GB1420636A - Cyclopropane derivatives - Google Patents

Cyclopropane derivatives

Info

Publication number
GB1420636A
GB1420636A GB5216973A GB5216973A GB1420636A GB 1420636 A GB1420636 A GB 1420636A GB 5216973 A GB5216973 A GB 5216973A GB 5216973 A GB5216973 A GB 5216973A GB 1420636 A GB1420636 A GB 1420636A
Authority
GB
United Kingdom
Prior art keywords
group
formula
alkyl
alkenyl
optionally substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5216973A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of GB1420636A publication Critical patent/GB1420636A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40Radicals substituted by oxygen atoms
    • C07D307/42Singly bound oxygen atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40Radicals substituted by oxygen atoms
    • C07D307/42Singly bound oxygen atoms
    • C07D307/45Oxygen atoms acylated by a cyclopropane containing carboxylic acyl radical, e.g. chrysanthemumates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1420636 cyclopropane derivatives ROUSSEL UCLAF 9 Nov 1973 [10 Nov 1972] 52169/73 Heading C2C The invention comprises stereoisomers of compounds of the formula wherein the olefinic double bond is of E-structure and X represents an alkyl group containing from 1 to 6 carbon atoms (optionally substituted by a halogen atom, or by an alkoxy group); a benzyl group (optionally substituted by one or more substituents selected from alkyl, alkenyl, alkadienyl, methylenedioxy and benzyl groups, and halogen atoms); a cyclohexenedicarboximido-methyl group having the olefinic double bond at any position in the carbocyclic ring and optionally substituted on the ring by one or more halogen atoms, methyl groups or acetoxy groups; a group of formula wherein Y 1 and Y 2 , which may be the same or different, each represents a hydrogen atom, an alkyl, alkenyl or alkadienyl group and Y 3 represents a hydrogen atom, or an optionally substituted alkyl, alkenyl, alkadienyl, aryl or heterocyclic group; or a group of formula wherein Z represents an alkyl, alkenyl, alkynyl, aryl, aralkyl, cycloalkyl, cycloalkenyl or heterocyclic group; and Y represents an alkyl group containing from 1 to 6 carbon atoms. The invention further comprises stereoisomers of compounds of the formulae The compounds of Formula I may be obtained by reducing a compound of the formula to give a compound of Formula III, reacting this with a strong base and an esterifying and etherifying agent and if desired saponifying the ester function to give a compound of Formula IV<SP>1</SP> and subsequently converting this into the desired ester.
GB5216973A 1972-11-10 1973-11-09 Cyclopropane derivatives Expired GB1420636A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7239890A FR2213013B1 (en) 1972-11-10 1972-11-10

Publications (1)

Publication Number Publication Date
GB1420636A true GB1420636A (en) 1976-01-07

Family

ID=9106967

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5216973A Expired GB1420636A (en) 1972-11-10 1973-11-09 Cyclopropane derivatives

Country Status (14)

Country Link
JP (1) JPS49100061A (en)
BE (1) BE807144A (en)
CA (1) CA1017753A (en)
CH (1) CH596135A5 (en)
DE (1) DE2356125A1 (en)
DK (1) DK138640B (en)
FR (1) FR2213013B1 (en)
GB (1) GB1420636A (en)
HU (1) HU173381B (en)
IE (1) IE39034B1 (en)
IL (1) IL43593A (en)
IT (1) IT1047930B (en)
NL (1) NL7315411A (en)
SU (2) SU640656A3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0002077A1 (en) * 1977-10-27 1979-05-30 Shell Internationale Researchmaatschappij B.V. Esters of substituted cyclopropanecarboxylic acids and process for the preparation thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2455018A1 (en) * 1979-04-26 1980-11-21 Roussel Uclaf ALLETHROLONE DERIVATIVES AND THEIR PREPARATION PROCESS
DE2919820A1 (en) 1979-05-16 1980-11-20 Bayer Ag FLUOR-SUBSTITUTED OXYALKENYL-CYCLOPROPANCARBONIC ACID ESTERS, METHODS FOR THE PRODUCTION THEREOF AND THEIR USE AS INSECTICIDES AND ACARICIDES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0002077A1 (en) * 1977-10-27 1979-05-30 Shell Internationale Researchmaatschappij B.V. Esters of substituted cyclopropanecarboxylic acids and process for the preparation thereof

Also Published As

Publication number Publication date
IL43593A (en) 1977-01-31
HU173381B (en) 1979-04-28
CA1017753A (en) 1977-09-20
DK138640C (en) 1979-03-19
IL43593A0 (en) 1974-03-14
IE39034B1 (en) 1978-07-19
SU849978A3 (en) 1981-07-23
FR2213013B1 (en) 1976-08-20
CH596135A5 (en) 1978-02-28
DE2356125A1 (en) 1974-05-30
DK138640B (en) 1978-10-09
NL7315411A (en) 1974-05-14
IT1047930B (en) 1980-10-20
SU640656A3 (en) 1978-12-30
FR2213013A1 (en) 1974-08-02
JPS49100061A (en) 1974-09-20
IE39034L (en) 1974-05-10
BE807144A (en) 1974-05-09

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee