GB1431944A - Process for preparing a crystalline aluminosilicate zeolite and process for the conversion of hydrocarbon oils - Google Patents

Process for preparing a crystalline aluminosilicate zeolite and process for the conversion of hydrocarbon oils

Info

Publication number
GB1431944A
GB1431944A GB2081873A GB2081873A GB1431944A GB 1431944 A GB1431944 A GB 1431944A GB 2081873 A GB2081873 A GB 2081873A GB 2081873 A GB2081873 A GB 2081873A GB 1431944 A GB1431944 A GB 1431944A
Authority
GB
United Kingdom
Prior art keywords
zeolite
sio
solution
exchanged
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2081873A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1431944A publication Critical patent/GB1431944A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
    • C01B33/2853—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively) of type Y
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2876—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures from a reacting mixture containing an amine or an organic cation, e.g. a quaternary onium cation-ammonium, phosphonium, stibonium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1431944 Aluminosilicate zeolites SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 2 May 1973 [4 May 1972 (2)] 20818/73 Heading C1A [Also in Divisions B1 and C4-C5] A high-silica faujasite zeolite (529) having SiO 2 /Al 2 O 3 ratio 5À5 to 8À0, unit cell 24À35- 24À60 Š and a benzene sorption at 20‹ C. of 17-24 wt. per cent is made by: (1) heating to 40-70‹ C. a faujasite precursor solution having Na 2 O/SiO 2 =1 to 3/1, SiO 2 /Al 2 O 3 =4 to 20/1, H 2 O/Na 2 O = 10 to 30/1 (molar ratios); (2) combining the solution with Na silicate solution to increase the SiO 2 /Al 2 O 3 molar ratio to 50- 135/1; (3) mixing the combined solution with AlCl 3 solution to form a gel slurry; (4) heating the slurry at 20-150‹ C. and separating an amorphous gel therefrom; (5) mixing the gel with H 2 O to reduce the solids content by 10- 80%; (6) crystallizing the zeolite by heating the mixture at 20-150‹ C. The zeolite may be exchanged with ammonium or metal ions, or converted to hydrogen form by calcining at 500-800‹ C. The NH 4 <SP>+</SP>- exchanged zeolite may be calcined, further NH 4 <SP>+</SP>-exchanged and re-calcined at a lower temperature to provide a catalyst useful in hydrocarbon cracking. The zeolite may also be composited with hydrogenation metal components (see Division B1).
GB2081873A 1972-05-04 1973-05-02 Process for preparing a crystalline aluminosilicate zeolite and process for the conversion of hydrocarbon oils Expired GB1431944A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US25039472A 1972-05-04 1972-05-04
US25022072A 1972-05-04 1972-05-04

Publications (1)

Publication Number Publication Date
GB1431944A true GB1431944A (en) 1976-04-14

Family

ID=26940697

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2081873A Expired GB1431944A (en) 1972-05-04 1973-05-02 Process for preparing a crystalline aluminosilicate zeolite and process for the conversion of hydrocarbon oils

Country Status (7)

Country Link
JP (1) JPS56366B2 (en)
AU (1) AU468048B2 (en)
CA (1) CA1006865A (en)
DE (1) DE2322099C2 (en)
FR (1) FR2183156B1 (en)
GB (1) GB1431944A (en)
NL (1) NL7306078A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4503023A (en) * 1979-08-14 1985-03-05 Union Carbide Corporation Silicon substituted zeolite compositions and process for preparing same
USH282H (en) 1982-12-27 1987-06-02 W. R. Grace & Co. High silica/alumina ratio faujasite type NaY
US4711770A (en) * 1979-08-14 1987-12-08 Union Carbide Corporation Silicon substituted Y zeolite composition LZ-210
US4897178A (en) * 1983-05-02 1990-01-30 Uop Hydrocracking catalyst and hydrocracking process
WO2009126974A2 (en) * 2008-04-10 2009-10-15 Shell Oil Company Diluents, method for preparing a diluted hydrocarbon composition, and diluted hydrocarbon compositions
US8450538B2 (en) 2008-04-10 2013-05-28 Shell Oil Company Hydrocarbon composition
CN104743572A (en) * 2013-12-27 2015-07-01 陕西煤化工技术工程中心有限公司 Method for synthesis of high silica-alumina ratio ultrafine NaY molecular sieve

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3004060A1 (en) * 1979-02-07 1980-08-21 Toyo Soda Mfg Co Ltd METHOD FOR PRODUCING Y ZEOLITE
NL191266C (en) * 1979-05-25 1995-04-18 Shell Int Research Process for the preparation of light hydrocarbon fractions.
JPS6121911A (en) * 1984-07-11 1986-01-30 Toyo Soda Mfg Co Ltd Preparation of faujasite type zeolite
US4663025A (en) * 1986-08-14 1987-05-05 Phillips Petroleum Company Catalytic cracking processes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1058929B (en) * 1954-04-20 1959-06-04 Milprint Inc Hose-like container made of flexible material
US3492090A (en) * 1966-04-07 1970-01-27 Mobil Oil Corp Process for producing faujasite

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4503023A (en) * 1979-08-14 1985-03-05 Union Carbide Corporation Silicon substituted zeolite compositions and process for preparing same
US4711770A (en) * 1979-08-14 1987-12-08 Union Carbide Corporation Silicon substituted Y zeolite composition LZ-210
USH282H (en) 1982-12-27 1987-06-02 W. R. Grace & Co. High silica/alumina ratio faujasite type NaY
US4897178A (en) * 1983-05-02 1990-01-30 Uop Hydrocracking catalyst and hydrocracking process
WO2009126974A2 (en) * 2008-04-10 2009-10-15 Shell Oil Company Diluents, method for preparing a diluted hydrocarbon composition, and diluted hydrocarbon compositions
WO2009126974A3 (en) * 2008-04-10 2010-03-18 Shell Oil Company Method for preparing a diluted hydrocarbon composition, and diluted hydrocarbon compositions
US8450538B2 (en) 2008-04-10 2013-05-28 Shell Oil Company Hydrocarbon composition
US8734634B2 (en) 2008-04-10 2014-05-27 Shell Oil Company Method for producing a crude product, method for preparing a diluted hydrocarbon composition, crude products, diluents and uses of such crude products and diluents
CN104743572A (en) * 2013-12-27 2015-07-01 陕西煤化工技术工程中心有限公司 Method for synthesis of high silica-alumina ratio ultrafine NaY molecular sieve
CN104743572B (en) * 2013-12-27 2018-02-16 陕西煤化工技术工程中心有限公司 A kind of method of the ultra-fine NaY molecular sieve of synthesizing high-silicon aluminum ratio

Also Published As

Publication number Publication date
FR2183156A1 (en) 1973-12-14
AU5514173A (en) 1974-11-07
DE2322099C2 (en) 1982-08-26
DE2322099A1 (en) 1973-11-22
JPS56366B2 (en) 1981-01-07
JPS4961096A (en) 1974-06-13
FR2183156B1 (en) 1976-06-11
NL7306078A (en) 1973-11-06
AU468048B2 (en) 1975-12-18
CA1006865A (en) 1977-03-15

Similar Documents

Publication Publication Date Title
CA1154419A (en) High silica faujasite polymorph csz-3 and method of synthesizing
GB1474263A (en) Small pore synthetic crystalline aluminosilicate zeolite and its preparation
US4151189A (en) Synthesizing low sodium crystalline aluminosilicate zeolites with primary amines
US3791964A (en) Hydrocarbon conversion process employing a crystalline aluminosilicate and method of preparing the same
US3321272A (en) Process for making crystalline zeolites
US3355246A (en) Crystalline zeolite zk-21
GB1318157A (en) Process for preparation of high-silica zeolites
GB1525782A (en) Process for the production of a crystalline zeolitic molecular sieve of type a
GB1161974A (en) Synthetic Crystalline Aluminosilicate and method of preparing the same
GB1348527A (en) Synthesis of a high-silica zeolite
GB1431944A (en) Process for preparing a crystalline aluminosilicate zeolite and process for the conversion of hydrocarbon oils
GB1061474A (en) Synthetic zeolites
JPS57123815A (en) Production of crystalline aluminosilicate zeolite
GB1202511A (en) Process for preparing zeolite l
GB1413876A (en) Method of making hydrocarbon conversion catalysts having regene ration properties and catalysts made by the method
US3411874A (en) Zsm-2 zeolite and preparation thereof
SE7408598L (en)
EP0142317A3 (en) Crystalline silicate zsm-48 and method for its preparation
ES489504A1 (en) Process for producing a boron containing zeolite with the structure of ZSM-5 and its use as a catalyst.
GB1430421A (en) Hydrocarbon cracking catalyst composition containing a faujasite
GB1342977A (en) Process for preparing attrition resistant zeolitc particles
GB1528532A (en) Preparation of a zeolite catalyst
FR1264290A (en) Process for the catalytic preparation of ethylene glycol
GB1560223A (en) Synethesis of favjasite
GB1297927A (en)

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19920502