GB1387759A - Manufacture of polyesters - Google Patents
Manufacture of polyestersInfo
- Publication number
- GB1387759A GB1387759A GB3250173A GB3250173A GB1387759A GB 1387759 A GB1387759 A GB 1387759A GB 3250173 A GB3250173 A GB 3250173A GB 3250173 A GB3250173 A GB 3250173A GB 1387759 A GB1387759 A GB 1387759A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dicarboxylic acid
- reaction
- diol
- acid
- monoacylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
1387759 Solid phase preparation of polyesters IMPERIAL CHEMICAL INDUSTRIES Ltd 10 July 1973 [21 July 1972 14 Nov 1972] 32501/73 and 32502/73 Divided out of 1387335 Heading C3R A process for preparing a polyester comprises reacting an aromatic dicarboxylic acid in the solid state with a diol or a diol monoacylate, the reaction conditions being controlled so that throughout the reaction a major part of the reaction mass forms a solid phase. The reaction may be carried out under fluidized bed conditions with the diacid in particulate form and the diol or diol monoacylate in the vapour state, preferably in a chemically inert carrier gas, e.g. nitrogen. The examples describe reacting terephthalic acid with ethylene glycol. The following are also described; (a) reaction of ethylene glycol with naphthalene - 2,6 and 2,7 - dicarboxylic acid, 1,2-diphenoxy-ethane and butanep,p<SP>1</SP> - dicarboxylic acid, biphenyl - 4,41- dicarbocylic acid, diphenyl sulphone-4,41-dicarboxylic acid, bibenzyl-4,41-dicarboxylic acid, stilbene - 4,4<SP>1</SP> - dicarboxylic acid, 1,2 - di - pcarboxy - benzoyloxyethane and 1,6 - di - pcarboxybenzamidohexane, (b) reaction of 1,3- propanediol with biphenyl-4,4<SP>1</SP>-dicarboxylic acid and diphenyl sulphone-4,4<SP>1</SP>-dicarboxylic acid and (c) reaction of 2-hydroxyethyl acetate with terephthalic acid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3250173A GB1387759A (en) | 1972-07-21 | 1972-07-21 | Manufacture of polyesters |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3250173A GB1387759A (en) | 1972-07-21 | 1972-07-21 | Manufacture of polyesters |
GB3250273 | 1972-11-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1387759A true GB1387759A (en) | 1975-03-19 |
Family
ID=26261410
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3250173A Expired GB1387759A (en) | 1972-07-21 | 1972-07-21 | Manufacture of polyesters |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1387759A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6649263B2 (en) | 2001-11-16 | 2003-11-18 | Honeywell International Inc. | Polyester resin and industrial yarn process |
-
1972
- 1972-07-21 GB GB3250173A patent/GB1387759A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6649263B2 (en) | 2001-11-16 | 2003-11-18 | Honeywell International Inc. | Polyester resin and industrial yarn process |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |