GB1410328A - Alkoxylation process - Google Patents

Alkoxylation process

Info

Publication number
GB1410328A
GB1410328A GB5929571A GB5929571A GB1410328A GB 1410328 A GB1410328 A GB 1410328A GB 5929571 A GB5929571 A GB 5929571A GB 5929571 A GB5929571 A GB 5929571A GB 1410328 A GB1410328 A GB 1410328A
Authority
GB
United Kingdom
Prior art keywords
fluoroalcohols
dec
alkali metal
catalytic amount
formation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5929571A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Original Assignee
Unilever PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC filed Critical Unilever PLC
Priority to GB5929571A priority Critical patent/GB1410328A/en
Priority to DE19722261681 priority patent/DE2261681A1/en
Priority to CA159,481A priority patent/CA971978A/en
Publication of GB1410328A publication Critical patent/GB1410328A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2639—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing elements other than oxygen, nitrogen or sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1410328 Alkoxylating fluoroalcohols UNILEVER Ltd 20 Dec 1972 [21 Dec 1971] 59295/71 Heading C3R [Also in Division C2] Fluoroalcohols of the general formula wherein X denotes H or F and n is from 5 to 12, are alkoxylated by reacting with ethylene or propylene oxide firstly in the presence of a catalytic amount of an elemental alkali metal or an alkali metal hydroxide and subsequently in the presence of a catalytic amount of an acidic catalyst. The basic catalyst results in the formation of monoalkoxylates and the acid catalyst results in the subsequent formation of polyalkoxylates, preferably having 10 to 16 alkoxyl units. Temperatures of both stages are preferably in the range 70‹ to 110‹ C. and suitable acid catalysts are BF 3 , SbCl 5 or SnCl 4 . Examples describe the preparation of mono- and poly-adducts in which n is 7, 8 or 9 and X is H or F. Uses.-The polyadducts are useful as non- ionic surfactants.
GB5929571A 1971-12-21 1971-12-21 Alkoxylation process Expired GB1410328A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB5929571A GB1410328A (en) 1971-12-21 1971-12-21 Alkoxylation process
DE19722261681 DE2261681A1 (en) 1971-12-21 1972-12-16 ALCOXYLATION PROCESS
CA159,481A CA971978A (en) 1971-12-21 1972-12-20 Ethoxylation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5929571A GB1410328A (en) 1971-12-21 1971-12-21 Alkoxylation process

Publications (1)

Publication Number Publication Date
GB1410328A true GB1410328A (en) 1975-10-15

Family

ID=10483477

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5929571A Expired GB1410328A (en) 1971-12-21 1971-12-21 Alkoxylation process

Country Status (3)

Country Link
CA (1) CA971978A (en)
DE (1) DE2261681A1 (en)
GB (1) GB1410328A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0485637A1 (en) * 1990-05-11 1992-05-20 Asahi Glass Company Ltd. Process for producing polyoxyalkylene compound
US8946486B2 (en) * 2007-12-03 2015-02-03 Tyco Fire & Security Gmbh Method of forming alkoxylated fluoroalcohols

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2010874B (en) * 1977-12-07 1982-10-06 Ciba Geigy Ag Fluorinated nonionic surfactants

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0485637A1 (en) * 1990-05-11 1992-05-20 Asahi Glass Company Ltd. Process for producing polyoxyalkylene compound
EP0485637A4 (en) * 1990-05-11 1994-03-15 Asahi Glass Co Ltd Process for producing polyoxyalkylene compound.
US8946486B2 (en) * 2007-12-03 2015-02-03 Tyco Fire & Security Gmbh Method of forming alkoxylated fluoroalcohols
US9950978B2 (en) 2007-12-03 2018-04-24 Tyco Fire & Security Gmbh Method of forming alkoxylated fluoroalcohols

Also Published As

Publication number Publication date
DE2261681A1 (en) 1973-07-05
CA971978A (en) 1975-07-29

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee