tetrahydrofuran |
| US8124805B2 (en) | 2009-11-25 | 2012-02-28 | Lyondell Chemical Technology, L.P. | Allyl acetate hydroformylation process |
| CN114522738B (en) * | 2020-11-23 | 2023-10-03 | 中国科学院大连化学物理研究所 | Method for preparing 1, 3-propylene glycol by one-step hydrogenation of 3-acetoxy propionaldehyde |
-
1974
- 1974-03-15 GB GB1166274A patent/GB1461831A/en not_active Expired
- 1974-05-28 DE DE19742425653 patent/DE2425653A1/en not_active Withdrawn
- 1974-05-29 FR FR7418579A patent/FR2231645B1/fr not_active Expired
- 1974-05-29 NL NL7407237A patent/NL7407237A/xx not_active Application Discontinuation
- 1974-05-29 JP JP5984174A patent/JPS5030809A/ja active Pending
- 1974-05-30 IT IT2334874A patent/IT1012955B/en active
- 1974-05-30 BR BR440574A patent/BR7404405D0/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5195251A (en) * | 1975-02-19 | 1976-08-20 |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7407237A (en) | 1974-12-03 |
| GB1461831A (en) | 1977-01-19 |
| IT1012955B (en) | 1977-03-10 |
| FR2231645B1 (en) | 1980-08-01 |
| DE2425653A1 (en) | 1974-12-19 |
| AU6952274A (en) | 1975-12-04 |
| BR7404405D0 (en) | 1975-09-30 |
| FR2231645A1 (en) | 1974-12-27 |
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