GB1409307A - Electrochemical systems - Google Patents

Electrochemical systems

Info

Publication number
GB1409307A
GB1409307A GB5937272A GB5937272A GB1409307A GB 1409307 A GB1409307 A GB 1409307A GB 5937272 A GB5937272 A GB 5937272A GB 5937272 A GB5937272 A GB 5937272A GB 1409307 A GB1409307 A GB 1409307A
Authority
GB
United Kingdom
Prior art keywords
chloride
lithium
anode
bromide
solute
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5937272A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB1409307A publication Critical patent/GB1409307A/en
Expired legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Primary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Conductive Materials (AREA)
  • Cell Separators (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

1409307 Electric cells UNION CARBIDE CORP 22 Dec 1972 [27 Dec 1971] 59372/72 Heading H1B A non-aqueous primary or secondary electrochemical cell comprises an anode 14, 16, a cathode collector 18, 20 and an ionically coduotive electrolyte 26 comprising a solution of an ionically conductive solute dissolved in an active cathode depolarizer with or without a co-solvent, wherein the active cathode depolarizer consists solely of a liquid oxyhalide of an element of Group V or Group VI of the Periodic Table. The oxyhalide may be phosphoryl chloride, vanadyl trichloride, vanadyl tribromide, thionyl bromide, thionyl chloride, sulphuryl chloride, pyrosulphuryl chloride chromyl chloride, selenium oxychloride, selenium oxyfluoride or mixed halides and oxyhalides of two or more elements from Groups V and VI. The solute may be a complex salt of a Lewis acid, such as aluminium or boron chloride, bromide or fluoride, antimony or phosphorus pentachloride or zirconium tetrachloride, and an inorganic ionizable salt, such as lithium, sodium or potassium chloride, bromide or fluoride or lithium sulphide, and an example given is lithium aluminium tetrachloride. As shown, a magnesium or nickel can 12 houses the anode 14, 16 which may comprise alkali metals, alkaline earth metals or alloys thereof with each other and other metals, e.g. lithium, sodium, potassium, lithium-magnesium or lithium-monoaluminate. The cathode collector preferably comprises a porous graphite cylinder 18 and a graphite rod 20, although it may also comprise metal film or screen, at least partially carbonaceous pressed powder or a PTFE-carbon mixture. Between the anode and cathode may be a separator comprising a side separator 22 of a sheet of compacted polypropylene fibres and a bottom separator 24 of a perforated disc of PTFE. The electrolyte may additionally contain an organic liquid co-colvent for the solute comprising propylene carbonate, nitrobenzene or dimethyl sulphoxide and/or a gelling agent comprising colloidal silica and/or carbon. A number of particular examples of cells are given.
GB5937272A 1971-12-27 1972-12-22 Electrochemical systems Expired GB1409307A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US21258271A 1971-12-27 1971-12-27

Publications (1)

Publication Number Publication Date
GB1409307A true GB1409307A (en) 1975-10-08

Family

ID=22791633

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5937272A Expired GB1409307A (en) 1971-12-27 1972-12-22 Electrochemical systems

Country Status (23)

Country Link
JP (1) JPS526446B2 (en)
AR (1) AR192848A1 (en)
AT (1) AT321389B (en)
AU (1) AU467969B2 (en)
BE (1) BE793372A (en)
BR (1) BR7209100D0 (en)
CA (1) CA982216A (en)
CH (1) CH565457A5 (en)
DE (1) DE2262256C3 (en)
DK (1) DK136443B (en)
ES (1) ES410039A1 (en)
FR (1) FR2166015B1 (en)
GB (1) GB1409307A (en)
IT (1) IT974314B (en)
KE (1) KE2653A (en)
MY (1) MY7600259A (en)
NL (1) NL172807C (en)
NO (1) NO142237C (en)
OA (1) OA04308A (en)
PH (1) PH10524A (en)
SE (1) SE430189C (en)
SU (1) SU524541A3 (en)
ZA (1) ZA728971B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2837511A1 (en) * 1977-08-29 1979-03-08 Catanzarite Vincent Owen ELECTROCHEMICAL CELL
EP0072197A2 (en) * 1981-08-06 1983-02-16 Altus Corporation Liquid cathode electrochemical cell with improved geometry and containing a high efficiency cathode current collector
US4448861A (en) * 1983-06-24 1984-05-15 Rayovac Corporation Lithium-thionyl chloride cell with lithium surface alloys to reduce voltage delay
EP0130504A1 (en) * 1983-06-24 1985-01-09 RAYOVAC Corporation Minimizing voltage delay by high surface area Li anodes
DE3918168A1 (en) * 1988-08-26 1990-03-08 Altus Corp RECHARGEABLE, NONWATER ELECTROCHEMICAL CELL

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51115625A (en) * 1975-01-09 1976-10-12 Gte Laboratories Inc Primary electrochemical battery and preemolded cathode for use therefor
US3993501A (en) * 1975-03-24 1976-11-23 Union Carbide Corporation Nonaqueous electrochemical cell
US3985573A (en) * 1975-06-30 1976-10-12 Union Carbide Corporation Slotted cathode collector bobbin for use in liquid cathode cell systems
US4049887A (en) * 1976-07-20 1977-09-20 Exxon Research & Engineering Co. Electrochemical cells with cathode-active materials of layered compounds
IL53717A (en) * 1977-12-29 1981-09-13 Tadiran Israel Elect Ind Ltd Reserve cell
CH625914A5 (en) * 1978-01-31 1981-10-15 Accumulateurs Fixes
DE2844181C2 (en) * 1978-10-10 1986-10-16 Vincent Owen Las Vegas Nev. Catanzarite Electrochemical cell
US4177329A (en) * 1978-11-02 1979-12-04 P. R. Mallory & Co. Inc. Electrolyte salts for non aqueous electrochemical cells
US4184014A (en) * 1978-11-24 1980-01-15 P. R. Mallory & Co. Inc. Abuse resistant cells containing fluid depolarizers
US4218523A (en) * 1979-02-28 1980-08-19 Union Carbide Corporation Nonaqueous electrochemical cell
JPS56112U (en) * 1979-06-14 1981-01-06
DK155559C (en) * 1979-06-27 1989-10-16 Eveready Battery Inc NON-ELECTRICAL ELECTROCHEMICAL ELEMENT
DK156152C (en) * 1979-06-27 1989-11-20 Eveready Battery Inc NON-ELECTRICAL ELECTROCHEMICAL ELEMENT
US4238552A (en) * 1979-07-03 1980-12-09 P. R. Mallory & Co. Inc. Electrolyte salt for non-aqueous electrochemical cells
IL59591A (en) * 1979-08-08 1983-07-31 Greatbatch W Ltd Electrochemical cell having mixed soluble depolarizer including halogens and interhalogens
US4246327A (en) * 1979-10-01 1981-01-20 Medtronic, Inc. High energy-density battery system
US4279973A (en) * 1980-04-14 1981-07-21 Honeywell Inc. Electrochemical cell
IL63336A (en) * 1981-07-16 1984-03-30 Univ Ramot Electrochemical cell
US4405693A (en) * 1981-10-05 1983-09-20 Honeywell Inc. High rate metal-sulfuryl chloride batteries
DE3633385A1 (en) * 1986-10-01 1988-04-14 Silberkraft Leichtakku Electrochemical cell having a soluble electrode which consists of alkaline metals or alkaline-earth metals
CN115050920B (en) * 2022-06-15 2024-01-30 中国科学院长春应用化学研究所 Antimony-based integrated electrode and preparation method and application thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3508966A (en) * 1967-05-22 1970-04-28 Electrochimica Corp Electrochemical cell with non-aqueous electrolyte
FR1583804A (en) * 1968-04-03 1969-12-05
US3578500A (en) * 1968-07-08 1971-05-11 American Cyanamid Co Nonaqueous electro-chemical current producing cell having soluble cathode depolarizer
FR2079744A5 (en) * 1970-02-11 1971-11-12 Accumulateurs Fixes Non aqueous electrolyte for lithium halide cells - contg tetrachloraluminate and quaternary ammonium aluminate in thiony

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2837511A1 (en) * 1977-08-29 1979-03-08 Catanzarite Vincent Owen ELECTROCHEMICAL CELL
EP0072197A2 (en) * 1981-08-06 1983-02-16 Altus Corporation Liquid cathode electrochemical cell with improved geometry and containing a high efficiency cathode current collector
EP0072197A3 (en) * 1981-08-06 1983-10-05 Altus Corporation Liquid cathode electrochemical cell with improved geometry and containing a high efficiency cathode current collector
US4448861A (en) * 1983-06-24 1984-05-15 Rayovac Corporation Lithium-thionyl chloride cell with lithium surface alloys to reduce voltage delay
EP0130504A1 (en) * 1983-06-24 1985-01-09 RAYOVAC Corporation Minimizing voltage delay by high surface area Li anodes
DE3918168A1 (en) * 1988-08-26 1990-03-08 Altus Corp RECHARGEABLE, NONWATER ELECTROCHEMICAL CELL

Also Published As

Publication number Publication date
BR7209100D0 (en) 1973-09-20
MY7600259A (en) 1976-12-31
KE2653A (en) 1976-08-13
NO142237C (en) 1980-07-16
DK136443B (en) 1977-10-10
SE430189C (en) 1987-04-13
AU5049072A (en) 1974-06-27
NL172807B (en) 1983-05-16
NL7217557A (en) 1973-06-29
DE2262256B2 (en) 1980-10-02
AR192848A1 (en) 1973-03-14
AT321389B (en) 1975-03-25
NL172807C (en) 1986-07-16
OA04308A (en) 1980-01-15
CH565457A5 (en) 1975-08-15
NO142237B (en) 1980-04-08
FR2166015B1 (en) 1977-12-30
AU467969B2 (en) 1974-06-27
ES410039A1 (en) 1975-12-01
FR2166015A1 (en) 1973-08-10
DE2262256A1 (en) 1973-07-26
SU524541A3 (en) 1976-08-05
JPS526446B2 (en) 1977-02-22
DE2262256C3 (en) 1986-04-17
SE430189B (en) 1983-10-24
CA982216A (en) 1976-01-20
IT974314B (en) 1974-06-20
BE793372A (en) 1973-06-27
JPS4876031A (en) 1973-10-13
PH10524A (en) 1977-05-26
ZA728971B (en) 1973-09-26

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Legal Events

Date Code Title Description
PS Patent sealed
732 Registration of transactions, instruments or events in the register (sect. 32/1977)
PE20 Patent expired after termination of 20 years

Effective date: 19921220