GB1367138A - Processes for the manufacture of diesters and polyesters - Google Patents

Processes for the manufacture of diesters and polyesters

Info

Publication number
GB1367138A
GB1367138A GB4057871A GB4057871A GB1367138A GB 1367138 A GB1367138 A GB 1367138A GB 4057871 A GB4057871 A GB 4057871A GB 4057871 A GB4057871 A GB 4057871A GB 1367138 A GB1367138 A GB 1367138A
Authority
GB
United Kingdom
Prior art keywords
hydrolysis
diol
aromatic dicarboxylic
ester
dicarboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4057871A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1367138A publication Critical patent/GB1367138A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1367138 Esters FARBWERKE HOECHST AG 31 Aug 1971 [3 Sept 1970] 40578/71 Heading C2C [Also in Division C3] A process for the preparation of a di-ester of an aromatic dicarboxylic acid and a diol and/or a low molecular weight oligomer thereof, comprises hydrolysing a dialkyl ester of an aromatic dicarboxylic acid in the absence of a catalyst to form a hydrolysate containing at least 60% but less than 100% of free acid groups, calculated on the total number of free acid and unhydrolysed alkyl ester groups, and reacting the hydrolysate with a diol. The hydrolysis is preferably carried out at 150‹ to 300‹ C. under pressure in an autoclave using water without any additives. The examples describe the potential hydrolysis of dimethyl terephthalate, optionally mixed with dimethyl isophthalate, and the reaction of the hydrolysis product with ethylene glycol.
GB4057871A 1970-09-03 1971-08-31 Processes for the manufacture of diesters and polyesters Expired GB1367138A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19702043630 DE2043630A1 (en) 1970-09-03 1970-09-03

Publications (1)

Publication Number Publication Date
GB1367138A true GB1367138A (en) 1974-09-18

Family

ID=5781441

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4057871A Expired GB1367138A (en) 1970-09-03 1971-08-31 Processes for the manufacture of diesters and polyesters

Country Status (9)

Country Link
AT (1) AT322854B (en)
BE (1) BE772056A (en)
BR (1) BR7105806D0 (en)
CA (1) CA970897A (en)
CH (1) CH550835A (en)
DE (1) DE2043630A1 (en)
FR (1) FR2105227B1 (en)
GB (1) GB1367138A (en)
NL (1) NL7111832A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5296587A (en) * 1993-03-22 1994-03-22 Eastman Chemical Company Copolymerization of dicarboxylic acids and dialkyl esters of dicarboxylic acids to form polyesters

Also Published As

Publication number Publication date
BE772056A (en) 1972-03-01
BR7105806D0 (en) 1973-06-28
FR2105227A1 (en) 1972-04-28
NL7111832A (en) 1972-03-07
FR2105227B1 (en) 1976-03-26
CA970897A (en) 1975-07-08
AT322854B (en) 1975-06-10
CH550835A (en) 1974-06-28
DE2043630A1 (en) 1972-03-09

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees