GB1392102A - Production of phosphate ester salts and their use as cleaning intensifiers - Google Patents

Production of phosphate ester salts and their use as cleaning intensifiers

Info

Publication number
GB1392102A
GB1392102A GB1519272A GB1519272A GB1392102A GB 1392102 A GB1392102 A GB 1392102A GB 1519272 A GB1519272 A GB 1519272A GB 1519272 A GB1519272 A GB 1519272A GB 1392102 A GB1392102 A GB 1392102A
Authority
GB
United Kingdom
Prior art keywords
reacting
urea
paraformaldehyde
aminoethyl
ethanolamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1519272A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemische Fabrik Pfersee GmbH
Original Assignee
Chemische Fabrik Pfersee GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19712166397 external-priority patent/DE2166397C3/en
Application filed by Chemische Fabrik Pfersee GmbH filed Critical Chemische Fabrik Pfersee GmbH
Publication of GB1392102A publication Critical patent/GB1392102A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/50—Derivatives of urea, thiourea, cyanamide, guanidine or urethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
    • D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/40—Monoamines or polyamines; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/528—Carboxylic amides (R1-CO-NR2R3), where at least one of the chains R1, R2 or R3 is interrupted by a functional group, e.g. a -NH-, -NR-, -CO-, or -CON- group

Abstract

1392102 Phosphate ester salts CHEMISCHE FABRIK PFERSEE GmbH 30 March 1972 [31 March 1971 13 Nov 1971 17 March 1972] 15192/72 Headings C2P and C2C [Also in Division C5] A cationic cleaning intensifier (i.e. a dry cleaning detergent), is obtained by (a) condensing one mole of a fatty acid aminoalkyl alkanolamide of the formula RCONHC n H 2n NHC x H 2x OH in which R is a saturated or unsaturated C 9 -C 22 aliphatic hydrocarbyl radical which may be substituted, e.g. by OH, and n and x are integers from 2 to 4, with 0-4 to 0-9 mole of urea or acetyl urea such that 0À55 to 0-9 mole of ammonia is released and (b) at least partly neutralizing the condensation product with a compound of the formula HO.P:(O)(OR<SP>1</SP>) 2 and/or where R<SP>1</SP> is a C 2 -C 6 alkyl group. The product from (a) may be reacted prior to the neutralization step (b) with 0-2 to 0-6 mole of a compound of the formula H 2 N-CaH 2a -X in which X is NH 2 , OH, NH-C b H 2b -NH 2 or where a and b are like or unlike integers of 2 or 3 and such further condensation products may optionally be reacted with formaldehyde, e.g. as paraformaldehyde, prior to the neutralization step, the formaldehyde being used in an amount of 0-2 to 1-5 moles per mol of the originally used amount of the fatty acid aminoalkyl alkanolamide of the given formula. The amount of the phosphoric ester or ester mixture used in the neutralization step preferably be such as to give a pH value of between 4 and 7 preferably between 5 and 6. The products are useful for the dry cleaning of textiles. Condensation products are obtained by (1) reacting oleic acid with aminoethyl ethanolamine and then with urea and optionally further reacting with aminoethyl ethanolamine and optionally paraformaldehyde; (2) as in (1) but using diethylene triamine instead of aminoethyl ethanolamine in the further condensation step and omitting the paraformaldehyde reaction; (3) reacting ricinoleic acid aminoethyl ethanolamide with urea and then with ethylene diamine and optionally further reacting with formaldehyde; (4) reacting a mixture of stearic acid aminopropyl ethanolamide and ricinoleic acid aminoethyl ethanolamide with acetyl urea, then with aminopropyl propanolamine and then optionally further reacting with paraformaldehyde; and (5) reacting an aminoethyl ethanolamide of a coconut fatty acid with urea and then with monoethanolamine and optional further reaction with paraformaldehyde.
GB1519272A 1971-03-31 1972-03-30 Production of phosphate ester salts and their use as cleaning intensifiers Expired GB1392102A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE19712115477 DE2115477C3 (en) 1971-03-31 1971-03-31 Process for the production of cleaning enhancers based on condensation products from fatty acid aminoalkylalkanolamides and urea or acetylurea
DE19712166397 DE2166397C3 (en) 1971-03-31 Cleaning enhancer mixtures
DE19712156454 DE2156454C3 (en) 1971-03-31 1971-11-13 Cleaning enhancer mixtures
DE19722264704 DE2264704A1 (en) 1971-03-31 1972-03-17 USE OF CLEANING AMPLIFIERS
DE19722212867 DE2212867A1 (en) 1971-03-31 1972-03-17 USE OF CLEANSING AMPLIFIERS AND CLEANSING AMPLIFIERS

Publications (1)

Publication Number Publication Date
GB1392102A true GB1392102A (en) 1975-04-23

Family

ID=27510155

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1519272A Expired GB1392102A (en) 1971-03-31 1972-03-30 Production of phosphate ester salts and their use as cleaning intensifiers

Country Status (5)

Country Link
CH (3) CH573391A5 (en)
DE (4) DE2115477C3 (en)
FR (1) FR2132290B1 (en)
GB (1) GB1392102A (en)
NL (1) NL7204348A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2747723C2 (en) * 1977-10-25 1979-12-13 Hoechst Ag, 6000 Frankfurt Quaternized amine-amide condensation products and their use in oil-based fiber finishes
US4336386A (en) 1978-11-30 1982-06-22 Mona Industries, Inc. Quaternary imidazolinium phosphite derivatives
US4243602A (en) * 1978-11-30 1981-01-06 Mona Industries Novel quaternary compounds
JPS61289182A (en) * 1985-06-14 1986-12-19 竹本油脂株式会社 Antistatic agent for synthetic fiber

Also Published As

Publication number Publication date
FR2132290B1 (en) 1976-06-11
FR2132290A1 (en) 1972-11-17
CH554447A (en) 1974-09-30
DE2115477B2 (en) 1973-12-20
DE2166397B2 (en) 1975-12-11
DE2156454B2 (en) 1977-11-03
NL7204348A (en) 1972-10-03
DE2156454C3 (en) 1984-02-02
DE2115477A1 (en) 1972-10-05
DE2212867A1 (en) 1973-09-27
DE2166397A1 (en) 1973-11-08
CH573391A5 (en) 1976-03-15
DE2156454A1 (en) 1973-05-17
DE2264704A1 (en) 1974-08-15
CH461472A4 (en) 1974-03-15
DE2115477C3 (en) 1975-08-28

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees