GB1413125A - Photographic emulsions - Google Patents

Photographic emulsions

Info

Publication number
GB1413125A
GB1413125A GB5902472A GB5902472A GB1413125A GB 1413125 A GB1413125 A GB 1413125A GB 5902472 A GB5902472 A GB 5902472A GB 5902472 A GB5902472 A GB 5902472A GB 1413125 A GB1413125 A GB 1413125A
Authority
GB
United Kingdom
Prior art keywords
methyl
tosylate
methacryloyloxy
ter
methosulphate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5902472A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB1413125A publication Critical patent/GB1413125A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/04Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
    • G03C1/053Polymers obtained by reactions involving only carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Pyridine Compounds (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1413125 Copolymers for silver halide emulsion preparation EASTMAN KODAK CO 21 Dec 1972 [29 Dec 1971] 59024/72 Heading C3P [Also in Division G2] A silver halide emulsion contains as peptizer a co- or ter-polymer containing the following monomers:- (A) a vinyl imidazolium monomer, a vinyl pyridinium monomer (either of which may be substituted by alkyl or aryl groups) or a monomer of formula wherein Z is O or NH, X is an anion, R 1 is H or methyl, R 2 is alkylene with 1-6 C atoms and R 3 , R 4 and R 5 are alkyl with 1-8 C atoms, or R 3 and R 4 together complete a 5- or 6-membered heterocyclic ring or R 3 , R 4 and R 5 together complete a 5- or 6-membered heterocyclic ring and the N atom bonded to R 2 has a double bond attached thereto and (B) at least one ethylenically unsaturated compound having at least one carboxylic group; the molar ratio of quaternary ammonium groups to carboxylic groups in the polymer being 1À1 to 15. Specified terpolymers are acrylic acid/methacrylic acid/2- (methacryloyloxy) - ethyltrimethylammonium methyl sulphate or tosylate or 1,2-dimethyl-5- vinylpyridinium methyl sulphate or tosylate or 3-methyl-1-vinylimidazolium methyl sulphate and the specified copolymer is acrylic acid/2- (methacryloyloxy) ethyltrimethylammonium methyl sulphate. The co- and ter-polymers are used to produce ammonical and neutral emulsions and may be admixed with gelatin. The co- and ter-polymers are prepared by mixing in water the quaternary ammonium salt with acrylic acid and optionally methacrylic acid, potassium persulphate and sodium metabisulphite and heating. Specified quaternary salts are 2-(methacryloyloxy)ethyltrimethyl ammonium methosulphate, or tosylate; 1,2 - dimethyl - 5 - vinyl - pyridinium methosulphate or tosylate and 3-methyl-1-vinylimidazolium methosulphate.
GB5902472A 1971-12-29 1972-12-21 Photographic emulsions Expired GB1413125A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US21380771A 1971-12-29 1971-12-29

Publications (1)

Publication Number Publication Date
GB1413125A true GB1413125A (en) 1975-11-05

Family

ID=22796598

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5902472A Expired GB1413125A (en) 1971-12-29 1972-12-21 Photographic emulsions

Country Status (5)

Country Link
US (1) US3749577A (en)
JP (1) JPS4874831A (en)
BE (1) BE793586A (en)
DE (1) DE2263859A1 (en)
GB (1) GB1413125A (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925083A (en) * 1973-01-02 1975-12-09 Polaroid Corp Synthetic silver halide emulsion binder
US3816129A (en) * 1973-01-02 1974-06-11 Polaroid Corp Synthetic silver halide emulsion binder
GB1504949A (en) * 1974-09-17 1978-03-22 Eastman Kodak Co Aqueous polymer latexes containing hydrophobic materials
JPS5251940A (en) * 1975-10-24 1977-04-26 Fuji Photo Film Co Ltd Processing of silver halide photographic light sensitive material
US4297431A (en) * 1978-09-15 1981-10-27 Polaroid Corporation Diffusion control layers in diffusion transfer photographic products
US4426481A (en) 1980-03-14 1984-01-17 Polaroid Corporation Polymeric matrix containing β-eliminating polymer and process for preparing same
US4546159A (en) * 1980-03-14 1985-10-08 Polaroid Corporation Eliminating polymers useful in diffusion control layers
US4288523A (en) * 1980-03-14 1981-09-08 Polaroid Corporation Diffusion control layers in diffusion transfer photographic products
US4749762A (en) * 1982-05-12 1988-06-07 E. I. Du Pont De Nemours And Company Acrylic amphoteric polymers
US5187059A (en) * 1982-05-12 1993-02-16 E. I. Du Pont De Nemours And Company Silver halide emulsion containing acrylic amphoteric polymers
US5011898A (en) * 1982-05-12 1991-04-30 E. I. Du Pont De Nemours And Company Acrylic amphoteric polymers
US5229250A (en) * 1982-05-12 1993-07-20 E. I. Du Pont De Nemours And Company Element containing acrylic amphoteric polymers
US4448850A (en) * 1982-07-23 1984-05-15 Eastman Kodak Company Vinyl acetate polymers and latex compositions containing same
DE3684166D1 (en) * 1985-04-22 1992-04-16 Du Pont SYNTHETIC AMPHOTERIC POLYMERS CONTAINING WASH-OFF FILM.
US5385819A (en) * 1993-12-22 1995-01-31 Eastman Kodak Company Preparation of thin tabular grain silver halide emulsions using synthetic polymeric peptizers
US5380642A (en) * 1993-12-22 1995-01-10 Eastman Kodak Company Process for preparing a thin tabular grain silver halide emulsion
US5804363A (en) * 1997-04-28 1998-09-08 Eastman Kodak Company High bromide (111) tabular grain emulsions containing a cationic peptizer having diallylammonium derived repeating units
TWI434908B (en) * 2007-07-17 2014-04-21 Lintec Corp An adhesive composition, an adhesive layer, and an adhesive sheet

Also Published As

Publication number Publication date
DE2263859A1 (en) 1973-07-05
US3749577A (en) 1973-07-31
BE793586A (en) 1973-06-29
JPS4874831A (en) 1973-10-09

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee