GB1437476A - Radiation cross-linked polyurethane foams - Google Patents

Radiation cross-linked polyurethane foams

Info

Publication number
GB1437476A
GB1437476A GB2441573A GB2441573A GB1437476A GB 1437476 A GB1437476 A GB 1437476A GB 2441573 A GB2441573 A GB 2441573A GB 2441573 A GB2441573 A GB 2441573A GB 1437476 A GB1437476 A GB 1437476A
Authority
GB
United Kingdom
Prior art keywords
polyester polyol
foam
bis
ionising radiation
polyol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2441573A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kimberly Clark Tissue Co
Original Assignee
Scott Paper Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scott Paper Co filed Critical Scott Paper Co
Publication of GB1437476A publication Critical patent/GB1437476A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/637—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the in situ polymerisation of the compounds having carbon-to-carbon double bonds in a reaction mixture of saturated polymers and isocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

1437476 Irradication-modified cross-linked polymethane foams SCOTT PAPER CO 22 May 1973 [1 June 1972] 24415/73 Heading C3R A polyurethane foam comprising the reaction product of: (a) a polyol consisting of (i) a polyester polyol, (ii) a polyester polyol of M.W. not exeeding 1500 or (iii) a mixture of a polyester polyol of M.W. 400 to 5000 and polyester polyol of M.W. 250 to 6500; (b) an organic polyisocyanate; and (c) at least one cross-linking agent consisting of an at least bis-acrylate or methacrylate, triallyl cyanurate, methyl methacrylate, 1,5-cyclooctadiene or bis(beta-chloroethyl)vinyl phosphonate is subjected to ionising radiation at a dosage sufficient to modify the properties of the foam. Apart from (a), (b) and (c) the reaction mixture also includes a catalyst, e.g. a t-amine or metal salt; blowing agent; and optionally a surfactant, fillers, pigments, dyes, plasticisers or stabilizers. The ionising radiation has an energy of at least 50 ev., preferably at least 0À1 mev. The reactants and catalysts are extensively exemplified. The treatment is stated to increase the tensile and tear strength and improve the compression/deflection characteristics of the foam. Several possible applications of the product are specified.
GB2441573A 1972-06-01 1973-05-22 Radiation cross-linked polyurethane foams Expired GB1437476A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US25848872A 1972-06-01 1972-06-01

Publications (1)

Publication Number Publication Date
GB1437476A true GB1437476A (en) 1976-05-26

Family

ID=22980763

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2441573A Expired GB1437476A (en) 1972-06-01 1973-05-22 Radiation cross-linked polyurethane foams

Country Status (7)

Country Link
JP (1) JPS527480B2 (en)
AU (1) AU5612873A (en)
BE (1) BE800349A (en)
CA (1) CA1021898A (en)
DE (1) DE2328850A1 (en)
FR (1) FR2186504B1 (en)
GB (1) GB1437476A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4337130A (en) * 1980-06-25 1982-06-29 E. I. Du Pont De Nemours And Company Photocurable polyurethane film coatings
DE102007016791A1 (en) * 2007-04-05 2008-10-09 Heraeus Kulzer Gmbh Foaming, solidifying compositions for molding surfaces and suitable impression trays
MX2009010354A (en) * 2009-09-25 2011-03-25 Concreto W S A De C V Equipment for metering out and applying foamed polyurethane in three-dimensional prefabricated-panel metal structures.
DE102010010621A1 (en) 2010-03-09 2011-09-15 Bayer Materialscience Ag Radiation-curable foams

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1265862A (en) * 1959-05-15 1961-07-07 Atlantic Res Corp Expanded polyurethane plastics, rigid
GB1147732A (en) * 1966-05-20 1969-04-02 O Brien Corp Improvements in or relating to isocyano-acrylic polymerization systems

Also Published As

Publication number Publication date
DE2328850A1 (en) 1973-12-13
FR2186504B1 (en) 1977-05-06
AU5612873A (en) 1974-11-28
CA1021898A (en) 1977-11-29
BE800349A (en) 1973-11-30
JPS4961293A (en) 1974-06-13
JPS527480B2 (en) 1977-03-02
FR2186504A1 (en) 1974-01-11

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee