GB867166A - A process for the manufacture of alpha tocopherol and its acetate - Google Patents
A process for the manufacture of alpha tocopherol and its acetateInfo
- Publication number
- GB867166A GB867166A GB35278/59A GB3527859A GB867166A GB 867166 A GB867166 A GB 867166A GB 35278/59 A GB35278/59 A GB 35278/59A GB 3527859 A GB3527859 A GB 3527859A GB 867166 A GB867166 A GB 867166A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetate
- manufacture
- alpha tocopherol
- tocopherol
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
- C07D311/70—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with two hydrocarbon radicals attached in position 2 and elements other than carbon and hydrogen in position 6
- C07D311/72—3,4-Dihydro derivatives having in position 2 at least one methyl radical and in position 6 one oxygen atom, e.g. tocopherols
Abstract
Alpha-tocopherol is synthesised by condensing trimethylhydroquinone with isophytol in presence of a BF3 condensing agent (which may be a BF3 di-lower alkyl, e.g. Et, etherate); optionally the product is converted to the acetate using acetic anhydride. An example is given.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US867166XA | 1958-10-24 | 1958-10-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB867166A true GB867166A (en) | 1961-05-03 |
Family
ID=22200406
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB35278/59A Expired GB867166A (en) | 1958-10-24 | 1959-10-19 | A process for the manufacture of alpha tocopherol and its acetate |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB867166A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7858813B2 (en) | 2004-08-19 | 2010-12-28 | Dsm Ip Assets B.V. | Process for the rectification of mixtures of high-boiling air-and/or temperature-sensitive useful products |
US8183396B2 (en) * | 2004-08-19 | 2012-05-22 | Dsm Ip Assets B.V. | Process for the working-up of a vitamin E- and vitamin E-acetate- containing mixture or products stream |
-
1959
- 1959-10-19 GB GB35278/59A patent/GB867166A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7858813B2 (en) | 2004-08-19 | 2010-12-28 | Dsm Ip Assets B.V. | Process for the rectification of mixtures of high-boiling air-and/or temperature-sensitive useful products |
US8183396B2 (en) * | 2004-08-19 | 2012-05-22 | Dsm Ip Assets B.V. | Process for the working-up of a vitamin E- and vitamin E-acetate- containing mixture or products stream |
US8414850B2 (en) | 2004-08-19 | 2013-04-09 | Dsm Ip Assets B.V. | Process for the working-up of a vitamin E- and vitamin E-acetate-containing mixture or product stream |
US8420838B2 (en) | 2004-08-19 | 2013-04-16 | Dsm Ip Assets B.V. | Process for the rectification of mixtures of high-boiling air- and/or temperature-sensitive useful products |
US8747621B2 (en) | 2004-08-19 | 2014-06-10 | Dsm Ip Assets B.V. | Process for the rectification of mixtures of high-boiling air- and/or temperature-sensitive useful products |
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