GB1446522A - Production of aromatic compounds measuring apparatus for machine tool systm - Google Patents

Production of aromatic compounds measuring apparatus for machine tool systm

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Publication number
GB1446522A
GB1446522A GB3517774A GB3517774A GB1446522A GB 1446522 A GB1446522 A GB 1446522A GB 3517774 A GB3517774 A GB 3517774A GB 3517774 A GB3517774 A GB 3517774A GB 1446522 A GB1446522 A GB 1446522A
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GB
United Kingdom
Prior art keywords
zsm
oil
aug
systm
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3517774A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US387218A external-priority patent/US3894103A/en
Priority claimed from US387224A external-priority patent/US3907915A/en
Priority claimed from US387221A external-priority patent/US3894105A/en
Priority claimed from US387222A external-priority patent/US3894106A/en
Priority claimed from US387223A external-priority patent/US3894107A/en
Priority claimed from US387219A external-priority patent/US3894104A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1446522A publication Critical patent/GB1446522A/en
Expired legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46Iron group metals or copper
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/322Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a sulfur atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/323Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a nitrogen atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/48Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/26After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/36Steaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44Noble metals
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/46Iron group metals or copper
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1022Fischer-Tropsch products
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products
    • C10G2300/305Octane number, e.g. motor octane number [MON], research octane number [RON]
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006Temperature
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10G2300/4012Pressure
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    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018Spatial velocity, e.g. LHSV, WHSV
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    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline
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    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30Aromatics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1446522 Aromatic hydrocarbons MOBIL OIL CORP 9 Aug 1974 [9 Aug 1973 (7)] 35177/74 Heading C5E A feed comprising aliphatic oxygen-containing organic compounds is transformed into a product comprising aromatic hydrocarbons by contact at 0-3000 p.s.i.g. at a temperature of at least 500‹ F. with a crystalline aluminosilicate zeolite having a SiO 2 : Al 2 O 3 ratio of at least 12 and a constraint index (defined) of 1 to 12. The feed may comprise an alcohol, ether or ketone or a plurality of oxygen-containing compounds obtained by conversion synthesis gas which is itself obtained from a fossil fuel such as coal, shale oil or oil from tar sands. Suitable zeolites are ferrocrite, brevosterite, stillbite, dachiardite, epistilbite, henlandite, clinoptilolite, ZSM-5 type ZSM-12, ZSM-21 or tetraethylammonium nordenite. The zeolite may be subjected to base exchange with cations of metals of Groups Ib, IIa, IIb, IIIa, IIIb, IVa, IVb or VIII.
GB3517774A 1973-08-09 1974-08-09 Production of aromatic compounds measuring apparatus for machine tool systm Expired GB1446522A (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US38722073A 1973-08-09 1973-08-09
US387218A US3894103A (en) 1973-08-09 1973-08-09 Aromatization reactions
US387224A US3907915A (en) 1973-08-09 1973-08-09 Conversion of carbonyl compounds to aromatics
US387221A US3894105A (en) 1973-08-09 1973-08-09 Production of durene
US387222A US3894106A (en) 1973-08-09 1973-08-09 Conversion of ethers
US387223A US3894107A (en) 1973-08-09 1973-08-09 Conversion of alcohols, mercaptans, sulfides, halides and/or amines
US387219A US3894104A (en) 1973-08-09 1973-08-09 Aromatization of hetero-atom substituted hydrocarbons

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EP0005287A1 (en) * 1978-04-21 1979-11-14 Shell Internationale Researchmaatschappij B.V. A process for the preparation of an aromatic hydrocarbon mixture
EP0014544A1 (en) * 1979-02-01 1980-08-20 Mobil Oil Corporation Synthesis of mordenite and mordenite so synthesized
EP0020140A1 (en) * 1979-06-01 1980-12-10 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors
EP0031675A2 (en) * 1979-12-31 1981-07-08 Mobil Oil Corporation Conversion of olefin containing mixtures to gasoline
EP0039996A1 (en) * 1980-05-09 1981-11-18 Coal Industry (Patents) Limited Alumina and/or silica catalysts supported on microporous glass
EP0014546B1 (en) * 1979-02-01 1983-02-09 Mobil Oil Corporation Preparation of nitrogenous zeolites and zeolites so prepared
EP0082701A1 (en) * 1981-12-23 1983-06-29 Mobil Oil Corporation A process for producing a mixture of hydrocarbons rich in benzene, toluene, and xylene
US4394300A (en) 1980-04-07 1983-07-19 Mobil Oil Corporation Zeolite catalyst modified with group IVB metal
EP0032414B1 (en) * 1980-01-10 1986-08-13 Mobil Oil Corporation Reformate upgrading
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WO2013170939A1 (en) * 2012-05-14 2013-11-21 Saudi Basic Industries Corporation Process for conversion of lower aliphatic ethers to aromatics and lower olefins
WO2014152370A3 (en) * 2013-03-14 2014-12-04 Virent, Inc. Production of aromatics from di-and poly-oxygenates
US9255227B2 (en) 2006-12-13 2016-02-09 Haldor Topsoe A/S Process for the synthesis of hydrocarbon constituents of gasoline
US9873644B2 (en) 2013-05-22 2018-01-23 Virent, Inc. Hydrogenation of carboxylic acids to increase yield of aromatics
US9873643B2 (en) 2011-11-23 2018-01-23 Virent, Inc. Dehydrogenation of alkanols to increase yield of aromatics
US9873836B2 (en) 2013-05-22 2018-01-23 Virent, Inc. Process for converting biomass to aromatic hydrocarbons
US9878966B2 (en) 2011-11-23 2018-01-30 Virent, Inc. Dehydrogenation of alkanols to increase yield of aromatics
US10196325B2 (en) 2015-01-15 2019-02-05 Exxonmobil Chemical Patents Inc. Process for converting syngas to aromatics and catalyst system suitable therefor
CN110002933A (en) * 2019-04-03 2019-07-12 浙江天禄环境科技有限公司 A kind of method that low-order coal sub-prime prepares methanol and low-carbon alkene using Poly-generation
CN114641510A (en) * 2019-11-07 2022-06-17 伊士曼化工公司 Recovery of the constituent polyvinyl Acetal

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US5276240A (en) * 1991-10-18 1994-01-04 Board Of Regents, The University Of Texas System Catalytic hydrodehalogenation of polyhalogenated hydrocarbons
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US7977517B2 (en) * 2007-03-08 2011-07-12 Virent Energy Systems, Inc. Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
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JP5098704B2 (en) * 2008-03-04 2012-12-12 国立大学法人北海道大学 Catalyst for the production of olefins from ketones
JP5504494B2 (en) * 2009-03-02 2014-05-28 国立大学法人 鹿児島大学 Equipment for producing aromatic hydrocarbons or ketone compounds
WO2010101120A1 (en) * 2009-03-02 2010-09-10 国立大学法人 鹿児島大学 Apparatus for producing aromatic hydrocarbons or ketone compounds, apparatus for producing levulinic acid, apparatus for separating levulinic acid, and apparatus for producing hydrocarbons from levulinic acid
RU2569897C2 (en) * 2010-06-03 2015-12-10 Стора Энсо Ойй Hydrogen treatment of crude tall oil for producing aromatic monomers
JP5798821B2 (en) 2011-07-15 2015-10-21 三菱重工業株式会社 Method and system for producing gasoline from methanol and generating electricity
JP5812781B2 (en) 2011-09-21 2015-11-17 三菱重工業株式会社 Method and apparatus for producing gasoline and hydrogen from methanol
CN103537315B (en) * 2012-07-12 2015-11-25 中国石油化工股份有限公司 Methanol arenes catalytic agent and preparation method thereof
RU2594564C1 (en) * 2015-05-18 2016-08-20 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Catalyst and method of converting ethanol, methanol or mixture thereof

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US2950332A (en) * 1958-11-26 1960-08-23 Exxon Research Engineering Co Conversion of ketones to aromatics
US3728408A (en) * 1969-05-05 1973-04-17 Mobil Oil Corp Conversion of polar compounds using highly siliceous zeolite-type catalysts

Cited By (30)

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Publication number Priority date Publication date Assignee Title
DE2854258A1 (en) * 1977-12-20 1979-06-21 Mobil Oil Corp METHOD FOR THE PRODUCTION OF HIGH QUALITY LUBRICANT BASE OIL
EP0005287A1 (en) * 1978-04-21 1979-11-14 Shell Internationale Researchmaatschappij B.V. A process for the preparation of an aromatic hydrocarbon mixture
EP0014544A1 (en) * 1979-02-01 1980-08-20 Mobil Oil Corporation Synthesis of mordenite and mordenite so synthesized
EP0014546B1 (en) * 1979-02-01 1983-02-09 Mobil Oil Corporation Preparation of nitrogenous zeolites and zeolites so prepared
EP0020140A1 (en) * 1979-06-01 1980-12-10 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing dual reactors
EP0031675A2 (en) * 1979-12-31 1981-07-08 Mobil Oil Corporation Conversion of olefin containing mixtures to gasoline
EP0031675A3 (en) * 1979-12-31 1981-07-15 Mobil Oil Corporation Conversion of olefin containing mixtures to gasoline
EP0032414B1 (en) * 1980-01-10 1986-08-13 Mobil Oil Corporation Reformate upgrading
US4394300A (en) 1980-04-07 1983-07-19 Mobil Oil Corporation Zeolite catalyst modified with group IVB metal
EP0039996A1 (en) * 1980-05-09 1981-11-18 Coal Industry (Patents) Limited Alumina and/or silica catalysts supported on microporous glass
EP0082701A1 (en) * 1981-12-23 1983-06-29 Mobil Oil Corporation A process for producing a mixture of hydrocarbons rich in benzene, toluene, and xylene
US9255227B2 (en) 2006-12-13 2016-02-09 Haldor Topsoe A/S Process for the synthesis of hydrocarbon constituents of gasoline
RU2458898C1 (en) * 2011-02-18 2012-08-20 Общество с ограниченной ответственностью Производственный научно-технический центр "ЭОН" (ООО ПНТЦ "ЭОН") Method of producing aromatic hydrocarbons
US9873643B2 (en) 2011-11-23 2018-01-23 Virent, Inc. Dehydrogenation of alkanols to increase yield of aromatics
US9878966B2 (en) 2011-11-23 2018-01-30 Virent, Inc. Dehydrogenation of alkanols to increase yield of aromatics
WO2013170939A1 (en) * 2012-05-14 2013-11-21 Saudi Basic Industries Corporation Process for conversion of lower aliphatic ethers to aromatics and lower olefins
US8940953B2 (en) 2012-05-14 2015-01-27 Saudi Basic Industries Corporation Process for conversion of lower aliphatic ethers to aromatics and lower olefins
AU2014239915B2 (en) * 2013-03-14 2019-04-04 Virent, Inc. Production of aromatics from di-and poly-oxygenates
CN105143406A (en) * 2013-03-14 2015-12-09 维仁特公司 Production of aromatics from di- and poly-oxygenates
WO2014152370A3 (en) * 2013-03-14 2014-12-04 Virent, Inc. Production of aromatics from di-and poly-oxygenates
US9403736B2 (en) 2013-03-14 2016-08-02 Virent, Inc. Production of aromatics from di- and polyoxygenates
US9440892B2 (en) 2013-03-14 2016-09-13 Virent, Inc. Production of aromatics from di- and polyoxygenates
CN107011936A (en) * 2013-03-14 2017-08-04 维仁特公司 Aromatic compound is produced from dioxy compound and polyoxy compound
EP2970775B1 (en) * 2013-03-14 2022-10-19 Virent, Inc. Production of aromatics from di-and poly-oxygenates
US9873836B2 (en) 2013-05-22 2018-01-23 Virent, Inc. Process for converting biomass to aromatic hydrocarbons
US9873644B2 (en) 2013-05-22 2018-01-23 Virent, Inc. Hydrogenation of carboxylic acids to increase yield of aromatics
US10196325B2 (en) 2015-01-15 2019-02-05 Exxonmobil Chemical Patents Inc. Process for converting syngas to aromatics and catalyst system suitable therefor
CN110002933A (en) * 2019-04-03 2019-07-12 浙江天禄环境科技有限公司 A kind of method that low-order coal sub-prime prepares methanol and low-carbon alkene using Poly-generation
CN110002933B (en) * 2019-04-03 2022-02-18 浙江天禄环境科技有限公司 Method for preparing methanol and low-carbon olefin by poly-generation through low-rank coal quality-based utilization
CN114641510A (en) * 2019-11-07 2022-06-17 伊士曼化工公司 Recovery of the constituent polyvinyl Acetal

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NO145758C (en) 1982-06-02
IT1019796B (en) 1977-11-30
NO145758B (en) 1982-02-15
JPS599525B2 (en) 1984-03-03
CS191916B2 (en) 1979-07-31
DE2463420C2 (en) 1986-10-02
FR2240281A1 (en) 1975-03-07
BE818708A (en) 1975-02-10
PL94448B1 (en) 1977-08-31
DE2463418C2 (en) 1987-02-19
DK422074A (en) 1975-04-14
NL7410583A (en) 1975-02-11
FR2240281B1 (en) 1978-03-24
NO742859L (en) 1975-03-10
MY7700175A (en) 1977-12-31
DE2438252A1 (en) 1975-02-20
JPS5076027A (en) 1975-06-21
AU7215474A (en) 1976-02-12
NL181104B (en) 1987-01-16
DE2463421C2 (en) 1986-10-02
DE2463419A1 (en) 1985-02-28
SU589903A3 (en) 1978-01-25
DE2438252C2 (en) 1986-08-28
NL181104C (en) 1987-06-16

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