GB1387759A - Manufacture of polyesters - Google Patents

Manufacture of polyesters

Info

Publication number
GB1387759A
GB1387759A GB3250173A GB3250173A GB1387759A GB 1387759 A GB1387759 A GB 1387759A GB 3250173 A GB3250173 A GB 3250173A GB 3250173 A GB3250173 A GB 3250173A GB 1387759 A GB1387759 A GB 1387759A
Authority
GB
United Kingdom
Prior art keywords
dicarboxylic acid
reaction
diol
acid
monoacylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3250173A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3250173A priority Critical patent/GB1387759A/en
Publication of GB1387759A publication Critical patent/GB1387759A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/80Solid-state polycondensation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

1387759 Solid phase preparation of polyesters IMPERIAL CHEMICAL INDUSTRIES Ltd 10 July 1973 [21 July 1972 14 Nov 1972] 32501/73 and 32502/73 Divided out of 1387335 Heading C3R A process for preparing a polyester comprises reacting an aromatic dicarboxylic acid in the solid state with a diol or a diol monoacylate, the reaction conditions being controlled so that throughout the reaction a major part of the reaction mass forms a solid phase. The reaction may be carried out under fluidized bed conditions with the diacid in particulate form and the diol or diol monoacylate in the vapour state, preferably in a chemically inert carrier gas, e.g. nitrogen. The examples describe reacting terephthalic acid with ethylene glycol. The following are also described; (a) reaction of ethylene glycol with naphthalene - 2,6 and 2,7 - dicarboxylic acid, 1,2-diphenoxy-ethane and butanep,p<SP>1</SP> - dicarboxylic acid, biphenyl - 4,41- dicarbocylic acid, diphenyl sulphone-4,41-dicarboxylic acid, bibenzyl-4,41-dicarboxylic acid, stilbene - 4,4<SP>1</SP> - dicarboxylic acid, 1,2 - di - pcarboxy - benzoyloxyethane and 1,6 - di - pcarboxybenzamidohexane, (b) reaction of 1,3- propanediol with biphenyl-4,4<SP>1</SP>-dicarboxylic acid and diphenyl sulphone-4,4<SP>1</SP>-dicarboxylic acid and (c) reaction of 2-hydroxyethyl acetate with terephthalic acid.
GB3250173A 1972-07-21 1972-07-21 Manufacture of polyesters Expired GB1387759A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3250173A GB1387759A (en) 1972-07-21 1972-07-21 Manufacture of polyesters

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB3250173A GB1387759A (en) 1972-07-21 1972-07-21 Manufacture of polyesters
GB3250273 1972-11-14

Publications (1)

Publication Number Publication Date
GB1387759A true GB1387759A (en) 1975-03-19

Family

ID=26261410

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3250173A Expired GB1387759A (en) 1972-07-21 1972-07-21 Manufacture of polyesters

Country Status (1)

Country Link
GB (1) GB1387759A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6649263B2 (en) 2001-11-16 2003-11-18 Honeywell International Inc. Polyester resin and industrial yarn process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6649263B2 (en) 2001-11-16 2003-11-18 Honeywell International Inc. Polyester resin and industrial yarn process

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee