GB1404814A - Polyasphartic acid derivatives having surface-active properties - Google Patents
Polyasphartic acid derivatives having surface-active propertiesInfo
- Publication number
- GB1404814A GB1404814A GB4923872A GB4923872A GB1404814A GB 1404814 A GB1404814 A GB 1404814A GB 4923872 A GB4923872 A GB 4923872A GB 4923872 A GB4923872 A GB 4923872A GB 1404814 A GB1404814 A GB 1404814A
- Authority
- GB
- United Kingdom
- Prior art keywords
- product
- acid
- lauryl
- aspartic acid
- amide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
- A61K47/16—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing nitrogen, e.g. nitro-, nitroso-, azo-compounds, nitriles, cyanates
- A61K47/18—Amines; Amides; Ureas; Quaternary ammonium compounds; Amino acids; Oligopeptides having up to five amino acids
- A61K47/183—Amino acids, e.g. glycine, EDTA or aspartame
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/30—Macromolecular organic or inorganic compounds, e.g. inorganic polyphosphates
- A61K47/34—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polyesters, polyamino acids, polysiloxanes, polyphosphazines, copolymers of polyalkylene glycol or poloxamers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K9/00—Medicinal preparations characterised by special physical form
- A61K9/0012—Galenical forms characterised by the site of application
- A61K9/0014—Skin, i.e. galenical aspects of topical compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/10—Alpha-amino-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1003—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Animal Behavior & Ethology (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Epidemiology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Pharmacology & Pharmacy (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Textile Engineering (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Detergent Compositions (AREA)
- Polyamides (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
1404814 Aspartic acid-amide copolymers; modified polyimides KYOWA HAKKO KOGYO CO Ltd 25 Oct 1972 [1 Nov 1971] 49238/72 Heading C3R [Also in Divisions A5 and C5] Polyaspartic acid derivatives having hydrophobic and hydrophilic substitutents are obtained by reacting (a) a polyimide having a unit as the main compound and which is the heat polycondensation product of aspartic acid or of an ammonium salt or mono- or di-amide of, or mixture of ammonia with, aspartic, malic, maleic or fumaric acid, with (b) at least one primary or secondary amine R<SP>1</SP>R<SP>11</SP>NH where R<SP>1</SP> is H or C 1-20 alkyl or alkenyl and R<SP>11</SP> is C 8-20 alkyl or alkenyl, and hydrolysing the reaction product with alkali. The polyimide may have a molecular weight of 300 to 30,000. 0À005 to 1À0, preferably 0À015 to 0À5 equivalents of amine may be used per imide group of the polyimide. The product may be further treated by ionexchange to partially convert the alkali salt groups to free acid or to a different salt. In examples lauryl, oleyl, N-methyl-N-lauryl and a mixture of lauryl and polmityl amines are used as the amine. Uses.-The products are useful as surfactants especially for detergent and cosmetic compositions. In Examples (2) 10% of the product, a copolymer of α,#-aspartic acid and itsoleyl amide is blended with 5% anhydrous sodium sulphate, 0À5% perfume and 84À5% water to give a liquid shampoo; (3) 25% of the product, a copolymer of α,#-aspartic acid with its N- methyl-N-laury amide is blended with 1À2% triethanolamine, 10% glycerine, 0À9% perfume, 5% stearic acid and 57À9% water to give a vanishing cream; and (4) 20% of the product, a terpolymer of the lauryl and palmityl amides and potassium salt of α,#-aspartic acid, is blended with 3% sodium citrate, 0À5% perfume, 3% anhydrous sodium sulphate and 73À5% water to give a detergent for table-ware.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP46086288A JPS4851995A (en) | 1971-11-01 | 1971-11-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1404814A true GB1404814A (en) | 1975-09-03 |
Family
ID=13882633
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4923872A Expired GB1404814A (en) | 1971-11-01 | 1972-10-25 | Polyasphartic acid derivatives having surface-active properties |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS4851995A (en) |
CA (1) | CA990282A (en) |
DE (1) | DE2253190A1 (en) |
FR (1) | FR2158291B1 (en) |
GB (1) | GB1404814A (en) |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0454126A1 (en) * | 1990-04-26 | 1991-10-30 | Rohm And Haas Company | Polyaminoacids as builders for detergent formulations |
FR2675153A1 (en) * | 1991-04-15 | 1992-10-16 | Rhone Poulenc Chimie | DETERGENT COMPOSITION CONTAINING A POLYIMIDE BIOPOLYMER HYDROLYSABLE IN A WASHING MEDIUM. |
EP0581452A1 (en) * | 1992-07-31 | 1994-02-02 | Rohm And Haas Company | Detergent compositions containing polysuccinimide |
US5393868A (en) * | 1992-10-13 | 1995-02-28 | Rohm And Haas Company | Production of polysuccinimide by thermal polymerization of maleamic acid |
US5457176A (en) * | 1993-09-21 | 1995-10-10 | Rohm And Haas Company | Acid catalyzed process for preparing amino acid polymers |
US5506335A (en) * | 1994-08-24 | 1996-04-09 | Bayer Ag | Sulfonic acid group-containing polyaspartic acid derivatives, use thereof and preparation thereof |
US5538671A (en) * | 1992-10-27 | 1996-07-23 | The Procter & Gamble Company | Detergent compositions with builder system comprising aluminosilicates and polyaspartate |
US5540863A (en) * | 1993-09-10 | 1996-07-30 | Bayer Ag | Mixtures of polyamino acids and citrate |
US5580355A (en) * | 1994-11-09 | 1996-12-03 | Bayer Aktiengesellschaft | Leather tanning agent and standardizing agents for dyestuffs |
US5594077A (en) * | 1993-11-02 | 1997-01-14 | Bayer Ag | Process for preparing polymers which contain aspartic acid |
US5610267A (en) * | 1992-05-14 | 1997-03-11 | Bayer Ag | Process for preparing polysuccinimide by high temperature reaction |
US5714558A (en) * | 1993-03-02 | 1998-02-03 | Bayer Ag | Process for preparing polyaspartic acid |
US5726280A (en) * | 1994-08-24 | 1998-03-10 | Bayer Ag | Sulfonic acid group-containing polyaspartic acid derivatives, use thereof and prepartion thereof |
US5773565A (en) * | 1992-05-14 | 1998-06-30 | Bayer Ag | Salts of polyaspartic acid by high temperature reaction |
US5804639A (en) * | 1995-10-31 | 1998-09-08 | Bayer Ag | Pigment preparations having a high solids content |
US5885474A (en) * | 1995-08-04 | 1999-03-23 | Bayer Aktiengesellschaft | Use of polyaspartic acid amides as leather auxiliary products |
US5902357A (en) * | 1996-08-30 | 1999-05-11 | Bayer Aktiengesellschaft | Composition for dyeing or printing textile materials |
US5942150A (en) * | 1995-08-17 | 1999-08-24 | Bayer Aktiengesellschaft | Use as antifreeze of polymers with recurring succinyl units |
US6051258A (en) | 1995-06-07 | 2000-04-18 | Emisphere Technologies, Inc. | Proteinoid emulsions and methods for preparation and use thereof |
US6096097A (en) * | 1998-03-05 | 2000-08-01 | Bayer Aktiengesellschaft | Simultaneous washing and bleaching of native fibres and textile products therefrom |
EP1173499A1 (en) * | 1999-04-07 | 2002-01-23 | National Starch & Chemical Company | Use of polyamino acid salts in water-borne adhesive applications |
EP1417251A1 (en) * | 2001-08-03 | 2004-05-12 | The Procter & Gamble Company | Polyaspartate derivatives for use in detergent compositions |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2403076A1 (en) * | 1977-09-14 | 1979-04-13 | Oreal | Cosmetic compsn. for skin and hair treatment - contains poly:aspartic acid amide giving improved smoothness, gloss etc. |
FR2424293A1 (en) * | 1978-04-27 | 1979-11-23 | Oreal | Poly:dehydro:aspartic acid prodn. from aspartic acid - by heating in high boiling solvent in presence of acid ion exchange resin, intermediates for cosmetic adjuvants |
FR2424292A1 (en) * | 1978-04-27 | 1979-11-23 | Oreal | Mixed amide derivs. of poly-aspartic acid - useful as adjuvants in cosmetics for skin and hair |
DE4217847A1 (en) * | 1992-05-29 | 1993-12-02 | Basf Ag | Use of condensates of aspartic acid as a deposit inhibitor when evaporating sugar juices |
DE4221875A1 (en) * | 1992-07-03 | 1994-01-05 | Basf Ag | Modified polyaspartic acids, process for their preparation and their use |
FR2696473A1 (en) * | 1992-10-06 | 1994-04-08 | Rhone Poulenc Chimie | Detergent composition incorporating a polyimide biopolymer hydrolyzable in a washing medium. |
ATE173282T1 (en) * | 1993-02-22 | 1998-11-15 | Bayer Ag | METHOD FOR PRODUCING POLYSUCCINIMIDE AND POLYASPARAGIC ACID |
DE4306412A1 (en) * | 1993-03-02 | 1994-09-08 | Bayer Ag | Process for the preparation of polyaspartic acid |
DE4307114A1 (en) * | 1993-03-06 | 1994-09-08 | Basf Ag | Process for the preparation of reaction products of polyaspartic acid amide and amino acids and their use |
EP0621300B1 (en) * | 1993-04-23 | 1998-09-30 | Rhodia Chimie | Polyanhydroaspartic acid and its biodegradable hydrolysats |
DE4425952A1 (en) | 1994-07-21 | 1996-01-25 | Bayer Ag | Process for the preparation of polysuccinimide or maleic acid |
DE19513903A1 (en) * | 1995-04-12 | 1996-10-17 | Bayer Ag | Wood preservative containing a copper compound |
DE19545678A1 (en) * | 1995-12-07 | 1997-06-12 | Goldschmidt Ag Th | Copolymers of polyamino acid esters |
EP0884344A3 (en) * | 1997-06-11 | 1999-11-17 | Th. Goldschmidt AG | Mild surfactant compositions with copolymer polyaspartic acid derivatives for cosmetics or cleaning |
EP0884380A3 (en) * | 1997-06-11 | 1999-11-17 | Th. Goldschmidt AG | Mild alkylpolyglucoside-free surfactant compositions comprising hydrophobe modified polyaspartic acid derivative |
DE19822601A1 (en) * | 1998-05-20 | 1999-11-25 | Goldschmidt Ag Th | Hydrophobically modified polyaspartic acid derivatives in O / W emulsions |
-
1971
- 1971-11-01 JP JP46086288A patent/JPS4851995A/ja active Pending
-
1972
- 1972-10-25 GB GB4923872A patent/GB1404814A/en not_active Expired
- 1972-10-26 FR FR7238017A patent/FR2158291B1/fr not_active Expired
- 1972-10-27 CA CA155,102A patent/CA990282A/en not_active Expired
- 1972-10-30 DE DE2253190A patent/DE2253190A1/en active Pending
Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0454126A1 (en) * | 1990-04-26 | 1991-10-30 | Rohm And Haas Company | Polyaminoacids as builders for detergent formulations |
US5658872A (en) * | 1990-04-26 | 1997-08-19 | Rohm And Haas Company | Polyaminoacids as builders for formulations of detergents |
US5328631A (en) * | 1990-04-26 | 1994-07-12 | S.R.L. Montedipe | Polyaminoacids as builders for formulations of detergents |
FR2675153A1 (en) * | 1991-04-15 | 1992-10-16 | Rhone Poulenc Chimie | DETERGENT COMPOSITION CONTAINING A POLYIMIDE BIOPOLYMER HYDROLYSABLE IN A WASHING MEDIUM. |
EP0511037A1 (en) * | 1991-04-15 | 1992-10-28 | Rhone-Poulenc Chimie | Detergent composition containing a polyimide biopolymer hydrolysable in the washing medium |
US5616547A (en) * | 1991-04-15 | 1997-04-01 | Rhone-Poulenc Chimie | Detergent compositions containing wash liquid-hydrolyzable polyimide biopolymers |
US5610267A (en) * | 1992-05-14 | 1997-03-11 | Bayer Ag | Process for preparing polysuccinimide by high temperature reaction |
US6072025A (en) * | 1992-05-14 | 2000-06-06 | Bayer Ag | Salts of polyaspartic acid by high temperature reaction |
US5773565A (en) * | 1992-05-14 | 1998-06-30 | Bayer Ag | Salts of polyaspartic acid by high temperature reaction |
EP0581452A1 (en) * | 1992-07-31 | 1994-02-02 | Rohm And Haas Company | Detergent compositions containing polysuccinimide |
US5612447A (en) * | 1992-10-13 | 1997-03-18 | Rohm And Haas Company | Production of polysuccinimide by thermal polymerization of maleamic acid |
US5393868A (en) * | 1992-10-13 | 1995-02-28 | Rohm And Haas Company | Production of polysuccinimide by thermal polymerization of maleamic acid |
US5538671A (en) * | 1992-10-27 | 1996-07-23 | The Procter & Gamble Company | Detergent compositions with builder system comprising aluminosilicates and polyaspartate |
US5714558A (en) * | 1993-03-02 | 1998-02-03 | Bayer Ag | Process for preparing polyaspartic acid |
US5540863A (en) * | 1993-09-10 | 1996-07-30 | Bayer Ag | Mixtures of polyamino acids and citrate |
US5457176A (en) * | 1993-09-21 | 1995-10-10 | Rohm And Haas Company | Acid catalyzed process for preparing amino acid polymers |
US5594077A (en) * | 1993-11-02 | 1997-01-14 | Bayer Ag | Process for preparing polymers which contain aspartic acid |
US5506335A (en) * | 1994-08-24 | 1996-04-09 | Bayer Ag | Sulfonic acid group-containing polyaspartic acid derivatives, use thereof and preparation thereof |
US5726280A (en) * | 1994-08-24 | 1998-03-10 | Bayer Ag | Sulfonic acid group-containing polyaspartic acid derivatives, use thereof and prepartion thereof |
US5580355A (en) * | 1994-11-09 | 1996-12-03 | Bayer Aktiengesellschaft | Leather tanning agent and standardizing agents for dyestuffs |
US6051258A (en) | 1995-06-07 | 2000-04-18 | Emisphere Technologies, Inc. | Proteinoid emulsions and methods for preparation and use thereof |
US5885474A (en) * | 1995-08-04 | 1999-03-23 | Bayer Aktiengesellschaft | Use of polyaspartic acid amides as leather auxiliary products |
US5942150A (en) * | 1995-08-17 | 1999-08-24 | Bayer Aktiengesellschaft | Use as antifreeze of polymers with recurring succinyl units |
US5804639A (en) * | 1995-10-31 | 1998-09-08 | Bayer Ag | Pigment preparations having a high solids content |
US5902357A (en) * | 1996-08-30 | 1999-05-11 | Bayer Aktiengesellschaft | Composition for dyeing or printing textile materials |
US6096097A (en) * | 1998-03-05 | 2000-08-01 | Bayer Aktiengesellschaft | Simultaneous washing and bleaching of native fibres and textile products therefrom |
EP1173499A1 (en) * | 1999-04-07 | 2002-01-23 | National Starch & Chemical Company | Use of polyamino acid salts in water-borne adhesive applications |
EP1173499A4 (en) * | 1999-04-07 | 2002-10-16 | Nat Starch & Chemical Company | Use of polyamino acid salts in water-borne adhesive applications |
EP1417251A1 (en) * | 2001-08-03 | 2004-05-12 | The Procter & Gamble Company | Polyaspartate derivatives for use in detergent compositions |
Also Published As
Publication number | Publication date |
---|---|
CA990282A (en) | 1976-06-01 |
DE2253190A1 (en) | 1973-05-10 |
FR2158291A1 (en) | 1973-06-15 |
FR2158291B1 (en) | 1976-08-20 |
JPS4851995A (en) | 1973-07-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |