GB1259381A - - Google Patents

Info

Publication number
GB1259381A
GB1259381A GB1193069A GB1259381DA GB1259381A GB 1259381 A GB1259381 A GB 1259381A GB 1193069 A GB1193069 A GB 1193069A GB 1259381D A GB1259381D A GB 1259381DA GB 1259381 A GB1259381 A GB 1259381A
Authority
GB
United Kingdom
Prior art keywords
iron
organic acid
treating
alkali solution
iron oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1193069A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1259381A publication Critical patent/GB1259381A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/862—Iron and chromium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B1/00—Shaft or like vertical or substantially vertical furnaces
    • F27B1/005—Shaft or like vertical or substantially vertical furnaces wherein no smelting of the charge occurs, e.g. calcining or sintering furnaces
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,259,381. Iron oxide catalysts. H. F. A. TOPSOE. 28 Jan., 1970 [6 March, 1969], No. 11930/69. Heading B1E. [Also in Division C1] A high temperature shift catalyst comprising iron oxide characterised by the presence of less than 50 ppm sulphur (claimed per se) is prepared by precipitating iron as a salt of an organic acid from solutions of iron salts in the form of coarse crystals, washing the precipitate to remove soluble impurities, then treating the precipitate with an alkali solution to obtain a flocculent iron oxide of high specific surface area and regenerate the organic acid reagent. The alkali solution may be NH 4 OH, NaOH, KOH. The organic acid may be oxalic acid and is preferably added in the form of its ammonium or alkali metal salt. The catalyst may contain Cr 2 O 3 and/or PbO as promotors. The precipitation of ferrous oxalate may be carried out at room temperature and the hydrolysis by means of the alkali solution at a temperature between 50‹C and 100‹C. The promotors, e.g. Cr 2 O 3 , PbO, may be added by treating the resulting Fe(OH) 2 suspension, after washing, with their soluble nitrates. Mixed oxide catalysts may also be prepared by the process of the invention by treating solutions containing soluble salts in addtion to the iron with the ammonium or alkali metal salt of an organic acid, e.g. oxalic acid.
GB1193069A 1969-03-06 1969-03-06 Expired GB1259381A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1193069 1969-03-06

Publications (1)

Publication Number Publication Date
GB1259381A true GB1259381A (en) 1972-01-05

Family

ID=9995263

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1193069A Expired GB1259381A (en) 1969-03-06 1969-03-06

Country Status (7)

Country Link
BE (1) BE746909A (en)
CA (1) CA924285A (en)
DE (1) DE2009374C3 (en)
FR (1) FR2037669A5 (en)
GB (1) GB1259381A (en)
LU (1) LU60465A1 (en)
NL (1) NL170812C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0019989A2 (en) * 1979-03-27 1980-12-10 Imperial Chemical Industries Plc Method for producing a solution containing nitrates of iron and chromium and making a high temperature shift catalyst from it
US4410443A (en) * 1982-05-24 1983-10-18 Katalco Corporation Method of dissolving iron oxide-chrome oxide spent shift catalysts to prepare a nitrate solution suitable for use in preparing a new catalyst
GB2119276A (en) * 1982-04-26 1983-11-16 United Technologies Corp Steam reforming utilizing iron oxide catalyst
US4482645A (en) * 1983-05-24 1984-11-13 Imperial Chemical Industries Limited Method of making an iron oxidechromium oxide catalyst

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5271816A (en) * 1988-11-18 1993-12-21 Mitsubishi Jidosha Kogyo Kabushiki Kaisha Oxygen sensor

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0019989A2 (en) * 1979-03-27 1980-12-10 Imperial Chemical Industries Plc Method for producing a solution containing nitrates of iron and chromium and making a high temperature shift catalyst from it
EP0019989A3 (en) * 1979-03-27 1981-01-07 Imperial Chemical Industries Plc Method for producing a solution containing nitrates of iron and chromium and making a high temperature shift catalyst from it
GB2119276A (en) * 1982-04-26 1983-11-16 United Technologies Corp Steam reforming utilizing iron oxide catalyst
US4410443A (en) * 1982-05-24 1983-10-18 Katalco Corporation Method of dissolving iron oxide-chrome oxide spent shift catalysts to prepare a nitrate solution suitable for use in preparing a new catalyst
US4482645A (en) * 1983-05-24 1984-11-13 Imperial Chemical Industries Limited Method of making an iron oxidechromium oxide catalyst

Also Published As

Publication number Publication date
FR2037669A5 (en) 1970-12-31
DE2009374B2 (en) 1979-05-17
DE2009374A1 (en) 1970-09-24
NL170812C (en) 1983-01-03
DE2009374C3 (en) 1980-02-14
NL7003268A (en) 1970-09-08
LU60465A1 (en) 1970-05-04
BE746909A (en) 1970-08-17
CA924285A (en) 1973-04-10

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years