GB1367138A - Processes for the manufacture of diesters and polyesters - Google Patents
Processes for the manufacture of diesters and polyestersInfo
- Publication number
- GB1367138A GB1367138A GB4057871A GB4057871A GB1367138A GB 1367138 A GB1367138 A GB 1367138A GB 4057871 A GB4057871 A GB 4057871A GB 4057871 A GB4057871 A GB 4057871A GB 1367138 A GB1367138 A GB 1367138A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrolysis
- diol
- aromatic dicarboxylic
- ester
- dicarboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1367138 Esters FARBWERKE HOECHST AG 31 Aug 1971 [3 Sept 1970] 40578/71 Heading C2C [Also in Division C3] A process for the preparation of a di-ester of an aromatic dicarboxylic acid and a diol and/or a low molecular weight oligomer thereof, comprises hydrolysing a dialkyl ester of an aromatic dicarboxylic acid in the absence of a catalyst to form a hydrolysate containing at least 60% but less than 100% of free acid groups, calculated on the total number of free acid and unhydrolysed alkyl ester groups, and reacting the hydrolysate with a diol. The hydrolysis is preferably carried out at 150‹ to 300‹ C. under pressure in an autoclave using water without any additives. The examples describe the potential hydrolysis of dimethyl terephthalate, optionally mixed with dimethyl isophthalate, and the reaction of the hydrolysis product with ethylene glycol.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19702043630 DE2043630A1 (en) | 1970-09-03 | 1970-09-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1367138A true GB1367138A (en) | 1974-09-18 |
Family
ID=5781441
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4057871A Expired GB1367138A (en) | 1970-09-03 | 1971-08-31 | Processes for the manufacture of diesters and polyesters |
Country Status (9)
Country | Link |
---|---|
AT (1) | AT322854B (en) |
BE (1) | BE772056A (en) |
BR (1) | BR7105806D0 (en) |
CA (1) | CA970897A (en) |
CH (1) | CH550835A (en) |
DE (1) | DE2043630A1 (en) |
FR (1) | FR2105227B1 (en) |
GB (1) | GB1367138A (en) |
NL (1) | NL7111832A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5296587A (en) * | 1993-03-22 | 1994-03-22 | Eastman Chemical Company | Copolymerization of dicarboxylic acids and dialkyl esters of dicarboxylic acids to form polyesters |
-
1970
- 1970-09-03 DE DE19702043630 patent/DE2043630A1/de active Pending
-
1971
- 1971-08-26 CA CA121,383A patent/CA970897A/en not_active Expired
- 1971-08-27 NL NL7111832A patent/NL7111832A/xx unknown
- 1971-08-31 CH CH1280871A patent/CH550835A/en not_active IP Right Cessation
- 1971-08-31 GB GB4057871A patent/GB1367138A/en not_active Expired
- 1971-09-01 AT AT759871A patent/AT322854B/en not_active IP Right Cessation
- 1971-09-01 BE BE772056A patent/BE772056A/en unknown
- 1971-09-02 BR BR580671A patent/BR7105806D0/en unknown
- 1971-09-03 FR FR7131883A patent/FR2105227B1/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BE772056A (en) | 1972-03-01 |
BR7105806D0 (en) | 1973-06-28 |
FR2105227A1 (en) | 1972-04-28 |
NL7111832A (en) | 1972-03-07 |
FR2105227B1 (en) | 1976-03-26 |
CA970897A (en) | 1975-07-08 |
AT322854B (en) | 1975-06-10 |
CH550835A (en) | 1974-06-28 |
DE2043630A1 (en) | 1972-03-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |