GB1456827A - Chromane derivatives - Google Patents
Chromane derivativesInfo
- Publication number
- GB1456827A GB1456827A GB5929673A GB5929673A GB1456827A GB 1456827 A GB1456827 A GB 1456827A GB 5929673 A GB5929673 A GB 5929673A GB 5929673 A GB5929673 A GB 5929673A GB 1456827 A GB1456827 A GB 1456827A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydroxyl
- hydrolysis
- converted
- preparation
- chromane derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0021—Preserving by using additives, e.g. anti-oxidants containing oxygen
- C11B5/0035—Phenols; Their halogenated and aminated derivates, their salts, their esters with carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/16—Preparation of halogenated hydrocarbons by replacement by halogens of hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/42—Unsaturated compounds containing hydroxy or O-metal groups
- C07C59/52—Unsaturated compounds containing hydroxy or O-metal groups a hydroxy or O-metal group being bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
- C07D311/70—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with two hydrocarbon radicals attached in position 2 and elements other than carbon and hydrogen in position 6
- C07D311/72—3,4-Dihydro derivatives having in position 2 at least one methyl radical and in position 6 one oxygen atom, e.g. tocopherols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
- C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
Abstract
The preparation of chroman aldehydes of the formula <IMAGE> in which R represents hydroxyl, an ether group which can be converted to hydroxyl by hydrolysis or hydrogenolysis or an ester group which can be converted to hydroxyl by hydrolysis, is described. These compounds are useful intermediates for the preparation of natural optically active alpha -tocopherol and its isomers.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US31756672A | 1972-12-22 | 1972-12-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1456827A true GB1456827A (en) | 1976-11-24 |
Family
ID=23234257
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2227175A Expired GB1456829A (en) | 1972-12-22 | 1973-12-21 | Chromane derivatives |
GB5929873A Expired GB1456828A (en) | 1972-12-22 | 1973-12-21 | Chromane derivatives |
GB2227275A Expired GB1456830A (en) | 1972-12-22 | 1973-12-21 | Substituted undecanes |
GB5929673A Expired GB1456827A (en) | 1972-12-22 | 1973-12-21 | Chromane derivatives |
Family Applications Before (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2227175A Expired GB1456829A (en) | 1972-12-22 | 1973-12-21 | Chromane derivatives |
GB5929873A Expired GB1456828A (en) | 1972-12-22 | 1973-12-21 | Chromane derivatives |
GB2227275A Expired GB1456830A (en) | 1972-12-22 | 1973-12-21 | Substituted undecanes |
Country Status (21)
Country | Link |
---|---|
JP (3) | JPS5946233B2 (en) |
KR (1) | KR780000008B1 (en) |
AR (1) | AR200751A1 (en) |
AT (1) | AT333755B (en) |
BE (2) | BE808942A (en) |
CA (1) | CA1022562A (en) |
CH (3) | CH603617A5 (en) |
DD (1) | DD109624A5 (en) |
DE (2) | DE2364165A1 (en) |
ES (1) | ES421683A1 (en) |
FR (2) | FR2255299B1 (en) |
GB (4) | GB1456829A (en) |
HU (1) | HU168043B (en) |
IE (1) | IE38671B1 (en) |
IL (1) | IL43888A (en) |
LU (1) | LU69067A1 (en) |
NL (2) | NL178968C (en) |
PH (1) | PH11133A (en) |
SE (1) | SE406912B (en) |
SU (1) | SU518135A3 (en) |
ZA (1) | ZA739471B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002012221A1 (en) * | 2000-08-03 | 2002-02-14 | Kuraray Co., Ltd. | Method for optical resolution of (±)-6-hydroxy-2,5,7,8-tetramethylcoumarone-2-carboxylic acid |
CN115066420A (en) * | 2020-02-21 | 2022-09-16 | 住友制药株式会社 | Optically resolved Trolox intermediates and process for producing the same |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH618695A5 (en) * | 1975-01-27 | 1980-08-15 | Hoffmann La Roche | Process for the preparation of chromane derivatives |
DE2820861A1 (en) * | 1977-05-16 | 1978-11-23 | Hoffmann La Roche | CHROME DERIVATIVES |
US4150050A (en) * | 1978-01-30 | 1979-04-17 | Hoffmann-La Roche Inc. | 3,6-Dioxo-1,4-cyclohexadien-1-yl-butandate esters |
EP0003484B1 (en) * | 1978-01-30 | 1981-10-14 | F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft | Process for the preparation of chromane derivatives |
DE2909601A1 (en) * | 1979-03-12 | 1980-09-25 | Basf Ag | METHOD FOR PRODUCING CHROME DERIVATIVES |
DE3010505A1 (en) * | 1980-03-19 | 1981-10-01 | Basf Ag, 6700 Ludwigshafen | CHROME DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF, THEIR USE AS STABILIZERS OF ORGANIC MATERIALS AND ORGANIC MATERIALS CONTAINING THESE STABILIZERS |
DE3010504A1 (en) * | 1980-03-19 | 1981-10-01 | Basf Ag, 6700 Ludwigshafen | METHOD FOR THE PRODUCTION OF 2-HYDROXYALKYLCHROMANS |
DE3103740A1 (en) | 1981-02-04 | 1982-08-19 | Basf Ag, 6700 Ludwigshafen | CHROME DERIVATIVES |
DE3103707A1 (en) * | 1981-02-04 | 1982-08-19 | Basf Ag, 6700 Ludwigshafen | CHROME DERIVATIVES |
JPS57136582A (en) * | 1981-02-19 | 1982-08-23 | Eisai Co Ltd | Preparation of optically active alpha-tocopherol |
JPS57145871A (en) * | 1981-03-05 | 1982-09-09 | Eisai Co Ltd | Chromanolcarboxylic derivative |
DE3139238A1 (en) * | 1981-10-02 | 1983-04-21 | Basf Ag, 6700 Ludwigshafen | OPTICALLY ACTIVE COMPONENTS FOR THE SYNTHESIS OF THE SIDE CHAIN OF (R, R, R) - (ALPHA) -TOCOPHEROL AND METHOD FOR THE PRODUCTION THEREOF |
EP0115142B1 (en) * | 1982-12-23 | 1986-11-05 | Ici Americas Inc. | Chroman compounds |
ZA844519B (en) * | 1983-06-24 | 1985-02-27 | Hoffmann La Roche | Dihydrobenzopyran derivatives |
EP0235510B1 (en) * | 1986-01-23 | 1989-03-08 | F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft | 3,4-dihydro-2,5,7,8-tetramethyl-2h-1-benzopyran derivatives and processes for their preparation |
US4987231A (en) * | 1989-08-04 | 1991-01-22 | Pfizer Inc. | Optical resolution method for 3R-(3-carboxybenzyl)-6-(5-fluoro-2-benzothiazolyl)methoxy-4R-chromanol |
CA2082004A1 (en) * | 1991-11-20 | 1993-05-21 | David Laffan | Substituted pentaalkylchromans |
DE19859251A1 (en) * | 1998-12-22 | 2000-06-29 | Basf Ag | Process for the preparation of substituted chroman derivatives |
WO2005073212A1 (en) * | 2004-01-30 | 2005-08-11 | Mitsubishi Gas Chemical Company, Inc. | Process for producing chroman compound |
KR101233223B1 (en) * | 2004-12-21 | 2013-02-14 | 제이엔씨 석유 화학 주식회사 | Liquid crystal compound having a chroman ring, liquid crystal composition, and liquid crystal display device comprising the liquid crystal composition |
EP2522647B1 (en) * | 2011-05-10 | 2014-04-30 | DSM IP Assets B.V. | Process of separating chiral isomers of chroman compounds and their derivatives and precursors |
NL2010010C2 (en) | 2012-12-19 | 2014-06-23 | Sulfateq B V | Compounds for protection of cells. |
-
1973
- 1973-12-13 ZA ZA739471*A patent/ZA739471B/en unknown
- 1973-12-19 CH CH1777173A patent/CH603617A5/xx not_active IP Right Cessation
- 1973-12-19 CH CH1777073A patent/CH605892A5/xx not_active IP Right Cessation
- 1973-12-20 DD DD175557A patent/DD109624A5/xx unknown
- 1973-12-20 PH PH15347A patent/PH11133A/en unknown
- 1973-12-21 GB GB2227175A patent/GB1456829A/en not_active Expired
- 1973-12-21 BE BE139128A patent/BE808942A/en unknown
- 1973-12-21 NL NLAANVRAGE7317590,A patent/NL178968C/en not_active IP Right Cessation
- 1973-12-21 SU SU1978253A patent/SU518135A3/en active
- 1973-12-21 JP JP48142527A patent/JPS5946233B2/en not_active Expired
- 1973-12-21 AR AR251651A patent/AR200751A1/en active
- 1973-12-21 GB GB5929873A patent/GB1456828A/en not_active Expired
- 1973-12-21 BE BE139129A patent/BE808943A/en not_active IP Right Cessation
- 1973-12-21 LU LU69067A patent/LU69067A1/xx unknown
- 1973-12-21 DE DE2364165A patent/DE2364165A1/en not_active Ceased
- 1973-12-21 DE DE2364141A patent/DE2364141A1/en not_active Ceased
- 1973-12-21 SE SE7317421A patent/SE406912B/en unknown
- 1973-12-21 AT AT1076973A patent/AT333755B/en not_active IP Right Cessation
- 1973-12-21 GB GB2227275A patent/GB1456830A/en not_active Expired
- 1973-12-21 GB GB5929673A patent/GB1456827A/en not_active Expired
- 1973-12-21 JP JP48142526A patent/JPS4988876A/ja active Pending
- 1973-12-21 IE IE2317/73A patent/IE38671B1/en unknown
- 1973-12-21 CA CA188,762A patent/CA1022562A/en not_active Expired
- 1973-12-21 IL IL43888A patent/IL43888A/en unknown
- 1973-12-21 NL NL7317587A patent/NL7317587A/xx not_active Application Discontinuation
- 1973-12-21 FR FR7346001A patent/FR2255299B1/fr not_active Expired
- 1973-12-21 FR FR7346000A patent/FR2284604A1/en active Granted
- 1973-12-21 ES ES421683A patent/ES421683A1/en not_active Expired
- 1973-12-21 HU HUHO1637A patent/HU168043B/hu unknown
- 1973-12-22 KR KR7302219A patent/KR780000008B1/en active
-
1976
- 1976-11-19 CH CH1457976A patent/CH622257A5/en not_active IP Right Cessation
-
1984
- 1984-01-18 JP JP59005854A patent/JPS6026795B2/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002012221A1 (en) * | 2000-08-03 | 2002-02-14 | Kuraray Co., Ltd. | Method for optical resolution of (±)-6-hydroxy-2,5,7,8-tetramethylcoumarone-2-carboxylic acid |
CN115066420A (en) * | 2020-02-21 | 2022-09-16 | 住友制药株式会社 | Optically resolved Trolox intermediates and process for producing the same |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |